Tris(1,10-phenanthroline-κ(2) N,N′)zinc(II) chloride 2-phenyl-4-selenazole-5-car­box­yl­ate decahydrate

The asymmetric unit of the title salt, [Zn(C(12)H(8)N(2))(3)](C(10)H(6)NO(2)Se)Cl·10H(2)O, contains a [Zn(phen)(3)](2+) cation (phen is 1,10-phenanthroline), uncoordinated chloride and 2-phenyl-4-selenazole-5-carboxyl­ate anions and ten uncoord­in­ated water mol­ecules. The central Zn(II) ion is six...

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Detalles Bibliográficos
Autores principales: Shen, Jin-Bei, Lv, Xin, Chen, Ji-Fei, Zhou, Yu-Feng, Zhao, Guo-Liang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051608/
https://www.ncbi.nlm.nih.gov/pubmed/21522857
http://dx.doi.org/10.1107/S1600536811000729
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author Shen, Jin-Bei
Lv, Xin
Chen, Ji-Fei
Zhou, Yu-Feng
Zhao, Guo-Liang
author_facet Shen, Jin-Bei
Lv, Xin
Chen, Ji-Fei
Zhou, Yu-Feng
Zhao, Guo-Liang
author_sort Shen, Jin-Bei
collection PubMed
description The asymmetric unit of the title salt, [Zn(C(12)H(8)N(2))(3)](C(10)H(6)NO(2)Se)Cl·10H(2)O, contains a [Zn(phen)(3)](2+) cation (phen is 1,10-phenanthroline), uncoordinated chloride and 2-phenyl-4-selenazole-5-carboxyl­ate anions and ten uncoord­in­ated water mol­ecules. The central Zn(II) ion is six-coordinated by six N atoms from three phen ligands in a distorted octa­hedral geometry. An extensive O—H⋯O, O—H⋯N and O—H⋯Cl hydrogen-bonding network stabilizes the crystal structure.
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spelling pubmed-30516082011-04-26 Tris(1,10-phenanthroline-κ(2) N,N′)zinc(II) chloride 2-phenyl-4-selenazole-5-car­box­yl­ate decahydrate Shen, Jin-Bei Lv, Xin Chen, Ji-Fei Zhou, Yu-Feng Zhao, Guo-Liang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title salt, [Zn(C(12)H(8)N(2))(3)](C(10)H(6)NO(2)Se)Cl·10H(2)O, contains a [Zn(phen)(3)](2+) cation (phen is 1,10-phenanthroline), uncoordinated chloride and 2-phenyl-4-selenazole-5-carboxyl­ate anions and ten uncoord­in­ated water mol­ecules. The central Zn(II) ion is six-coordinated by six N atoms from three phen ligands in a distorted octa­hedral geometry. An extensive O—H⋯O, O—H⋯N and O—H⋯Cl hydrogen-bonding network stabilizes the crystal structure. International Union of Crystallography 2011-01-15 /pmc/articles/PMC3051608/ /pubmed/21522857 http://dx.doi.org/10.1107/S1600536811000729 Text en © Shen et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Shen, Jin-Bei
Lv, Xin
Chen, Ji-Fei
Zhou, Yu-Feng
Zhao, Guo-Liang
Tris(1,10-phenanthroline-κ(2) N,N′)zinc(II) chloride 2-phenyl-4-selenazole-5-car­box­yl­ate decahydrate
title Tris(1,10-phenanthroline-κ(2) N,N′)zinc(II) chloride 2-phenyl-4-selenazole-5-car­box­yl­ate decahydrate
title_full Tris(1,10-phenanthroline-κ(2) N,N′)zinc(II) chloride 2-phenyl-4-selenazole-5-car­box­yl­ate decahydrate
title_fullStr Tris(1,10-phenanthroline-κ(2) N,N′)zinc(II) chloride 2-phenyl-4-selenazole-5-car­box­yl­ate decahydrate
title_full_unstemmed Tris(1,10-phenanthroline-κ(2) N,N′)zinc(II) chloride 2-phenyl-4-selenazole-5-car­box­yl­ate decahydrate
title_short Tris(1,10-phenanthroline-κ(2) N,N′)zinc(II) chloride 2-phenyl-4-selenazole-5-car­box­yl­ate decahydrate
title_sort tris(1,10-phenanthroline-κ(2) n,n′)zinc(ii) chloride 2-phenyl-4-selenazole-5-car­box­yl­ate decahydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051608/
https://www.ncbi.nlm.nih.gov/pubmed/21522857
http://dx.doi.org/10.1107/S1600536811000729
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