Benzene-1,3-diammonium bis­(pyridine-2,6-dicarboxyl­ato)nickelate(II) penta­hydrate

In the title compound, (C(6)H(10)N(2))[Ni(C(7)H(3)NO(4))(2)]·5H(2)O, the Ni(II) ion is six-coordinated by two N and four O atoms from two pyridine-2,6-dicarboxyl­ate ligands in a distorted octa­hedral fashion. The crystal packing is stabilized by inter­molecular O—H⋯O and N—H⋯O and weak C—H⋯O hydrog...

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Detalles Bibliográficos
Autores principales: Pasdar, Hoda, Sadat Kashani, Saghi, Aghabozorg, Hossein, Notash, Behrouz
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051631/
https://www.ncbi.nlm.nih.gov/pubmed/21522862
http://dx.doi.org/10.1107/S1600536810054371
Descripción
Sumario:In the title compound, (C(6)H(10)N(2))[Ni(C(7)H(3)NO(4))(2)]·5H(2)O, the Ni(II) ion is six-coordinated by two N and four O atoms from two pyridine-2,6-dicarboxyl­ate ligands in a distorted octa­hedral fashion. The crystal packing is stabilized by inter­molecular O—H⋯O and N—H⋯O and weak C—H⋯O hydrogen bonds and π–π inter­actions [centroid–centroid distances = 3.4669 (19) and 3.764 (2) Å].

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