Cargando…

Bis[2-(benzyl­amino)­pyridine-κN (1)]bis­(2-formyl­phenolato-κ(2) O,O′)nickel(II)

In the title complex, [Ni(C(7)H(5)O(2))(2)(C(12)H(12)N(2))(2)], the Ni(II) atom lies on a center of inversion and is coordinated in an octa­hedral geometry by two 2-(benzyl­amino)­pyridine (2-BAP) and two 2-formyl­phenolate ligands with the O-atom donors in the equatorial plane and the pyridine N at...

Descripción completa

Detalles Bibliográficos
Autores principales: Ayikoé, Kouassi, Butcher, Ray J., Gultneh, Yilma
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051610/
https://www.ncbi.nlm.nih.gov/pubmed/21522871
http://dx.doi.org/10.1107/S1600536811001425
_version_ 1782199519940706304
author Ayikoé, Kouassi
Butcher, Ray J.
Gultneh, Yilma
author_facet Ayikoé, Kouassi
Butcher, Ray J.
Gultneh, Yilma
author_sort Ayikoé, Kouassi
collection PubMed
description In the title complex, [Ni(C(7)H(5)O(2))(2)(C(12)H(12)N(2))(2)], the Ni(II) atom lies on a center of inversion and is coordinated in an octa­hedral geometry by two 2-(benzyl­amino)­pyridine (2-BAP) and two 2-formyl­phenolate ligands with the O-atom donors in the equatorial plane and the pyridine N atoms in axial positions. There are hydrogen-bonding inter­actions between the secondary amine H atom and the phenolate O atom, as well as C—H⋯O inter­actions, which result in the dihedral angle between the aromatic phenyl ring of the 2-formyl­phenolate moiety and the pyridine ring being 80.23 (4)°. In the packing, there are both C—H⋯π inter­actions, which link the mol­ecules into chains along the b axis, and offset π–π inter­actions involving both the pyridine and phenyl rings of the 2-BAP ligands [centroid–centroid distances = 4.0100 (8) Å for the pyridine rings and 3.6601 (8) and 4.8561 (8) Å for the phenyl rings].
format Text
id pubmed-3051610
institution National Center for Biotechnology Information
language English
publishDate 2011
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-30516102011-04-26 Bis[2-(benzyl­amino)­pyridine-κN (1)]bis­(2-formyl­phenolato-κ(2) O,O′)nickel(II) Ayikoé, Kouassi Butcher, Ray J. Gultneh, Yilma Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Ni(C(7)H(5)O(2))(2)(C(12)H(12)N(2))(2)], the Ni(II) atom lies on a center of inversion and is coordinated in an octa­hedral geometry by two 2-(benzyl­amino)­pyridine (2-BAP) and two 2-formyl­phenolate ligands with the O-atom donors in the equatorial plane and the pyridine N atoms in axial positions. There are hydrogen-bonding inter­actions between the secondary amine H atom and the phenolate O atom, as well as C—H⋯O inter­actions, which result in the dihedral angle between the aromatic phenyl ring of the 2-formyl­phenolate moiety and the pyridine ring being 80.23 (4)°. In the packing, there are both C—H⋯π inter­actions, which link the mol­ecules into chains along the b axis, and offset π–π inter­actions involving both the pyridine and phenyl rings of the 2-BAP ligands [centroid–centroid distances = 4.0100 (8) Å for the pyridine rings and 3.6601 (8) and 4.8561 (8) Å for the phenyl rings]. International Union of Crystallography 2011-01-15 /pmc/articles/PMC3051610/ /pubmed/21522871 http://dx.doi.org/10.1107/S1600536811001425 Text en © Ayikoé et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Ayikoé, Kouassi
Butcher, Ray J.
Gultneh, Yilma
Bis[2-(benzyl­amino)­pyridine-κN (1)]bis­(2-formyl­phenolato-κ(2) O,O′)nickel(II)
title Bis[2-(benzyl­amino)­pyridine-κN (1)]bis­(2-formyl­phenolato-κ(2) O,O′)nickel(II)
title_full Bis[2-(benzyl­amino)­pyridine-κN (1)]bis­(2-formyl­phenolato-κ(2) O,O′)nickel(II)
title_fullStr Bis[2-(benzyl­amino)­pyridine-κN (1)]bis­(2-formyl­phenolato-κ(2) O,O′)nickel(II)
title_full_unstemmed Bis[2-(benzyl­amino)­pyridine-κN (1)]bis­(2-formyl­phenolato-κ(2) O,O′)nickel(II)
title_short Bis[2-(benzyl­amino)­pyridine-κN (1)]bis­(2-formyl­phenolato-κ(2) O,O′)nickel(II)
title_sort bis[2-(benzyl­amino)­pyridine-κn (1)]bis­(2-formyl­phenolato-κ(2) o,o′)nickel(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051610/
https://www.ncbi.nlm.nih.gov/pubmed/21522871
http://dx.doi.org/10.1107/S1600536811001425
work_keys_str_mv AT ayikoekouassi bis2benzylaminopyridinekn1bis2formylphenolatok2oonickelii
AT butcherrayj bis2benzylaminopyridinekn1bis2formylphenolatok2oonickelii
AT gultnehyilma bis2benzylaminopyridinekn1bis2formylphenolatok2oonickelii