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Bis[2-(4-hydroxyphenyl)acetato-κO]bis(1,10-phenanthroline-κ(2) N,N′)cadmium pentahydrate
In the title compound, [Cd(C(8)H(7)O(3))(2)(C(12)H(8)N(2))(2)]·5H(2)O, the Cd(II) ion is six-coordinated by two carboxylate O atoms of monodentate 2-(4-hydroxyphenyl)acetate ligands and by four N atoms from two chelating 1,10-phenantroline ligands in a distorted trigonal–prismatic geometry. O—H⋯O...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2011
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051641/ https://www.ncbi.nlm.nih.gov/pubmed/21522901 http://dx.doi.org/10.1107/S1600536811001747 |
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author | Yu, Yu-Ye |
author_facet | Yu, Yu-Ye |
author_sort | Yu, Yu-Ye |
collection | PubMed |
description | In the title compound, [Cd(C(8)H(7)O(3))(2)(C(12)H(8)N(2))(2)]·5H(2)O, the Cd(II) ion is six-coordinated by two carboxylate O atoms of monodentate 2-(4-hydroxyphenyl)acetate ligands and by four N atoms from two chelating 1,10-phenantroline ligands in a distorted trigonal–prismatic geometry. O—H⋯O hydrogen bonds between water molecules and the complex molecules result in the formation of a three-dimensional network. Four water molecules act as single acceptors and double donors while the fifth water molecule is involved as a single acceptor and single donor in an O—H⋯O interaction and as a donor in an O—H⋯π interaction. |
format | Text |
id | pubmed-3051641 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30516412011-04-26 Bis[2-(4-hydroxyphenyl)acetato-κO]bis(1,10-phenanthroline-κ(2) N,N′)cadmium pentahydrate Yu, Yu-Ye Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cd(C(8)H(7)O(3))(2)(C(12)H(8)N(2))(2)]·5H(2)O, the Cd(II) ion is six-coordinated by two carboxylate O atoms of monodentate 2-(4-hydroxyphenyl)acetate ligands and by four N atoms from two chelating 1,10-phenantroline ligands in a distorted trigonal–prismatic geometry. O—H⋯O hydrogen bonds between water molecules and the complex molecules result in the formation of a three-dimensional network. Four water molecules act as single acceptors and double donors while the fifth water molecule is involved as a single acceptor and single donor in an O—H⋯O interaction and as a donor in an O—H⋯π interaction. International Union of Crystallography 2011-01-22 /pmc/articles/PMC3051641/ /pubmed/21522901 http://dx.doi.org/10.1107/S1600536811001747 Text en © Yu-Ye Yu 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Yu, Yu-Ye Bis[2-(4-hydroxyphenyl)acetato-κO]bis(1,10-phenanthroline-κ(2) N,N′)cadmium pentahydrate |
title | Bis[2-(4-hydroxyphenyl)acetato-κO]bis(1,10-phenanthroline-κ(2)
N,N′)cadmium pentahydrate |
title_full | Bis[2-(4-hydroxyphenyl)acetato-κO]bis(1,10-phenanthroline-κ(2)
N,N′)cadmium pentahydrate |
title_fullStr | Bis[2-(4-hydroxyphenyl)acetato-κO]bis(1,10-phenanthroline-κ(2)
N,N′)cadmium pentahydrate |
title_full_unstemmed | Bis[2-(4-hydroxyphenyl)acetato-κO]bis(1,10-phenanthroline-κ(2)
N,N′)cadmium pentahydrate |
title_short | Bis[2-(4-hydroxyphenyl)acetato-κO]bis(1,10-phenanthroline-κ(2)
N,N′)cadmium pentahydrate |
title_sort | bis[2-(4-hydroxyphenyl)acetato-κo]bis(1,10-phenanthroline-κ(2)
n,n′)cadmium pentahydrate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051641/ https://www.ncbi.nlm.nih.gov/pubmed/21522901 http://dx.doi.org/10.1107/S1600536811001747 |
work_keys_str_mv | AT yuyuye bis24hydroxyphenylacetatokobis110phenanthrolinek2nncadmiumpentahydrate |