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Diaquabis[5-(1-oxidopyridin-1-ium-2-yl)-1,2,3,4-tetrazolido]manganese(II) dihydrate
In the title compound, [Mn(C(6)H(4)N(5)O)(2)(H(2)O)(2)]·2H(2)O, the Mn(II) ion is situated on an inversion centre and is coordinated by the O and N atoms of two bis-chelating 5-(2-pyridyl-1-oxide)tetrazolate ligands and two O atoms of two water molecules in a distorted octahedral geometry. All th...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051705/ https://www.ncbi.nlm.nih.gov/pubmed/21522876 http://dx.doi.org/10.1107/S1600536811001620 |
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author | Gao, Feng Yao, Chang-Sheng Lu, Zai-Sheng Shi, Yan-Hui |
author_facet | Gao, Feng Yao, Chang-Sheng Lu, Zai-Sheng Shi, Yan-Hui |
author_sort | Gao, Feng |
collection | PubMed |
description | In the title compound, [Mn(C(6)H(4)N(5)O)(2)(H(2)O)(2)]·2H(2)O, the Mn(II) ion is situated on an inversion centre and is coordinated by the O and N atoms of two bis-chelating 5-(2-pyridyl-1-oxide)tetrazolate ligands and two O atoms of two water molecules in a distorted octahedral geometry. All the water H atoms are involved in O—H⋯N and O—H⋯O hydrogen bonds with uncoordinated water O atoms and tetrazole N atoms, which link the molecules into a three-dimensional network. |
format | Text |
id | pubmed-3051705 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30517052011-04-26 Diaquabis[5-(1-oxidopyridin-1-ium-2-yl)-1,2,3,4-tetrazolido]manganese(II) dihydrate Gao, Feng Yao, Chang-Sheng Lu, Zai-Sheng Shi, Yan-Hui Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Mn(C(6)H(4)N(5)O)(2)(H(2)O)(2)]·2H(2)O, the Mn(II) ion is situated on an inversion centre and is coordinated by the O and N atoms of two bis-chelating 5-(2-pyridyl-1-oxide)tetrazolate ligands and two O atoms of two water molecules in a distorted octahedral geometry. All the water H atoms are involved in O—H⋯N and O—H⋯O hydrogen bonds with uncoordinated water O atoms and tetrazole N atoms, which link the molecules into a three-dimensional network. International Union of Crystallography 2011-01-15 /pmc/articles/PMC3051705/ /pubmed/21522876 http://dx.doi.org/10.1107/S1600536811001620 Text en © Gao et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Gao, Feng Yao, Chang-Sheng Lu, Zai-Sheng Shi, Yan-Hui Diaquabis[5-(1-oxidopyridin-1-ium-2-yl)-1,2,3,4-tetrazolido]manganese(II) dihydrate |
title | Diaquabis[5-(1-oxidopyridin-1-ium-2-yl)-1,2,3,4-tetrazolido]manganese(II) dihydrate |
title_full | Diaquabis[5-(1-oxidopyridin-1-ium-2-yl)-1,2,3,4-tetrazolido]manganese(II) dihydrate |
title_fullStr | Diaquabis[5-(1-oxidopyridin-1-ium-2-yl)-1,2,3,4-tetrazolido]manganese(II) dihydrate |
title_full_unstemmed | Diaquabis[5-(1-oxidopyridin-1-ium-2-yl)-1,2,3,4-tetrazolido]manganese(II) dihydrate |
title_short | Diaquabis[5-(1-oxidopyridin-1-ium-2-yl)-1,2,3,4-tetrazolido]manganese(II) dihydrate |
title_sort | diaquabis[5-(1-oxidopyridin-1-ium-2-yl)-1,2,3,4-tetrazolido]manganese(ii) dihydrate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051705/ https://www.ncbi.nlm.nih.gov/pubmed/21522876 http://dx.doi.org/10.1107/S1600536811001620 |
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