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Methyl 2-{2-[(E)-(2-hy­droxy-3-meth­oxy­benzyl­idene)amino]­ethyl­amino}­cyclo­pentene-1-carbodithio­ate

In the title Schiff base compound, C(17)H(22)N(2)O(2)S(2), which adopts an E configuration with respect to the imine C=N double bond, the C=N and N—C bond distances are 1.2789 (16) and 1.4546 (16) Å, respectively. In the mol­ecule there are intra­molecular O—H⋯N and N—H⋯S hydrogen bonds, and the CH=...

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Autores principales: Menati, Saeid, Kakanejadi, Ali, Taeb, Abbas, Bruno, Giuseppe, Amiri Rudbari, Hadi
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051642/
https://www.ncbi.nlm.nih.gov/pubmed/21523183
http://dx.doi.org/10.1107/S1600536811002972
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author Menati, Saeid
Kakanejadi, Ali
Taeb, Abbas
Bruno, Giuseppe
Amiri Rudbari, Hadi
author_facet Menati, Saeid
Kakanejadi, Ali
Taeb, Abbas
Bruno, Giuseppe
Amiri Rudbari, Hadi
author_sort Menati, Saeid
collection PubMed
description In the title Schiff base compound, C(17)H(22)N(2)O(2)S(2), which adopts an E configuration with respect to the imine C=N double bond, the C=N and N—C bond distances are 1.2789 (16) and 1.4546 (16) Å, respectively. In the mol­ecule there are intra­molecular O—H⋯N and N—H⋯S hydrogen bonds, and the CH=N—C substituent is almost coplanar with the benzene ring [C—N—C—C torsion angle = −178.80 (11)°]. The crystal packing is stabilized by inter­molecular C—H⋯O and C—H⋯π inter­actions involving the aromatic ring.
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spelling pubmed-30516422011-04-26 Methyl 2-{2-[(E)-(2-hy­droxy-3-meth­oxy­benzyl­idene)amino]­ethyl­amino}­cyclo­pentene-1-carbodithio­ate Menati, Saeid Kakanejadi, Ali Taeb, Abbas Bruno, Giuseppe Amiri Rudbari, Hadi Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title Schiff base compound, C(17)H(22)N(2)O(2)S(2), which adopts an E configuration with respect to the imine C=N double bond, the C=N and N—C bond distances are 1.2789 (16) and 1.4546 (16) Å, respectively. In the mol­ecule there are intra­molecular O—H⋯N and N—H⋯S hydrogen bonds, and the CH=N—C substituent is almost coplanar with the benzene ring [C—N—C—C torsion angle = −178.80 (11)°]. The crystal packing is stabilized by inter­molecular C—H⋯O and C—H⋯π inter­actions involving the aromatic ring. International Union of Crystallography 2011-01-29 /pmc/articles/PMC3051642/ /pubmed/21523183 http://dx.doi.org/10.1107/S1600536811002972 Text en © Menati et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Menati, Saeid
Kakanejadi, Ali
Taeb, Abbas
Bruno, Giuseppe
Amiri Rudbari, Hadi
Methyl 2-{2-[(E)-(2-hy­droxy-3-meth­oxy­benzyl­idene)amino]­ethyl­amino}­cyclo­pentene-1-carbodithio­ate
title Methyl 2-{2-[(E)-(2-hy­droxy-3-meth­oxy­benzyl­idene)amino]­ethyl­amino}­cyclo­pentene-1-carbodithio­ate
title_full Methyl 2-{2-[(E)-(2-hy­droxy-3-meth­oxy­benzyl­idene)amino]­ethyl­amino}­cyclo­pentene-1-carbodithio­ate
title_fullStr Methyl 2-{2-[(E)-(2-hy­droxy-3-meth­oxy­benzyl­idene)amino]­ethyl­amino}­cyclo­pentene-1-carbodithio­ate
title_full_unstemmed Methyl 2-{2-[(E)-(2-hy­droxy-3-meth­oxy­benzyl­idene)amino]­ethyl­amino}­cyclo­pentene-1-carbodithio­ate
title_short Methyl 2-{2-[(E)-(2-hy­droxy-3-meth­oxy­benzyl­idene)amino]­ethyl­amino}­cyclo­pentene-1-carbodithio­ate
title_sort methyl 2-{2-[(e)-(2-hy­droxy-3-meth­oxy­benzyl­idene)amino]­ethyl­amino}­cyclo­pentene-1-carbodithio­ate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051642/
https://www.ncbi.nlm.nih.gov/pubmed/21523183
http://dx.doi.org/10.1107/S1600536811002972
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