{1-[(2-Oxidonaphthalen-1-yl)methylidene]thiosemicarbazidato-κ(3) N (1),O,S}diphenyl­tin(IV)

The asymmetric unit of the title compound, [Sn(C(6)H(5))(2)(C(12)H(9)N(3)OS)], contains two independent mol­ecules with almost identical configurations. In each mol­ecule, the Sn(IV) atom is coordinated by O, N and S atoms from a (2-oxido-1-naph­thaldehyde)­thio­semicarbazonato ligand and two C atom...

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Detalles Bibliográficos
Autores principales: Cui, Jichun, Ruan, Hong, Qiao, Yanling, Yin, Handong
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051660/
https://www.ncbi.nlm.nih.gov/pubmed/21522829
http://dx.doi.org/10.1107/S1600536810054024
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author Cui, Jichun
Ruan, Hong
Qiao, Yanling
Yin, Handong
author_facet Cui, Jichun
Ruan, Hong
Qiao, Yanling
Yin, Handong
author_sort Cui, Jichun
collection PubMed
description The asymmetric unit of the title compound, [Sn(C(6)H(5))(2)(C(12)H(9)N(3)OS)], contains two independent mol­ecules with almost identical configurations. In each mol­ecule, the Sn(IV) atom is coordinated by O, N and S atoms from a (2-oxido-1-naph­thaldehyde)­thio­semicarbazonato ligand and two C atoms from phenyl rings in a distorted trigonal–bipyramidal geometry. Weak inter­molecular N—H⋯O and N—H⋯S hydrogen bonds link four mol­ecules into a centrosymmetric tetra­mer. The crystal packing exhibits short inter­molecular S⋯S contacts of 3.335 (3) Å.
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spelling pubmed-30516602011-04-26 {1-[(2-Oxidonaphthalen-1-yl)methylidene]thiosemicarbazidato-κ(3) N (1),O,S}diphenyl­tin(IV) Cui, Jichun Ruan, Hong Qiao, Yanling Yin, Handong Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [Sn(C(6)H(5))(2)(C(12)H(9)N(3)OS)], contains two independent mol­ecules with almost identical configurations. In each mol­ecule, the Sn(IV) atom is coordinated by O, N and S atoms from a (2-oxido-1-naph­thaldehyde)­thio­semicarbazonato ligand and two C atoms from phenyl rings in a distorted trigonal–bipyramidal geometry. Weak inter­molecular N—H⋯O and N—H⋯S hydrogen bonds link four mol­ecules into a centrosymmetric tetra­mer. The crystal packing exhibits short inter­molecular S⋯S contacts of 3.335 (3) Å. International Union of Crystallography 2011-01-08 /pmc/articles/PMC3051660/ /pubmed/21522829 http://dx.doi.org/10.1107/S1600536810054024 Text en © Cui et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Cui, Jichun
Ruan, Hong
Qiao, Yanling
Yin, Handong
{1-[(2-Oxidonaphthalen-1-yl)methylidene]thiosemicarbazidato-κ(3) N (1),O,S}diphenyl­tin(IV)
title {1-[(2-Oxidonaphthalen-1-yl)methylidene]thiosemicarbazidato-κ(3) N (1),O,S}diphenyl­tin(IV)
title_full {1-[(2-Oxidonaphthalen-1-yl)methylidene]thiosemicarbazidato-κ(3) N (1),O,S}diphenyl­tin(IV)
title_fullStr {1-[(2-Oxidonaphthalen-1-yl)methylidene]thiosemicarbazidato-κ(3) N (1),O,S}diphenyl­tin(IV)
title_full_unstemmed {1-[(2-Oxidonaphthalen-1-yl)methylidene]thiosemicarbazidato-κ(3) N (1),O,S}diphenyl­tin(IV)
title_short {1-[(2-Oxidonaphthalen-1-yl)methylidene]thiosemicarbazidato-κ(3) N (1),O,S}diphenyl­tin(IV)
title_sort {1-[(2-oxidonaphthalen-1-yl)methylidene]thiosemicarbazidato-κ(3) n (1),o,s}diphenyl­tin(iv)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051660/
https://www.ncbi.nlm.nih.gov/pubmed/21522829
http://dx.doi.org/10.1107/S1600536810054024
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AT ruanhong 12oxidonaphthalen1ylmethylidenethiosemicarbazidatok3n1osdiphenyltiniv
AT qiaoyanling 12oxidonaphthalen1ylmethylidenethiosemicarbazidatok3n1osdiphenyltiniv
AT yinhandong 12oxidonaphthalen1ylmethylidenethiosemicarbazidatok3n1osdiphenyltiniv

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