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Poly[[hepta-μ(2)-aqua-bis­(μ(2)-pyrazine-2-carboxyl­ato)dibarium] bis­(pyrazine-2-carboxyl­ate)]

In the layered title coordination polymer, {[Ba(2)(C(5)H(3)N(2)O(2))(2)(H(2)O)(7)](C(5)H(3)N(2)O(2))(2)}(n), the coordination geometries around the two independent Ba(II) ions can be described as bicapped square-anti­prismatic [BaNO(9)] arrangements. A two-dimensional polymeric framework with (6,3)...

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Detalles Bibliográficos
Autores principales: Shuai, Qi, Ding, Ke-Lian, Hu, Fan, Yu, Ping
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051667/
https://www.ncbi.nlm.nih.gov/pubmed/21522928
http://dx.doi.org/10.1107/S1600536811003023
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author Shuai, Qi
Ding, Ke-Lian
Hu, Fan
Yu, Ping
author_facet Shuai, Qi
Ding, Ke-Lian
Hu, Fan
Yu, Ping
author_sort Shuai, Qi
collection PubMed
description In the layered title coordination polymer, {[Ba(2)(C(5)H(3)N(2)O(2))(2)(H(2)O)(7)](C(5)H(3)N(2)O(2))(2)}(n), the coordination geometries around the two independent Ba(II) ions can be described as bicapped square-anti­prismatic [BaNO(9)] arrangements. A two-dimensional polymeric framework with (6,3) topology can be observed in the ac plane, the nodes being provided by Ba(II) ions and the connectors being N and O atoms belonging to pyrazine-2-carboxyl­ate ligands and O atoms of bridging water mol­ecules. Non-coordinating pyrazine-2-carboxyl­ate ions are located between the polymeric layers in the crystal and are interconnected through extensive O—H⋯N,O hydrogen bonding.
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spelling pubmed-30516672011-04-26 Poly[[hepta-μ(2)-aqua-bis­(μ(2)-pyrazine-2-carboxyl­ato)dibarium] bis­(pyrazine-2-carboxyl­ate)] Shuai, Qi Ding, Ke-Lian Hu, Fan Yu, Ping Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the layered title coordination polymer, {[Ba(2)(C(5)H(3)N(2)O(2))(2)(H(2)O)(7)](C(5)H(3)N(2)O(2))(2)}(n), the coordination geometries around the two independent Ba(II) ions can be described as bicapped square-anti­prismatic [BaNO(9)] arrangements. A two-dimensional polymeric framework with (6,3) topology can be observed in the ac plane, the nodes being provided by Ba(II) ions and the connectors being N and O atoms belonging to pyrazine-2-carboxyl­ate ligands and O atoms of bridging water mol­ecules. Non-coordinating pyrazine-2-carboxyl­ate ions are located between the polymeric layers in the crystal and are interconnected through extensive O—H⋯N,O hydrogen bonding. International Union of Crystallography 2011-01-29 /pmc/articles/PMC3051667/ /pubmed/21522928 http://dx.doi.org/10.1107/S1600536811003023 Text en © Shuai et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Shuai, Qi
Ding, Ke-Lian
Hu, Fan
Yu, Ping
Poly[[hepta-μ(2)-aqua-bis­(μ(2)-pyrazine-2-carboxyl­ato)dibarium] bis­(pyrazine-2-carboxyl­ate)]
title Poly[[hepta-μ(2)-aqua-bis­(μ(2)-pyrazine-2-carboxyl­ato)dibarium] bis­(pyrazine-2-carboxyl­ate)]
title_full Poly[[hepta-μ(2)-aqua-bis­(μ(2)-pyrazine-2-carboxyl­ato)dibarium] bis­(pyrazine-2-carboxyl­ate)]
title_fullStr Poly[[hepta-μ(2)-aqua-bis­(μ(2)-pyrazine-2-carboxyl­ato)dibarium] bis­(pyrazine-2-carboxyl­ate)]
title_full_unstemmed Poly[[hepta-μ(2)-aqua-bis­(μ(2)-pyrazine-2-carboxyl­ato)dibarium] bis­(pyrazine-2-carboxyl­ate)]
title_short Poly[[hepta-μ(2)-aqua-bis­(μ(2)-pyrazine-2-carboxyl­ato)dibarium] bis­(pyrazine-2-carboxyl­ate)]
title_sort poly[[hepta-μ(2)-aqua-bis­(μ(2)-pyrazine-2-carboxyl­ato)dibarium] bis­(pyrazine-2-carboxyl­ate)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051667/
https://www.ncbi.nlm.nih.gov/pubmed/21522928
http://dx.doi.org/10.1107/S1600536811003023
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