3-Meth­oxy-2-[(E)-(4-meth­oxy­phen­yl)imino­meth­yl]phenol

The title compound, C(15)H(15)NO(3), adopts the enol–imine tautomeric form. The two rings are twisted with respect to each other, making a dihedral angle of 44.08 (5)°. The 3-methoxy-2-[(E)-(4-methoxyphenyl)-iminomethyl]phenol unit is almost planar, the largest deviation from the mean plane being 0....

Descripción completa

Detalles Bibliográficos
Autores principales: Özdemir Tari, Gonca, Işık, Şamil, Özkan, Ramazan, Alaman Ağar, Ayşen
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051687/
https://www.ncbi.nlm.nih.gov/pubmed/21523025
http://dx.doi.org/10.1107/S1600536811000596
_version_ 1782199538292883456
author Özdemir Tari, Gonca
Işık, Şamil
Özkan, Ramazan
Alaman Ağar, Ayşen
author_facet Özdemir Tari, Gonca
Işık, Şamil
Özkan, Ramazan
Alaman Ağar, Ayşen
author_sort Özdemir Tari, Gonca
collection PubMed
description The title compound, C(15)H(15)NO(3), adopts the enol–imine tautomeric form. The two rings are twisted with respect to each other, making a dihedral angle of 44.08 (5)°. The 3-methoxy-2-[(E)-(4-methoxyphenyl)-iminomethyl]phenol unit is almost planar, the largest deviation from the mean plane being 0.047 (2) Å. Such a planar conformation might be related to the occurrence of an intra­molecular O—H⋯N hydrogen bond. In the crystal, inter­molecular C—H⋯O hydrogen bonds link the mol­ecules into sheets parallel to (010). These sheets are inter­connected by weak C—H⋯π inter­actions.
format Text
id pubmed-3051687
institution National Center for Biotechnology Information
language English
publishDate 2011
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-30516872011-04-26 3-Meth­oxy-2-[(E)-(4-meth­oxy­phen­yl)imino­meth­yl]phenol Özdemir Tari, Gonca Işık, Şamil Özkan, Ramazan Alaman Ağar, Ayşen Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(15)H(15)NO(3), adopts the enol–imine tautomeric form. The two rings are twisted with respect to each other, making a dihedral angle of 44.08 (5)°. The 3-methoxy-2-[(E)-(4-methoxyphenyl)-iminomethyl]phenol unit is almost planar, the largest deviation from the mean plane being 0.047 (2) Å. Such a planar conformation might be related to the occurrence of an intra­molecular O—H⋯N hydrogen bond. In the crystal, inter­molecular C—H⋯O hydrogen bonds link the mol­ecules into sheets parallel to (010). These sheets are inter­connected by weak C—H⋯π inter­actions. International Union of Crystallography 2011-01-12 /pmc/articles/PMC3051687/ /pubmed/21523025 http://dx.doi.org/10.1107/S1600536811000596 Text en © Özdemir Tari et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Özdemir Tari, Gonca
Işık, Şamil
Özkan, Ramazan
Alaman Ağar, Ayşen
3-Meth­oxy-2-[(E)-(4-meth­oxy­phen­yl)imino­meth­yl]phenol
title 3-Meth­oxy-2-[(E)-(4-meth­oxy­phen­yl)imino­meth­yl]phenol
title_full 3-Meth­oxy-2-[(E)-(4-meth­oxy­phen­yl)imino­meth­yl]phenol
title_fullStr 3-Meth­oxy-2-[(E)-(4-meth­oxy­phen­yl)imino­meth­yl]phenol
title_full_unstemmed 3-Meth­oxy-2-[(E)-(4-meth­oxy­phen­yl)imino­meth­yl]phenol
title_short 3-Meth­oxy-2-[(E)-(4-meth­oxy­phen­yl)imino­meth­yl]phenol
title_sort 3-meth­oxy-2-[(e)-(4-meth­oxy­phen­yl)imino­meth­yl]phenol
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051687/
https://www.ncbi.nlm.nih.gov/pubmed/21523025
http://dx.doi.org/10.1107/S1600536811000596
work_keys_str_mv AT ozdemirtarigonca 3methoxy2e4methoxyphenyliminomethylphenol
AT isıksamil 3methoxy2e4methoxyphenyliminomethylphenol
AT ozkanramazan 3methoxy2e4methoxyphenyliminomethylphenol
AT alamanagaraysen 3methoxy2e4methoxyphenyliminomethylphenol

Ejemplares similares