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Bis[2-(benzyl­amino)­pyridine-κN (1)]bis­(2-formyl­phenolato-κ(2) O,O′)nickel(II)

In the title complex, [Ni(C(7)H(5)O(2))(2)(C(12)H(12)N(2))(2)], the Ni(II) atom lies on a center of inversion and is coordinated in an octa­hedral geometry by two 2-(benzyl­amino)­pyridine (2-BAP) and two 2-formyl­phenolate ligands with the O-atom donors in the equatorial plane and the pyridine N at...

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Detalles Bibliográficos
Autores principales: Ayikoé, Kouassi, Butcher, Ray J., Gultneh, Yilma
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051610/
https://www.ncbi.nlm.nih.gov/pubmed/21522871
http://dx.doi.org/10.1107/S1600536811001425
Descripción
Sumario:In the title complex, [Ni(C(7)H(5)O(2))(2)(C(12)H(12)N(2))(2)], the Ni(II) atom lies on a center of inversion and is coordinated in an octa­hedral geometry by two 2-(benzyl­amino)­pyridine (2-BAP) and two 2-formyl­phenolate ligands with the O-atom donors in the equatorial plane and the pyridine N atoms in axial positions. There are hydrogen-bonding inter­actions between the secondary amine H atom and the phenolate O atom, as well as C—H⋯O inter­actions, which result in the dihedral angle between the aromatic phenyl ring of the 2-formyl­phenolate moiety and the pyridine ring being 80.23 (4)°. In the packing, there are both C—H⋯π inter­actions, which link the mol­ecules into chains along the b axis, and offset π–π inter­actions involving both the pyridine and phenyl rings of the 2-BAP ligands [centroid–centroid distances = 4.0100 (8) Å for the pyridine rings and 3.6601 (8) and 4.8561 (8) Å for the phenyl rings].