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catena-Poly[[(2,2′-bipyridine-κ(2) N,N′)cadmium]-μ(3)-4-nitro­phthalato-κ(4) O:O′,O′′:O′′′]

In the title polymeric compound, [Cd(C(8)H(3)NO(6))(C(10)H(8)N(2))](n), two O atoms from both carboxyl­ate groups of a nitro­phthalate anion coordinate to the Cd(II) cation, forming a seven-membered chelate ring and two carboxyl­ate O atoms from another two nitro­phthalate anions and a 2,2′-bipyridi...

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Detalles Bibliográficos
Autores principales: Fan, Yang, Xu, Guo-Min, Lu, Hai-Ting, Li, Wei
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051688/
https://www.ncbi.nlm.nih.gov/pubmed/21522865
http://dx.doi.org/10.1107/S1600536811000468
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author Fan, Yang
Xu, Guo-Min
Lu, Hai-Ting
Li, Wei
author_facet Fan, Yang
Xu, Guo-Min
Lu, Hai-Ting
Li, Wei
author_sort Fan, Yang
collection PubMed
description In the title polymeric compound, [Cd(C(8)H(3)NO(6))(C(10)H(8)N(2))](n), two O atoms from both carboxyl­ate groups of a nitro­phthalate anion coordinate to the Cd(II) cation, forming a seven-membered chelate ring and two carboxyl­ate O atoms from another two nitro­phthalate anions and a 2,2′-bipyridine ligand coordinate to the Cd cation to complete the distorted octa­hedral coordination geometry. The carboxyl­ate groups of the nitro­phthalate anion adopt a syn–anti bridging mode, linking adjacent Cd(II) cations and forming a polymeric chain running along the a axis. Weak intra- and inter­molecular C—H⋯O hydrogen bonding is present in the crystal structure.
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spelling pubmed-30516882011-04-26 catena-Poly[[(2,2′-bipyridine-κ(2) N,N′)cadmium]-μ(3)-4-nitro­phthalato-κ(4) O:O′,O′′:O′′′] Fan, Yang Xu, Guo-Min Lu, Hai-Ting Li, Wei Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title polymeric compound, [Cd(C(8)H(3)NO(6))(C(10)H(8)N(2))](n), two O atoms from both carboxyl­ate groups of a nitro­phthalate anion coordinate to the Cd(II) cation, forming a seven-membered chelate ring and two carboxyl­ate O atoms from another two nitro­phthalate anions and a 2,2′-bipyridine ligand coordinate to the Cd cation to complete the distorted octa­hedral coordination geometry. The carboxyl­ate groups of the nitro­phthalate anion adopt a syn–anti bridging mode, linking adjacent Cd(II) cations and forming a polymeric chain running along the a axis. Weak intra- and inter­molecular C—H⋯O hydrogen bonding is present in the crystal structure. International Union of Crystallography 2011-01-15 /pmc/articles/PMC3051688/ /pubmed/21522865 http://dx.doi.org/10.1107/S1600536811000468 Text en © Fan et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Fan, Yang
Xu, Guo-Min
Lu, Hai-Ting
Li, Wei
catena-Poly[[(2,2′-bipyridine-κ(2) N,N′)cadmium]-μ(3)-4-nitro­phthalato-κ(4) O:O′,O′′:O′′′]
title catena-Poly[[(2,2′-bipyridine-κ(2) N,N′)cadmium]-μ(3)-4-nitro­phthalato-κ(4) O:O′,O′′:O′′′]
title_full catena-Poly[[(2,2′-bipyridine-κ(2) N,N′)cadmium]-μ(3)-4-nitro­phthalato-κ(4) O:O′,O′′:O′′′]
title_fullStr catena-Poly[[(2,2′-bipyridine-κ(2) N,N′)cadmium]-μ(3)-4-nitro­phthalato-κ(4) O:O′,O′′:O′′′]
title_full_unstemmed catena-Poly[[(2,2′-bipyridine-κ(2) N,N′)cadmium]-μ(3)-4-nitro­phthalato-κ(4) O:O′,O′′:O′′′]
title_short catena-Poly[[(2,2′-bipyridine-κ(2) N,N′)cadmium]-μ(3)-4-nitro­phthalato-κ(4) O:O′,O′′:O′′′]
title_sort catena-poly[[(2,2′-bipyridine-κ(2) n,n′)cadmium]-μ(3)-4-nitro­phthalato-κ(4) o:o′,o′′:o′′′]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051688/
https://www.ncbi.nlm.nih.gov/pubmed/21522865
http://dx.doi.org/10.1107/S1600536811000468
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