Bis(2-amino-4-methyl­pyridinium) bis­(pyridine-2,6-dicarboxyl­ato)cuprate(II)

The asymmetric unit of the title compound, (C(6)H(9)N(2))(2)[Cu(C(7)H(3)NO(4))(2)], contains half of a [Cu(pydc)(2)](2−) (pydcH(2) is pyridine-2,6-dicarb­oxy­lic acid) anion and one protonated 2-amino-4-methyl­pyridine (2a4mpH)(+) counter-ion. The anion is a six-coordinated complex with a distorted...

Descripción completa

Detalles Bibliográficos
Autores principales: Aghabozorg, Hossein, Mofidi Rouchi, Azadeh, Notash, Behrouz, Mirzaei, Masoud
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051671/
https://www.ncbi.nlm.nih.gov/pubmed/21522859
http://dx.doi.org/10.1107/S1600536811001139
_version_ 1782199534481309696
author Aghabozorg, Hossein
Mofidi Rouchi, Azadeh
Notash, Behrouz
Mirzaei, Masoud
author_facet Aghabozorg, Hossein
Mofidi Rouchi, Azadeh
Notash, Behrouz
Mirzaei, Masoud
author_sort Aghabozorg, Hossein
collection PubMed
description The asymmetric unit of the title compound, (C(6)H(9)N(2))(2)[Cu(C(7)H(3)NO(4))(2)], contains half of a [Cu(pydc)(2)](2−) (pydcH(2) is pyridine-2,6-dicarb­oxy­lic acid) anion and one protonated 2-amino-4-methyl­pyridine (2a4mpH)(+) counter-ion. The anion is a six-coordinated complex with a distorted CuN(2)O(4) octa­hedral geometry around the Cu(II) ion. N—H⋯O and C—H⋯O hydrogen bonds along with π–π contacts between the pyridine rings of the (2a4mpH)(+) cations [centroid–centroid distance = 3.573 (2) Å] stabilize the crystal structure.
format Text
id pubmed-3051671
institution National Center for Biotechnology Information
language English
publishDate 2011
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-30516712011-04-26 Bis(2-amino-4-methyl­pyridinium) bis­(pyridine-2,6-dicarboxyl­ato)cuprate(II) Aghabozorg, Hossein Mofidi Rouchi, Azadeh Notash, Behrouz Mirzaei, Masoud Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, (C(6)H(9)N(2))(2)[Cu(C(7)H(3)NO(4))(2)], contains half of a [Cu(pydc)(2)](2−) (pydcH(2) is pyridine-2,6-dicarb­oxy­lic acid) anion and one protonated 2-amino-4-methyl­pyridine (2a4mpH)(+) counter-ion. The anion is a six-coordinated complex with a distorted CuN(2)O(4) octa­hedral geometry around the Cu(II) ion. N—H⋯O and C—H⋯O hydrogen bonds along with π–π contacts between the pyridine rings of the (2a4mpH)(+) cations [centroid–centroid distance = 3.573 (2) Å] stabilize the crystal structure. International Union of Crystallography 2011-01-15 /pmc/articles/PMC3051671/ /pubmed/21522859 http://dx.doi.org/10.1107/S1600536811001139 Text en © Aghabozorg et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Aghabozorg, Hossein
Mofidi Rouchi, Azadeh
Notash, Behrouz
Mirzaei, Masoud
Bis(2-amino-4-methyl­pyridinium) bis­(pyridine-2,6-dicarboxyl­ato)cuprate(II)
title Bis(2-amino-4-methyl­pyridinium) bis­(pyridine-2,6-dicarboxyl­ato)cuprate(II)
title_full Bis(2-amino-4-methyl­pyridinium) bis­(pyridine-2,6-dicarboxyl­ato)cuprate(II)
title_fullStr Bis(2-amino-4-methyl­pyridinium) bis­(pyridine-2,6-dicarboxyl­ato)cuprate(II)
title_full_unstemmed Bis(2-amino-4-methyl­pyridinium) bis­(pyridine-2,6-dicarboxyl­ato)cuprate(II)
title_short Bis(2-amino-4-methyl­pyridinium) bis­(pyridine-2,6-dicarboxyl­ato)cuprate(II)
title_sort bis(2-amino-4-methyl­pyridinium) bis­(pyridine-2,6-dicarboxyl­ato)cuprate(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051671/
https://www.ncbi.nlm.nih.gov/pubmed/21522859
http://dx.doi.org/10.1107/S1600536811001139
work_keys_str_mv AT aghabozorghossein bis2amino4methylpyridiniumbispyridine26dicarboxylatocuprateii
AT mofidirouchiazadeh bis2amino4methylpyridiniumbispyridine26dicarboxylatocuprateii
AT notashbehrouz bis2amino4methylpyridiniumbispyridine26dicarboxylatocuprateii
AT mirzaeimasoud bis2amino4methylpyridiniumbispyridine26dicarboxylatocuprateii

Ejemplares similares