Dimeth­yl(4′-pyridyl-2,2′:6′,2′′-terpyridine-κ(3) N (1),N (1′),N (1′′))bis(thio­cyanato-κN)tin(IV)

The Sn atom in the title compound, [Sn(CH(3))(2)(NCS)(2)(C(20)H(14)N(4))], is N,N′,N′′-chelated by the terpyridine part of the N-heterocycle. The Sn atom exists in a trans-C(2)SnN(5) penta­gonal–bipyramidal geometry [C—Sn—C = 173.66 (8)°] with the methyl groups in axial and the N atoms in equatorial...

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Detalles Bibliográficos
Autores principales: Najafi, Ezzatollah, Amini, Mostafa M., Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051620/
https://www.ncbi.nlm.nih.gov/pubmed/21522874
http://dx.doi.org/10.1107/S1600536811001309
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author Najafi, Ezzatollah
Amini, Mostafa M.
Ng, Seik Weng
author_facet Najafi, Ezzatollah
Amini, Mostafa M.
Ng, Seik Weng
author_sort Najafi, Ezzatollah
collection PubMed
description The Sn atom in the title compound, [Sn(CH(3))(2)(NCS)(2)(C(20)H(14)N(4))], is N,N′,N′′-chelated by the terpyridine part of the N-heterocycle. The Sn atom exists in a trans-C(2)SnN(5) penta­gonal–bipyramidal geometry [C—Sn—C = 173.66 (8)°] with the methyl groups in axial and the N atoms in equatorial positions.
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spelling pubmed-30516202011-04-26 Dimeth­yl(4′-pyridyl-2,2′:6′,2′′-terpyridine-κ(3) N (1),N (1′),N (1′′))bis(thio­cyanato-κN)tin(IV) Najafi, Ezzatollah Amini, Mostafa M. Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Sn atom in the title compound, [Sn(CH(3))(2)(NCS)(2)(C(20)H(14)N(4))], is N,N′,N′′-chelated by the terpyridine part of the N-heterocycle. The Sn atom exists in a trans-C(2)SnN(5) penta­gonal–bipyramidal geometry [C—Sn—C = 173.66 (8)°] with the methyl groups in axial and the N atoms in equatorial positions. International Union of Crystallography 2011-01-15 /pmc/articles/PMC3051620/ /pubmed/21522874 http://dx.doi.org/10.1107/S1600536811001309 Text en © Najafi et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Najafi, Ezzatollah
Amini, Mostafa M.
Ng, Seik Weng
Dimeth­yl(4′-pyridyl-2,2′:6′,2′′-terpyridine-κ(3) N (1),N (1′),N (1′′))bis(thio­cyanato-κN)tin(IV)
title Dimeth­yl(4′-pyridyl-2,2′:6′,2′′-terpyridine-κ(3) N (1),N (1′),N (1′′))bis(thio­cyanato-κN)tin(IV)
title_full Dimeth­yl(4′-pyridyl-2,2′:6′,2′′-terpyridine-κ(3) N (1),N (1′),N (1′′))bis(thio­cyanato-κN)tin(IV)
title_fullStr Dimeth­yl(4′-pyridyl-2,2′:6′,2′′-terpyridine-κ(3) N (1),N (1′),N (1′′))bis(thio­cyanato-κN)tin(IV)
title_full_unstemmed Dimeth­yl(4′-pyridyl-2,2′:6′,2′′-terpyridine-κ(3) N (1),N (1′),N (1′′))bis(thio­cyanato-κN)tin(IV)
title_short Dimeth­yl(4′-pyridyl-2,2′:6′,2′′-terpyridine-κ(3) N (1),N (1′),N (1′′))bis(thio­cyanato-κN)tin(IV)
title_sort dimeth­yl(4′-pyridyl-2,2′:6′,2′′-terpyridine-κ(3) n (1),n (1′),n (1′′))bis(thio­cyanato-κn)tin(iv)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051620/
https://www.ncbi.nlm.nih.gov/pubmed/21522874
http://dx.doi.org/10.1107/S1600536811001309
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AT ngseikweng dimethyl4pyridyl2262terpyridinek3n1n1n1bisthiocyanatokntiniv

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