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8-Hydroxy-2-methylquinolinium tetrachlorido(pyridine-2-carboxylato-κ(2) N,O)stannate(IV)
In the reaction of pyridine-2-carboxylic acid and stannic chloride in the presence of 2-methyl-8-hydroxyquinoline, the 2-methyl-8-hydroxyquinoline is protonated, yielding the title salt, (C(10)H(10)NO)[SnCl(4)(C(6)H(4)NO(2))]. The Sn(IV) atom in the anion is N,O-chelated by a pyridine-2-carbox...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2011
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051689/ https://www.ncbi.nlm.nih.gov/pubmed/21522895 http://dx.doi.org/10.1107/S1600536811001942 |
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author | Najafi, Ezzatollah Amini, Mostafa M. Ng, Seik Weng |
author_facet | Najafi, Ezzatollah Amini, Mostafa M. Ng, Seik Weng |
author_sort | Najafi, Ezzatollah |
collection | PubMed |
description | In the reaction of pyridine-2-carboxylic acid and stannic chloride in the presence of 2-methyl-8-hydroxyquinoline, the 2-methyl-8-hydroxyquinoline is protonated, yielding the title salt, (C(10)H(10)NO)[SnCl(4)(C(6)H(4)NO(2))]. The Sn(IV) atom in the anion is N,O-chelated by a pyridine-2-carboxylate in a cis-SnNOCl(4) octahedral geometry. The cation is linked to the anion by an O—H⋯O hydrogen bond. |
format | Text |
id | pubmed-3051689 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30516892011-04-26 8-Hydroxy-2-methylquinolinium tetrachlorido(pyridine-2-carboxylato-κ(2) N,O)stannate(IV) Najafi, Ezzatollah Amini, Mostafa M. Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the reaction of pyridine-2-carboxylic acid and stannic chloride in the presence of 2-methyl-8-hydroxyquinoline, the 2-methyl-8-hydroxyquinoline is protonated, yielding the title salt, (C(10)H(10)NO)[SnCl(4)(C(6)H(4)NO(2))]. The Sn(IV) atom in the anion is N,O-chelated by a pyridine-2-carboxylate in a cis-SnNOCl(4) octahedral geometry. The cation is linked to the anion by an O—H⋯O hydrogen bond. International Union of Crystallography 2011-01-22 /pmc/articles/PMC3051689/ /pubmed/21522895 http://dx.doi.org/10.1107/S1600536811001942 Text en © Najafi et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Najafi, Ezzatollah Amini, Mostafa M. Ng, Seik Weng 8-Hydroxy-2-methylquinolinium tetrachlorido(pyridine-2-carboxylato-κ(2) N,O)stannate(IV) |
title | 8-Hydroxy-2-methylquinolinium tetrachlorido(pyridine-2-carboxylato-κ(2)
N,O)stannate(IV) |
title_full | 8-Hydroxy-2-methylquinolinium tetrachlorido(pyridine-2-carboxylato-κ(2)
N,O)stannate(IV) |
title_fullStr | 8-Hydroxy-2-methylquinolinium tetrachlorido(pyridine-2-carboxylato-κ(2)
N,O)stannate(IV) |
title_full_unstemmed | 8-Hydroxy-2-methylquinolinium tetrachlorido(pyridine-2-carboxylato-κ(2)
N,O)stannate(IV) |
title_short | 8-Hydroxy-2-methylquinolinium tetrachlorido(pyridine-2-carboxylato-κ(2)
N,O)stannate(IV) |
title_sort | 8-hydroxy-2-methylquinolinium tetrachlorido(pyridine-2-carboxylato-κ(2)
n,o)stannate(iv) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051689/ https://www.ncbi.nlm.nih.gov/pubmed/21522895 http://dx.doi.org/10.1107/S1600536811001942 |
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