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1,1′-[4-(2,4-Dichloro­phen­yl)-2,6-di­methyl-1,4-di­hydro­pyridine-3,5-di­yl]diethanone

In the title compound, C(17)H(17)Cl(2)NO(2), the central 1,4-dihydro­pyridine ring adopts a flattened-boat conformation. The ethanone substituents of the dihydro­pyridine ring at positions 3 and 5 have synperiplanar (cis) or anti­periplanar (trans) conformations with respect to the adjacent C=C bond...

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Detalles Bibliográficos
Autores principales: Sundar, J. Kalyana, Reddy, B. Palakshi, Vijayakumar, V., Natarajan, S., Suresh, J., Lakshman, P. L. Nilantha
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051630/
https://www.ncbi.nlm.nih.gov/pubmed/21523057
http://dx.doi.org/10.1107/S1600536810052839
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author Sundar, J. Kalyana
Reddy, B. Palakshi
Vijayakumar, V.
Natarajan, S.
Suresh, J.
Lakshman, P. L. Nilantha
author_facet Sundar, J. Kalyana
Reddy, B. Palakshi
Vijayakumar, V.
Natarajan, S.
Suresh, J.
Lakshman, P. L. Nilantha
author_sort Sundar, J. Kalyana
collection PubMed
description In the title compound, C(17)H(17)Cl(2)NO(2), the central 1,4-dihydro­pyridine ring adopts a flattened-boat conformation. The ethanone substituents of the dihydro­pyridine ring at positions 3 and 5 have synperiplanar (cis) or anti­periplanar (trans) conformations with respect to the adjacent C=C bonds in the dihydro­pyridine ring. The 2,4-dichloro­phenyl ring is almost planar [r.m.s. deviation = 0.0045 (1) Å] and almost perpendicular [89.27 (3)°] to the mean plane of the dihydro­pyridine ring. In the crystal, an N—H⋯O hydrogen bond links mol­ecules into a zigzag chain along the ac diagonal. C—H⋯Cl contacts form centrosymmetric dimers and additional weak C—H⋯O contacts further consolidate the packing.
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spelling pubmed-30516302011-04-26 1,1′-[4-(2,4-Dichloro­phen­yl)-2,6-di­methyl-1,4-di­hydro­pyridine-3,5-di­yl]diethanone Sundar, J. Kalyana Reddy, B. Palakshi Vijayakumar, V. Natarajan, S. Suresh, J. Lakshman, P. L. Nilantha Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(17)H(17)Cl(2)NO(2), the central 1,4-dihydro­pyridine ring adopts a flattened-boat conformation. The ethanone substituents of the dihydro­pyridine ring at positions 3 and 5 have synperiplanar (cis) or anti­periplanar (trans) conformations with respect to the adjacent C=C bonds in the dihydro­pyridine ring. The 2,4-dichloro­phenyl ring is almost planar [r.m.s. deviation = 0.0045 (1) Å] and almost perpendicular [89.27 (3)°] to the mean plane of the dihydro­pyridine ring. In the crystal, an N—H⋯O hydrogen bond links mol­ecules into a zigzag chain along the ac diagonal. C—H⋯Cl contacts form centrosymmetric dimers and additional weak C—H⋯O contacts further consolidate the packing. International Union of Crystallography 2011-01-15 /pmc/articles/PMC3051630/ /pubmed/21523057 http://dx.doi.org/10.1107/S1600536810052839 Text en © Sundar et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Sundar, J. Kalyana
Reddy, B. Palakshi
Vijayakumar, V.
Natarajan, S.
Suresh, J.
Lakshman, P. L. Nilantha
1,1′-[4-(2,4-Dichloro­phen­yl)-2,6-di­methyl-1,4-di­hydro­pyridine-3,5-di­yl]diethanone
title 1,1′-[4-(2,4-Dichloro­phen­yl)-2,6-di­methyl-1,4-di­hydro­pyridine-3,5-di­yl]diethanone
title_full 1,1′-[4-(2,4-Dichloro­phen­yl)-2,6-di­methyl-1,4-di­hydro­pyridine-3,5-di­yl]diethanone
title_fullStr 1,1′-[4-(2,4-Dichloro­phen­yl)-2,6-di­methyl-1,4-di­hydro­pyridine-3,5-di­yl]diethanone
title_full_unstemmed 1,1′-[4-(2,4-Dichloro­phen­yl)-2,6-di­methyl-1,4-di­hydro­pyridine-3,5-di­yl]diethanone
title_short 1,1′-[4-(2,4-Dichloro­phen­yl)-2,6-di­methyl-1,4-di­hydro­pyridine-3,5-di­yl]diethanone
title_sort 1,1′-[4-(2,4-dichloro­phen­yl)-2,6-di­methyl-1,4-di­hydro­pyridine-3,5-di­yl]diethanone
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051630/
https://www.ncbi.nlm.nih.gov/pubmed/21523057
http://dx.doi.org/10.1107/S1600536810052839
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