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Poly[[hepta-μ(2)-aqua-bis(μ(2)-pyrazine-2-carboxylato)dibarium] bis(pyrazine-2-carboxylate)]
In the layered title coordination polymer, {[Ba(2)(C(5)H(3)N(2)O(2))(2)(H(2)O)(7)](C(5)H(3)N(2)O(2))(2)}(n), the coordination geometries around the two independent Ba(II) ions can be described as bicapped square-antiprismatic [BaNO(9)] arrangements. A two-dimensional polymeric framework with (6,3)...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051667/ https://www.ncbi.nlm.nih.gov/pubmed/21522928 http://dx.doi.org/10.1107/S1600536811003023 |
Sumario: | In the layered title coordination polymer, {[Ba(2)(C(5)H(3)N(2)O(2))(2)(H(2)O)(7)](C(5)H(3)N(2)O(2))(2)}(n), the coordination geometries around the two independent Ba(II) ions can be described as bicapped square-antiprismatic [BaNO(9)] arrangements. A two-dimensional polymeric framework with (6,3) topology can be observed in the ac plane, the nodes being provided by Ba(II) ions and the connectors being N and O atoms belonging to pyrazine-2-carboxylate ligands and O atoms of bridging water molecules. Non-coordinating pyrazine-2-carboxylate ions are located between the polymeric layers in the crystal and are interconnected through extensive O—H⋯N,O hydrogen bonding. |
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