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{2,6-Bis[(2,6-diphenylphosphanyl)oxy]-4-fluorophenyl-κ(3) P,C (1),P′}(6-methyl-2,2,4-trioxo-3,4-dihydro-1,2,3-oxathiazin-3-ido-κN)palladium(II)
The title acesulfamate complex, [Pd(C(30)H(22)FO(2)P(2))(C(4)H(4)NO(4)S)], contains a four-coordinate Pd(II) ion with the expected, although relatively distorted, square-planar geometry where the four L—Pd—L angles range from 79.58 (8) to 102.47 (7)°. The acesulfamate ligand is N-bound to Pd [Pd—N =...
| Autores principales: | , , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2011
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051636/ https://www.ncbi.nlm.nih.gov/pubmed/21522930 http://dx.doi.org/10.1107/S1600536811002911 |
| _version_ | 1782199526130450432 |
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| author | Wicker, Benjamin F. Seaman, Rachel Hoffman, Norris W. Davis, James H. Sykora, Richard E. |
| author_facet | Wicker, Benjamin F. Seaman, Rachel Hoffman, Norris W. Davis, James H. Sykora, Richard E. |
| author_sort | Wicker, Benjamin F. |
| collection | PubMed |
| description | The title acesulfamate complex, [Pd(C(30)H(22)FO(2)P(2))(C(4)H(4)NO(4)S)], contains a four-coordinate Pd(II) ion with the expected, although relatively distorted, square-planar geometry where the four L—Pd—L angles range from 79.58 (8) to 102.47 (7)°. The acesulfamate ligand is N-bound to Pd [Pd—N = 2.127 (2) Å] with a dihedral angle of 76.35 (6)° relative to the square plane. Relatively long phenyl–acesulfamate C—H⋯O and phenyl–fluorine C—H⋯F interactions consolidate the crystal packing. |
| format | Text |
| id | pubmed-3051636 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-30516362011-04-26 {2,6-Bis[(2,6-diphenylphosphanyl)oxy]-4-fluorophenyl-κ(3) P,C (1),P′}(6-methyl-2,2,4-trioxo-3,4-dihydro-1,2,3-oxathiazin-3-ido-κN)palladium(II) Wicker, Benjamin F. Seaman, Rachel Hoffman, Norris W. Davis, James H. Sykora, Richard E. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title acesulfamate complex, [Pd(C(30)H(22)FO(2)P(2))(C(4)H(4)NO(4)S)], contains a four-coordinate Pd(II) ion with the expected, although relatively distorted, square-planar geometry where the four L—Pd—L angles range from 79.58 (8) to 102.47 (7)°. The acesulfamate ligand is N-bound to Pd [Pd—N = 2.127 (2) Å] with a dihedral angle of 76.35 (6)° relative to the square plane. Relatively long phenyl–acesulfamate C—H⋯O and phenyl–fluorine C—H⋯F interactions consolidate the crystal packing. International Union of Crystallography 2011-01-29 /pmc/articles/PMC3051636/ /pubmed/21522930 http://dx.doi.org/10.1107/S1600536811002911 Text en © Wicker et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Wicker, Benjamin F. Seaman, Rachel Hoffman, Norris W. Davis, James H. Sykora, Richard E. {2,6-Bis[(2,6-diphenylphosphanyl)oxy]-4-fluorophenyl-κ(3) P,C (1),P′}(6-methyl-2,2,4-trioxo-3,4-dihydro-1,2,3-oxathiazin-3-ido-κN)palladium(II) |
| title | {2,6-Bis[(2,6-diphenylphosphanyl)oxy]-4-fluorophenyl-κ(3)
P,C
(1),P′}(6-methyl-2,2,4-trioxo-3,4-dihydro-1,2,3-oxathiazin-3-ido-κN)palladium(II) |
| title_full | {2,6-Bis[(2,6-diphenylphosphanyl)oxy]-4-fluorophenyl-κ(3)
P,C
(1),P′}(6-methyl-2,2,4-trioxo-3,4-dihydro-1,2,3-oxathiazin-3-ido-κN)palladium(II) |
| title_fullStr | {2,6-Bis[(2,6-diphenylphosphanyl)oxy]-4-fluorophenyl-κ(3)
P,C
(1),P′}(6-methyl-2,2,4-trioxo-3,4-dihydro-1,2,3-oxathiazin-3-ido-κN)palladium(II) |
| title_full_unstemmed | {2,6-Bis[(2,6-diphenylphosphanyl)oxy]-4-fluorophenyl-κ(3)
P,C
(1),P′}(6-methyl-2,2,4-trioxo-3,4-dihydro-1,2,3-oxathiazin-3-ido-κN)palladium(II) |
| title_short | {2,6-Bis[(2,6-diphenylphosphanyl)oxy]-4-fluorophenyl-κ(3)
P,C
(1),P′}(6-methyl-2,2,4-trioxo-3,4-dihydro-1,2,3-oxathiazin-3-ido-κN)palladium(II) |
| title_sort | {2,6-bis[(2,6-diphenylphosphanyl)oxy]-4-fluorophenyl-κ(3)
p,c
(1),p′}(6-methyl-2,2,4-trioxo-3,4-dihydro-1,2,3-oxathiazin-3-ido-κn)palladium(ii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051636/ https://www.ncbi.nlm.nih.gov/pubmed/21522930 http://dx.doi.org/10.1107/S1600536811002911 |
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