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Bis[2-(benzylamino)pyridine-κN (1)]bis(2-formylphenolato-κ(2) O,O′)nickel(II)
In the title complex, [Ni(C(7)H(5)O(2))(2)(C(12)H(12)N(2))(2)], the Ni(II) atom lies on a center of inversion and is coordinated in an octahedral geometry by two 2-(benzylamino)pyridine (2-BAP) and two 2-formylphenolate ligands with the O-atom donors in the equatorial plane and the pyridine N at...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051610/ https://www.ncbi.nlm.nih.gov/pubmed/21522871 http://dx.doi.org/10.1107/S1600536811001425 |
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author | Ayikoé, Kouassi Butcher, Ray J. Gultneh, Yilma |
author_facet | Ayikoé, Kouassi Butcher, Ray J. Gultneh, Yilma |
author_sort | Ayikoé, Kouassi |
collection | PubMed |
description | In the title complex, [Ni(C(7)H(5)O(2))(2)(C(12)H(12)N(2))(2)], the Ni(II) atom lies on a center of inversion and is coordinated in an octahedral geometry by two 2-(benzylamino)pyridine (2-BAP) and two 2-formylphenolate ligands with the O-atom donors in the equatorial plane and the pyridine N atoms in axial positions. There are hydrogen-bonding interactions between the secondary amine H atom and the phenolate O atom, as well as C—H⋯O interactions, which result in the dihedral angle between the aromatic phenyl ring of the 2-formylphenolate moiety and the pyridine ring being 80.23 (4)°. In the packing, there are both C—H⋯π interactions, which link the molecules into chains along the b axis, and offset π–π interactions involving both the pyridine and phenyl rings of the 2-BAP ligands [centroid–centroid distances = 4.0100 (8) Å for the pyridine rings and 3.6601 (8) and 4.8561 (8) Å for the phenyl rings]. |
format | Text |
id | pubmed-3051610 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30516102011-04-26 Bis[2-(benzylamino)pyridine-κN (1)]bis(2-formylphenolato-κ(2) O,O′)nickel(II) Ayikoé, Kouassi Butcher, Ray J. Gultneh, Yilma Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Ni(C(7)H(5)O(2))(2)(C(12)H(12)N(2))(2)], the Ni(II) atom lies on a center of inversion and is coordinated in an octahedral geometry by two 2-(benzylamino)pyridine (2-BAP) and two 2-formylphenolate ligands with the O-atom donors in the equatorial plane and the pyridine N atoms in axial positions. There are hydrogen-bonding interactions between the secondary amine H atom and the phenolate O atom, as well as C—H⋯O interactions, which result in the dihedral angle between the aromatic phenyl ring of the 2-formylphenolate moiety and the pyridine ring being 80.23 (4)°. In the packing, there are both C—H⋯π interactions, which link the molecules into chains along the b axis, and offset π–π interactions involving both the pyridine and phenyl rings of the 2-BAP ligands [centroid–centroid distances = 4.0100 (8) Å for the pyridine rings and 3.6601 (8) and 4.8561 (8) Å for the phenyl rings]. International Union of Crystallography 2011-01-15 /pmc/articles/PMC3051610/ /pubmed/21522871 http://dx.doi.org/10.1107/S1600536811001425 Text en © Ayikoé et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Ayikoé, Kouassi Butcher, Ray J. Gultneh, Yilma Bis[2-(benzylamino)pyridine-κN (1)]bis(2-formylphenolato-κ(2) O,O′)nickel(II) |
title | Bis[2-(benzylamino)pyridine-κN
(1)]bis(2-formylphenolato-κ(2)
O,O′)nickel(II) |
title_full | Bis[2-(benzylamino)pyridine-κN
(1)]bis(2-formylphenolato-κ(2)
O,O′)nickel(II) |
title_fullStr | Bis[2-(benzylamino)pyridine-κN
(1)]bis(2-formylphenolato-κ(2)
O,O′)nickel(II) |
title_full_unstemmed | Bis[2-(benzylamino)pyridine-κN
(1)]bis(2-formylphenolato-κ(2)
O,O′)nickel(II) |
title_short | Bis[2-(benzylamino)pyridine-κN
(1)]bis(2-formylphenolato-κ(2)
O,O′)nickel(II) |
title_sort | bis[2-(benzylamino)pyridine-κn
(1)]bis(2-formylphenolato-κ(2)
o,o′)nickel(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051610/ https://www.ncbi.nlm.nih.gov/pubmed/21522871 http://dx.doi.org/10.1107/S1600536811001425 |
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