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Methyl 2-{2-[(E)-(2-hydroxy-3-methoxybenzylidene)amino]ethylamino}cyclopentene-1-carbodithioate
In the title Schiff base compound, C(17)H(22)N(2)O(2)S(2), which adopts an E configuration with respect to the imine C=N double bond, the C=N and N—C bond distances are 1.2789 (16) and 1.4546 (16) Å, respectively. In the molecule there are intramolecular O—H⋯N and N—H⋯S hydrogen bonds, and the CH=...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051642/ https://www.ncbi.nlm.nih.gov/pubmed/21523183 http://dx.doi.org/10.1107/S1600536811002972 |
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author | Menati, Saeid Kakanejadi, Ali Taeb, Abbas Bruno, Giuseppe Amiri Rudbari, Hadi |
author_facet | Menati, Saeid Kakanejadi, Ali Taeb, Abbas Bruno, Giuseppe Amiri Rudbari, Hadi |
author_sort | Menati, Saeid |
collection | PubMed |
description | In the title Schiff base compound, C(17)H(22)N(2)O(2)S(2), which adopts an E configuration with respect to the imine C=N double bond, the C=N and N—C bond distances are 1.2789 (16) and 1.4546 (16) Å, respectively. In the molecule there are intramolecular O—H⋯N and N—H⋯S hydrogen bonds, and the CH=N—C substituent is almost coplanar with the benzene ring [C—N—C—C torsion angle = −178.80 (11)°]. The crystal packing is stabilized by intermolecular C—H⋯O and C—H⋯π interactions involving the aromatic ring. |
format | Text |
id | pubmed-3051642 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30516422011-04-26 Methyl 2-{2-[(E)-(2-hydroxy-3-methoxybenzylidene)amino]ethylamino}cyclopentene-1-carbodithioate Menati, Saeid Kakanejadi, Ali Taeb, Abbas Bruno, Giuseppe Amiri Rudbari, Hadi Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title Schiff base compound, C(17)H(22)N(2)O(2)S(2), which adopts an E configuration with respect to the imine C=N double bond, the C=N and N—C bond distances are 1.2789 (16) and 1.4546 (16) Å, respectively. In the molecule there are intramolecular O—H⋯N and N—H⋯S hydrogen bonds, and the CH=N—C substituent is almost coplanar with the benzene ring [C—N—C—C torsion angle = −178.80 (11)°]. The crystal packing is stabilized by intermolecular C—H⋯O and C—H⋯π interactions involving the aromatic ring. International Union of Crystallography 2011-01-29 /pmc/articles/PMC3051642/ /pubmed/21523183 http://dx.doi.org/10.1107/S1600536811002972 Text en © Menati et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Menati, Saeid Kakanejadi, Ali Taeb, Abbas Bruno, Giuseppe Amiri Rudbari, Hadi Methyl 2-{2-[(E)-(2-hydroxy-3-methoxybenzylidene)amino]ethylamino}cyclopentene-1-carbodithioate |
title | Methyl 2-{2-[(E)-(2-hydroxy-3-methoxybenzylidene)amino]ethylamino}cyclopentene-1-carbodithioate |
title_full | Methyl 2-{2-[(E)-(2-hydroxy-3-methoxybenzylidene)amino]ethylamino}cyclopentene-1-carbodithioate |
title_fullStr | Methyl 2-{2-[(E)-(2-hydroxy-3-methoxybenzylidene)amino]ethylamino}cyclopentene-1-carbodithioate |
title_full_unstemmed | Methyl 2-{2-[(E)-(2-hydroxy-3-methoxybenzylidene)amino]ethylamino}cyclopentene-1-carbodithioate |
title_short | Methyl 2-{2-[(E)-(2-hydroxy-3-methoxybenzylidene)amino]ethylamino}cyclopentene-1-carbodithioate |
title_sort | methyl 2-{2-[(e)-(2-hydroxy-3-methoxybenzylidene)amino]ethylamino}cyclopentene-1-carbodithioate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051642/ https://www.ncbi.nlm.nih.gov/pubmed/21523183 http://dx.doi.org/10.1107/S1600536811002972 |
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