Cargando…
Poly[[hepta-μ(2)-aqua-bis(μ(2)-pyrazine-2-carboxylato)dibarium] bis(pyrazine-2-carboxylate)]
In the layered title coordination polymer, {[Ba(2)(C(5)H(3)N(2)O(2))(2)(H(2)O)(7)](C(5)H(3)N(2)O(2))(2)}(n), the coordination geometries around the two independent Ba(II) ions can be described as bicapped square-antiprismatic [BaNO(9)] arrangements. A two-dimensional polymeric framework with (6,3)...
Autores principales: | , , , |
---|---|
Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051667/ https://www.ncbi.nlm.nih.gov/pubmed/21522928 http://dx.doi.org/10.1107/S1600536811003023 |
_version_ | 1782199533514522624 |
---|---|
author | Shuai, Qi Ding, Ke-Lian Hu, Fan Yu, Ping |
author_facet | Shuai, Qi Ding, Ke-Lian Hu, Fan Yu, Ping |
author_sort | Shuai, Qi |
collection | PubMed |
description | In the layered title coordination polymer, {[Ba(2)(C(5)H(3)N(2)O(2))(2)(H(2)O)(7)](C(5)H(3)N(2)O(2))(2)}(n), the coordination geometries around the two independent Ba(II) ions can be described as bicapped square-antiprismatic [BaNO(9)] arrangements. A two-dimensional polymeric framework with (6,3) topology can be observed in the ac plane, the nodes being provided by Ba(II) ions and the connectors being N and O atoms belonging to pyrazine-2-carboxylate ligands and O atoms of bridging water molecules. Non-coordinating pyrazine-2-carboxylate ions are located between the polymeric layers in the crystal and are interconnected through extensive O—H⋯N,O hydrogen bonding. |
format | Text |
id | pubmed-3051667 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30516672011-04-26 Poly[[hepta-μ(2)-aqua-bis(μ(2)-pyrazine-2-carboxylato)dibarium] bis(pyrazine-2-carboxylate)] Shuai, Qi Ding, Ke-Lian Hu, Fan Yu, Ping Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the layered title coordination polymer, {[Ba(2)(C(5)H(3)N(2)O(2))(2)(H(2)O)(7)](C(5)H(3)N(2)O(2))(2)}(n), the coordination geometries around the two independent Ba(II) ions can be described as bicapped square-antiprismatic [BaNO(9)] arrangements. A two-dimensional polymeric framework with (6,3) topology can be observed in the ac plane, the nodes being provided by Ba(II) ions and the connectors being N and O atoms belonging to pyrazine-2-carboxylate ligands and O atoms of bridging water molecules. Non-coordinating pyrazine-2-carboxylate ions are located between the polymeric layers in the crystal and are interconnected through extensive O—H⋯N,O hydrogen bonding. International Union of Crystallography 2011-01-29 /pmc/articles/PMC3051667/ /pubmed/21522928 http://dx.doi.org/10.1107/S1600536811003023 Text en © Shuai et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Shuai, Qi Ding, Ke-Lian Hu, Fan Yu, Ping Poly[[hepta-μ(2)-aqua-bis(μ(2)-pyrazine-2-carboxylato)dibarium] bis(pyrazine-2-carboxylate)] |
title | Poly[[hepta-μ(2)-aqua-bis(μ(2)-pyrazine-2-carboxylato)dibarium] bis(pyrazine-2-carboxylate)] |
title_full | Poly[[hepta-μ(2)-aqua-bis(μ(2)-pyrazine-2-carboxylato)dibarium] bis(pyrazine-2-carboxylate)] |
title_fullStr | Poly[[hepta-μ(2)-aqua-bis(μ(2)-pyrazine-2-carboxylato)dibarium] bis(pyrazine-2-carboxylate)] |
title_full_unstemmed | Poly[[hepta-μ(2)-aqua-bis(μ(2)-pyrazine-2-carboxylato)dibarium] bis(pyrazine-2-carboxylate)] |
title_short | Poly[[hepta-μ(2)-aqua-bis(μ(2)-pyrazine-2-carboxylato)dibarium] bis(pyrazine-2-carboxylate)] |
title_sort | poly[[hepta-μ(2)-aqua-bis(μ(2)-pyrazine-2-carboxylato)dibarium] bis(pyrazine-2-carboxylate)] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051667/ https://www.ncbi.nlm.nih.gov/pubmed/21522928 http://dx.doi.org/10.1107/S1600536811003023 |
work_keys_str_mv | AT shuaiqi polyheptam2aquabism2pyrazine2carboxylatodibariumbispyrazine2carboxylate AT dingkelian polyheptam2aquabism2pyrazine2carboxylatodibariumbispyrazine2carboxylate AT hufan polyheptam2aquabism2pyrazine2carboxylatodibariumbispyrazine2carboxylate AT yuping polyheptam2aquabism2pyrazine2carboxylatodibariumbispyrazine2carboxylate |