Tetra­yttrium(III) tris­ulfide disilicate

Tetra­yttrium(III) tris­ulfide disilicate, Y(4)S(3)(Si(2)O(7)), crystallizes in the Sm(4)S(3)(Si(2)O(7)) structure type. The structure consists of isolated (Si(2)O(7))(6−) units (2mm. symmetry) and two crystallo­graphically independent Y(3+) cations bridged by one S and one O atom. The first Y atom...

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Detalles Bibliográficos
Autores principales: Koscielski, Lukasz A., Ibers, James A.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Inorganic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051622/
https://www.ncbi.nlm.nih.gov/pubmed/21522813
http://dx.doi.org/10.1107/S1600536810054607
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author Koscielski, Lukasz A.
Ibers, James A.
author_facet Koscielski, Lukasz A.
Ibers, James A.
author_sort Koscielski, Lukasz A.
collection PubMed
description Tetra­yttrium(III) tris­ulfide disilicate, Y(4)S(3)(Si(2)O(7)), crystallizes in the Sm(4)S(3)(Si(2)O(7)) structure type. The structure consists of isolated (Si(2)O(7))(6−) units (2mm. symmetry) and two crystallo­graphically independent Y(3+) cations bridged by one S and one O atom. The first Y atom (site symmetry .m.) is coordinated by three O atoms and three S atoms in a trigonal–prismatic arrangement whereas the second Y atom (site symmetry ..2) is coordinated by six O atoms and three S atoms in a tricapped trigonal–prismatic arrangement.
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spelling pubmed-30516222011-04-26 Tetra­yttrium(III) tris­ulfide disilicate Koscielski, Lukasz A. Ibers, James A. Acta Crystallogr Sect E Struct Rep Online Inorganic Papers Tetra­yttrium(III) tris­ulfide disilicate, Y(4)S(3)(Si(2)O(7)), crystallizes in the Sm(4)S(3)(Si(2)O(7)) structure type. The structure consists of isolated (Si(2)O(7))(6−) units (2mm. symmetry) and two crystallo­graphically independent Y(3+) cations bridged by one S and one O atom. The first Y atom (site symmetry .m.) is coordinated by three O atoms and three S atoms in a trigonal–prismatic arrangement whereas the second Y atom (site symmetry ..2) is coordinated by six O atoms and three S atoms in a tricapped trigonal–prismatic arrangement. International Union of Crystallography 2011-01-15 /pmc/articles/PMC3051622/ /pubmed/21522813 http://dx.doi.org/10.1107/S1600536810054607 Text en © Koscielski and Ibers 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Inorganic Papers
Koscielski, Lukasz A.
Ibers, James A.
Tetra­yttrium(III) tris­ulfide disilicate
title Tetra­yttrium(III) tris­ulfide disilicate
title_full Tetra­yttrium(III) tris­ulfide disilicate
title_fullStr Tetra­yttrium(III) tris­ulfide disilicate
title_full_unstemmed Tetra­yttrium(III) tris­ulfide disilicate
title_short Tetra­yttrium(III) tris­ulfide disilicate
title_sort tetra­yttrium(iii) tris­ulfide disilicate
topic Inorganic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051622/
https://www.ncbi.nlm.nih.gov/pubmed/21522813
http://dx.doi.org/10.1107/S1600536810054607
work_keys_str_mv AT koscielskilukasza tetrayttriumiiitrisulfidedisilicate
AT ibersjamesa tetrayttriumiiitrisulfidedisilicate

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