Hexa-μ(2)-chlorido-μ(4)-oxido-tetra­kis­[(3-methyl-5-phenyl-1H-pyrazole-κN (2))copper(II)]

The title compound, [Cu(4)Cl(6)O(C(10)H(10)N(2))(4)], contains four Cu(II) atoms which are bridged by six chloride anions. The central O atom is located on a crystallographic fourfold roto-inversion axis. Each Cu(II) atom is coordinated by an N atom of a neutral monodentate 3-methyl-5-phenyl­pyrazol...

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Autor principal: He, Hongshan
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051691/
https://www.ncbi.nlm.nih.gov/pubmed/21522826
http://dx.doi.org/10.1107/S1600536810053663
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author He, Hongshan
author_facet He, Hongshan
author_sort He, Hongshan
collection PubMed
description The title compound, [Cu(4)Cl(6)O(C(10)H(10)N(2))(4)], contains four Cu(II) atoms which are bridged by six chloride anions. The central O atom is located on a crystallographic fourfold roto-inversion axis. Each Cu(II) atom is coordinated by an N atom of a neutral monodentate 3-methyl-5-phenyl­pyrazole ligand, three Cl(−) anions, and one O(2−) anion. The geometry at each Cu(II) atom is distorted trigonal–bipyramidal, with the three Cl(−) ions in the equatorial plane and the N and O atoms in the axial positions.
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spelling pubmed-30516912011-04-26 Hexa-μ(2)-chlorido-μ(4)-oxido-tetra­kis­[(3-methyl-5-phenyl-1H-pyrazole-κN (2))copper(II)] He, Hongshan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Cu(4)Cl(6)O(C(10)H(10)N(2))(4)], contains four Cu(II) atoms which are bridged by six chloride anions. The central O atom is located on a crystallographic fourfold roto-inversion axis. Each Cu(II) atom is coordinated by an N atom of a neutral monodentate 3-methyl-5-phenyl­pyrazole ligand, three Cl(−) anions, and one O(2−) anion. The geometry at each Cu(II) atom is distorted trigonal–bipyramidal, with the three Cl(−) ions in the equatorial plane and the N and O atoms in the axial positions. International Union of Crystallography 2011-01-08 /pmc/articles/PMC3051691/ /pubmed/21522826 http://dx.doi.org/10.1107/S1600536810053663 Text en © Hongshan He 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
He, Hongshan
Hexa-μ(2)-chlorido-μ(4)-oxido-tetra­kis­[(3-methyl-5-phenyl-1H-pyrazole-κN (2))copper(II)]
title Hexa-μ(2)-chlorido-μ(4)-oxido-tetra­kis­[(3-methyl-5-phenyl-1H-pyrazole-κN (2))copper(II)]
title_full Hexa-μ(2)-chlorido-μ(4)-oxido-tetra­kis­[(3-methyl-5-phenyl-1H-pyrazole-κN (2))copper(II)]
title_fullStr Hexa-μ(2)-chlorido-μ(4)-oxido-tetra­kis­[(3-methyl-5-phenyl-1H-pyrazole-κN (2))copper(II)]
title_full_unstemmed Hexa-μ(2)-chlorido-μ(4)-oxido-tetra­kis­[(3-methyl-5-phenyl-1H-pyrazole-κN (2))copper(II)]
title_short Hexa-μ(2)-chlorido-μ(4)-oxido-tetra­kis­[(3-methyl-5-phenyl-1H-pyrazole-κN (2))copper(II)]
title_sort hexa-μ(2)-chlorido-μ(4)-oxido-tetra­kis­[(3-methyl-5-phenyl-1h-pyrazole-κn (2))copper(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051691/
https://www.ncbi.nlm.nih.gov/pubmed/21522826
http://dx.doi.org/10.1107/S1600536810053663
work_keys_str_mv AT hehongshan hexam2chloridom4oxidotetrakis3methyl5phenyl1hpyrazolekn2copperii

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