{1-[(2-Oxidonaphthalen-1-yl)methylidene]thiosemicarbazidato-κ(3) N (1),O,S}diphenyl­tin(IV)

The asymmetric unit of the title compound, [Sn(C(6)H(5))(2)(C(12)H(9)N(3)OS)], contains two independent mol­ecules with almost identical configurations. In each mol­ecule, the Sn(IV) atom is coordinated by O, N and S atoms from a (2-oxido-1-naph­thaldehyde)­thio­semicarbazonato ligand and two C atom...

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Detalles Bibliográficos
Autores principales: Cui, Jichun, Ruan, Hong, Qiao, Yanling, Yin, Handong
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051660/
https://www.ncbi.nlm.nih.gov/pubmed/21522829
http://dx.doi.org/10.1107/S1600536810054024
Descripción
Sumario:The asymmetric unit of the title compound, [Sn(C(6)H(5))(2)(C(12)H(9)N(3)OS)], contains two independent mol­ecules with almost identical configurations. In each mol­ecule, the Sn(IV) atom is coordinated by O, N and S atoms from a (2-oxido-1-naph­thaldehyde)­thio­semicarbazonato ligand and two C atoms from phenyl rings in a distorted trigonal–bipyramidal geometry. Weak inter­molecular N—H⋯O and N—H⋯S hydrogen bonds link four mol­ecules into a centrosymmetric tetra­mer. The crystal packing exhibits short inter­molecular S⋯S contacts of 3.335 (3) Å.

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