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N-{4-[(E)-(4-Methyl­phen­yl)imino­meth­yl]phen­yl}acetamide

There are two symmetry-independent mol­ecules in the asymmetric unit of the title compound, C(16)H(16)N(2)O, that differ in conformation. The dihedral angles between the benzene rings in the two mol­ecules are 44.35 (19) and 48.14 (17)°, but the rings twist in opposite directions. The acetamide grou...

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Detalles Bibliográficos
Autores principales: Tahir, M. Nawaz, Shad, Hazoor Ahmad
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051704/
https://www.ncbi.nlm.nih.gov/pubmed/21523107
http://dx.doi.org/10.1107/S1600536811001887
Descripción
Sumario:There are two symmetry-independent mol­ecules in the asymmetric unit of the title compound, C(16)H(16)N(2)O, that differ in conformation. The dihedral angles between the benzene rings in the two mol­ecules are 44.35 (19) and 48.14 (17)°, but the rings twist in opposite directions. The acetamide groups make nearly equal dihedral angles of 25.4 (3) and 25.7 (3)° with the parent benzene rings. An S(6) ring motif is formed in each mol­ecule by intra­molecular C—H⋯O close contacts. In the crystal, strong N—H⋯O hydrogen bonds between acetamide groups generate a C(4) chain motif arranging the mol­ecules into two symmetry-independent polymeric structures extending along [010].