Bis[1-benzyl-3-(quinolin-8-ylmeth­yl)-2,3-dihydro-1H-imidazol-2-yl]dibromido­palladium(II) acetonitrile disolvate

In the title compound, [PdBr(2)(C(20)H(17)N(3))(2)]·2CH(3)CN, the Pd atom, which lies on an inversion center, is four-coordinated in a square-planar geometry. The two imidazole rings are coplanar and nearly perpendicular to the plane formed by Pd, the coordinated imidazole C atom and one of the Br a...

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Detalles Bibliográficos
Autores principales: Sun, Jiafeng, Wang, Guixiang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051708/
https://www.ncbi.nlm.nih.gov/pubmed/21522844
http://dx.doi.org/10.1107/S1600536811000973
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author Sun, Jiafeng
Wang, Guixiang
author_facet Sun, Jiafeng
Wang, Guixiang
author_sort Sun, Jiafeng
collection PubMed
description In the title compound, [PdBr(2)(C(20)H(17)N(3))(2)]·2CH(3)CN, the Pd atom, which lies on an inversion center, is four-coordinated in a square-planar geometry. The two imidazole rings are coplanar and nearly perpendicular to the plane formed by Pd, the coordinated imidazole C atom and one of the Br atoms, making a dihedral angle of 75.1 (2)°.
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spelling pubmed-30517082011-04-26 Bis[1-benzyl-3-(quinolin-8-ylmeth­yl)-2,3-dihydro-1H-imidazol-2-yl]dibromido­palladium(II) acetonitrile disolvate Sun, Jiafeng Wang, Guixiang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [PdBr(2)(C(20)H(17)N(3))(2)]·2CH(3)CN, the Pd atom, which lies on an inversion center, is four-coordinated in a square-planar geometry. The two imidazole rings are coplanar and nearly perpendicular to the plane formed by Pd, the coordinated imidazole C atom and one of the Br atoms, making a dihedral angle of 75.1 (2)°. International Union of Crystallography 2011-01-15 /pmc/articles/PMC3051708/ /pubmed/21522844 http://dx.doi.org/10.1107/S1600536811000973 Text en © Sun and Wang 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Sun, Jiafeng
Wang, Guixiang
Bis[1-benzyl-3-(quinolin-8-ylmeth­yl)-2,3-dihydro-1H-imidazol-2-yl]dibromido­palladium(II) acetonitrile disolvate
title Bis[1-benzyl-3-(quinolin-8-ylmeth­yl)-2,3-dihydro-1H-imidazol-2-yl]dibromido­palladium(II) acetonitrile disolvate
title_full Bis[1-benzyl-3-(quinolin-8-ylmeth­yl)-2,3-dihydro-1H-imidazol-2-yl]dibromido­palladium(II) acetonitrile disolvate
title_fullStr Bis[1-benzyl-3-(quinolin-8-ylmeth­yl)-2,3-dihydro-1H-imidazol-2-yl]dibromido­palladium(II) acetonitrile disolvate
title_full_unstemmed Bis[1-benzyl-3-(quinolin-8-ylmeth­yl)-2,3-dihydro-1H-imidazol-2-yl]dibromido­palladium(II) acetonitrile disolvate
title_short Bis[1-benzyl-3-(quinolin-8-ylmeth­yl)-2,3-dihydro-1H-imidazol-2-yl]dibromido­palladium(II) acetonitrile disolvate
title_sort bis[1-benzyl-3-(quinolin-8-ylmeth­yl)-2,3-dihydro-1h-imidazol-2-yl]dibromido­palladium(ii) acetonitrile disolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051708/
https://www.ncbi.nlm.nih.gov/pubmed/21522844
http://dx.doi.org/10.1107/S1600536811000973
work_keys_str_mv AT sunjiafeng bis1benzyl3quinolin8ylmethyl23dihydro1himidazol2yldibromidopalladiumiiacetonitriledisolvate
AT wangguixiang bis1benzyl3quinolin8ylmethyl23dihydro1himidazol2yldibromidopalladiumiiacetonitriledisolvate

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