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Bis[2-(4-hy­droxy­phen­yl)acetato-κO]bis­(1,10-phenanthroline-κ(2) N,N′)cadmium penta­hydrate

In the title compound, [Cd(C(8)H(7)O(3))(2)(C(12)H(8)N(2))(2)]·5H(2)O, the Cd(II) ion is six-coordinated by two carboxylate O atoms of monodentate 2-(4-hy­droxy­phen­yl)acetate ligands and by four N atoms from two chelating 1,10-phenantroline ligands in a distorted trigonal–prismatic geometry. O—H⋯O...

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Detalles Bibliográficos
Autor principal: Yu, Yu-Ye
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051641/
https://www.ncbi.nlm.nih.gov/pubmed/21522901
http://dx.doi.org/10.1107/S1600536811001747
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author Yu, Yu-Ye
author_facet Yu, Yu-Ye
author_sort Yu, Yu-Ye
collection PubMed
description In the title compound, [Cd(C(8)H(7)O(3))(2)(C(12)H(8)N(2))(2)]·5H(2)O, the Cd(II) ion is six-coordinated by two carboxylate O atoms of monodentate 2-(4-hy­droxy­phen­yl)acetate ligands and by four N atoms from two chelating 1,10-phenantroline ligands in a distorted trigonal–prismatic geometry. O—H⋯O hydrogen bonds between water mol­ecules and the complex mol­ecules result in the formation of a three-dimensional network. Four water mol­ecules act as single acceptors and double donors while the fifth water mol­ecule is involved as a single acceptor and single donor in an O—H⋯O inter­action and as a donor in an O—H⋯π inter­action.
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spelling pubmed-30516412011-04-26 Bis[2-(4-hy­droxy­phen­yl)acetato-κO]bis­(1,10-phenanthroline-κ(2) N,N′)cadmium penta­hydrate Yu, Yu-Ye Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cd(C(8)H(7)O(3))(2)(C(12)H(8)N(2))(2)]·5H(2)O, the Cd(II) ion is six-coordinated by two carboxylate O atoms of monodentate 2-(4-hy­droxy­phen­yl)acetate ligands and by four N atoms from two chelating 1,10-phenantroline ligands in a distorted trigonal–prismatic geometry. O—H⋯O hydrogen bonds between water mol­ecules and the complex mol­ecules result in the formation of a three-dimensional network. Four water mol­ecules act as single acceptors and double donors while the fifth water mol­ecule is involved as a single acceptor and single donor in an O—H⋯O inter­action and as a donor in an O—H⋯π inter­action. International Union of Crystallography 2011-01-22 /pmc/articles/PMC3051641/ /pubmed/21522901 http://dx.doi.org/10.1107/S1600536811001747 Text en © Yu-Ye Yu 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Yu, Yu-Ye
Bis[2-(4-hy­droxy­phen­yl)acetato-κO]bis­(1,10-phenanthroline-κ(2) N,N′)cadmium penta­hydrate
title Bis[2-(4-hy­droxy­phen­yl)acetato-κO]bis­(1,10-phenanthroline-κ(2) N,N′)cadmium penta­hydrate
title_full Bis[2-(4-hy­droxy­phen­yl)acetato-κO]bis­(1,10-phenanthroline-κ(2) N,N′)cadmium penta­hydrate
title_fullStr Bis[2-(4-hy­droxy­phen­yl)acetato-κO]bis­(1,10-phenanthroline-κ(2) N,N′)cadmium penta­hydrate
title_full_unstemmed Bis[2-(4-hy­droxy­phen­yl)acetato-κO]bis­(1,10-phenanthroline-κ(2) N,N′)cadmium penta­hydrate
title_short Bis[2-(4-hy­droxy­phen­yl)acetato-κO]bis­(1,10-phenanthroline-κ(2) N,N′)cadmium penta­hydrate
title_sort bis[2-(4-hy­droxy­phen­yl)acetato-κo]bis­(1,10-phenanthroline-κ(2) n,n′)cadmium penta­hydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051641/
https://www.ncbi.nlm.nih.gov/pubmed/21522901
http://dx.doi.org/10.1107/S1600536811001747
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