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Bis[2-(benzylamino)pyridine-κN (1)]bis(2-formylphenolato-κ(2) O,O′)nickel(II)
In the title complex, [Ni(C(7)H(5)O(2))(2)(C(12)H(12)N(2))(2)], the Ni(II) atom lies on a center of inversion and is coordinated in an octahedral geometry by two 2-(benzylamino)pyridine (2-BAP) and two 2-formylphenolate ligands with the O-atom donors in the equatorial plane and the pyridine N at...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051610/ https://www.ncbi.nlm.nih.gov/pubmed/21522871 http://dx.doi.org/10.1107/S1600536811001425 |
Sumario: | In the title complex, [Ni(C(7)H(5)O(2))(2)(C(12)H(12)N(2))(2)], the Ni(II) atom lies on a center of inversion and is coordinated in an octahedral geometry by two 2-(benzylamino)pyridine (2-BAP) and two 2-formylphenolate ligands with the O-atom donors in the equatorial plane and the pyridine N atoms in axial positions. There are hydrogen-bonding interactions between the secondary amine H atom and the phenolate O atom, as well as C—H⋯O interactions, which result in the dihedral angle between the aromatic phenyl ring of the 2-formylphenolate moiety and the pyridine ring being 80.23 (4)°. In the packing, there are both C—H⋯π interactions, which link the molecules into chains along the b axis, and offset π–π interactions involving both the pyridine and phenyl rings of the 2-BAP ligands [centroid–centroid distances = 4.0100 (8) Å for the pyridine rings and 3.6601 (8) and 4.8561 (8) Å for the phenyl rings]. |
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