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Aqua­[bis­(2-ethyl-5-methyl-1H-imidazol-4-yl-κN (3))methane]­oxalatocopper(II) dihydrate

In the title compound, [Cu(C(2)O(4))(C(13)H(20)N(4))(H(2)O)]·2H(2)O, the Cu(II) atom exhibits a distorted square-pyramidal geometry with the two N atoms of the imidazole ligand and the two O atoms of the oxalate ligand forming the basal plane, while the O atom of the coordinated water mol­ecule is i...

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Detalles Bibliográficos
Autores principales: Luo, Yang-Hui, Qian, Xiao-Min, Gao, Ge, Li, Jin-Feng, Mao, Shu-Lin
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051616/
https://www.ncbi.nlm.nih.gov/pubmed/21522849
http://dx.doi.org/10.1107/S1600536811001012
Descripción
Sumario:In the title compound, [Cu(C(2)O(4))(C(13)H(20)N(4))(H(2)O)]·2H(2)O, the Cu(II) atom exhibits a distorted square-pyramidal geometry with the two N atoms of the imidazole ligand and the two O atoms of the oxalate ligand forming the basal plane, while the O atom of the coordinated water mol­ecule is in an apical position. The Cu(II) atom is shifted 0.232 (2) Å out of the basal plane toward the water mol­ecule. The asymmetric unit is completed by two solvent water mol­ecules. These water mol­ecules participate in the formation of an intricate three-dimensionnal network of hydrogen bonds involving the coordinated water mol­ecule and the NH groups.