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Hexa-μ(2)-chlorido-μ(4)-oxido-tetrakis[(3-methyl-5-phenyl-1H-pyrazole-κN (2))copper(II)]
The title compound, [Cu(4)Cl(6)O(C(10)H(10)N(2))(4)], contains four Cu(II) atoms which are bridged by six chloride anions. The central O atom is located on a crystallographic fourfold roto-inversion axis. Each Cu(II) atom is coordinated by an N atom of a neutral monodentate 3-methyl-5-phenylpyrazol...
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051691/ https://www.ncbi.nlm.nih.gov/pubmed/21522826 http://dx.doi.org/10.1107/S1600536810053663 |
Sumario: | The title compound, [Cu(4)Cl(6)O(C(10)H(10)N(2))(4)], contains four Cu(II) atoms which are bridged by six chloride anions. The central O atom is located on a crystallographic fourfold roto-inversion axis. Each Cu(II) atom is coordinated by an N atom of a neutral monodentate 3-methyl-5-phenylpyrazole ligand, three Cl(−) anions, and one O(2−) anion. The geometry at each Cu(II) atom is distorted trigonal–bipyramidal, with the three Cl(−) ions in the equatorial plane and the N and O atoms in the axial positions. |
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