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catena-Poly[[(2,2′-bipyridine-κ(2) N,N′)cadmium]-μ(3)-4-nitrophthalato-κ(4) O:O′,O′′:O′′′]
In the title polymeric compound, [Cd(C(8)H(3)NO(6))(C(10)H(8)N(2))](n), two O atoms from both carboxylate groups of a nitrophthalate anion coordinate to the Cd(II) cation, forming a seven-membered chelate ring and two carboxylate O atoms from another two nitrophthalate anions and a 2,2′-bipyridi...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051688/ https://www.ncbi.nlm.nih.gov/pubmed/21522865 http://dx.doi.org/10.1107/S1600536811000468 |
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author | Fan, Yang Xu, Guo-Min Lu, Hai-Ting Li, Wei |
author_facet | Fan, Yang Xu, Guo-Min Lu, Hai-Ting Li, Wei |
author_sort | Fan, Yang |
collection | PubMed |
description | In the title polymeric compound, [Cd(C(8)H(3)NO(6))(C(10)H(8)N(2))](n), two O atoms from both carboxylate groups of a nitrophthalate anion coordinate to the Cd(II) cation, forming a seven-membered chelate ring and two carboxylate O atoms from another two nitrophthalate anions and a 2,2′-bipyridine ligand coordinate to the Cd cation to complete the distorted octahedral coordination geometry. The carboxylate groups of the nitrophthalate anion adopt a syn–anti bridging mode, linking adjacent Cd(II) cations and forming a polymeric chain running along the a axis. Weak intra- and intermolecular C—H⋯O hydrogen bonding is present in the crystal structure. |
format | Text |
id | pubmed-3051688 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30516882011-04-26 catena-Poly[[(2,2′-bipyridine-κ(2) N,N′)cadmium]-μ(3)-4-nitrophthalato-κ(4) O:O′,O′′:O′′′] Fan, Yang Xu, Guo-Min Lu, Hai-Ting Li, Wei Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title polymeric compound, [Cd(C(8)H(3)NO(6))(C(10)H(8)N(2))](n), two O atoms from both carboxylate groups of a nitrophthalate anion coordinate to the Cd(II) cation, forming a seven-membered chelate ring and two carboxylate O atoms from another two nitrophthalate anions and a 2,2′-bipyridine ligand coordinate to the Cd cation to complete the distorted octahedral coordination geometry. The carboxylate groups of the nitrophthalate anion adopt a syn–anti bridging mode, linking adjacent Cd(II) cations and forming a polymeric chain running along the a axis. Weak intra- and intermolecular C—H⋯O hydrogen bonding is present in the crystal structure. International Union of Crystallography 2011-01-15 /pmc/articles/PMC3051688/ /pubmed/21522865 http://dx.doi.org/10.1107/S1600536811000468 Text en © Fan et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Fan, Yang Xu, Guo-Min Lu, Hai-Ting Li, Wei catena-Poly[[(2,2′-bipyridine-κ(2) N,N′)cadmium]-μ(3)-4-nitrophthalato-κ(4) O:O′,O′′:O′′′] |
title |
catena-Poly[[(2,2′-bipyridine-κ(2)
N,N′)cadmium]-μ(3)-4-nitrophthalato-κ(4)
O:O′,O′′:O′′′] |
title_full |
catena-Poly[[(2,2′-bipyridine-κ(2)
N,N′)cadmium]-μ(3)-4-nitrophthalato-κ(4)
O:O′,O′′:O′′′] |
title_fullStr |
catena-Poly[[(2,2′-bipyridine-κ(2)
N,N′)cadmium]-μ(3)-4-nitrophthalato-κ(4)
O:O′,O′′:O′′′] |
title_full_unstemmed |
catena-Poly[[(2,2′-bipyridine-κ(2)
N,N′)cadmium]-μ(3)-4-nitrophthalato-κ(4)
O:O′,O′′:O′′′] |
title_short |
catena-Poly[[(2,2′-bipyridine-κ(2)
N,N′)cadmium]-μ(3)-4-nitrophthalato-κ(4)
O:O′,O′′:O′′′] |
title_sort | catena-poly[[(2,2′-bipyridine-κ(2)
n,n′)cadmium]-μ(3)-4-nitrophthalato-κ(4)
o:o′,o′′:o′′′] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051688/ https://www.ncbi.nlm.nih.gov/pubmed/21522865 http://dx.doi.org/10.1107/S1600536811000468 |
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