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N-(4-Methoxyphenyl)benzenesulfonamide
In the title compound, C(13)H(13)NO(3)S, the benzene ring of the benzenesulfonamide moiety is disordered with an occupancy ratio of 0.56 (3):0.44 (3), the disorder components being twisted at and angle of 21 (1)° to each other. The methoxybenzene group is roughly planar (r.m.s. deviation = 0.0144...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051711/ https://www.ncbi.nlm.nih.gov/pubmed/21522988 http://dx.doi.org/10.1107/S1600536811000365 |
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author | Ibrahim, Saba Tahir, M. Nawaz Iqbal, Nadeem Shahwar, Durre Raza, Muhammad Asam |
author_facet | Ibrahim, Saba Tahir, M. Nawaz Iqbal, Nadeem Shahwar, Durre Raza, Muhammad Asam |
author_sort | Ibrahim, Saba |
collection | PubMed |
description | In the title compound, C(13)H(13)NO(3)S, the benzene ring of the benzenesulfonamide moiety is disordered with an occupancy ratio of 0.56 (3):0.44 (3), the disorder components being twisted at and angle of 21 (1)° to each other. The methoxybenzene group is roughly planar (r.m.s. deviation = 0.0144 Å) and the amide N atom is displaced from this plane by 0.090 (6) Å. The dihedral angles between the methoxybenzene group and the major and minor occupancy components of the disordered benzene ring are 54.6 (4) and 62.9 (5)°, respectively. In the crystal, infinite polymeric chains are formed along [100] due to intermolecular N—H⋯O hydrogen bonding. Weak C—H⋯π interactions are also present in the crystal. |
format | Text |
id | pubmed-3051711 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30517112011-04-26 N-(4-Methoxyphenyl)benzenesulfonamide Ibrahim, Saba Tahir, M. Nawaz Iqbal, Nadeem Shahwar, Durre Raza, Muhammad Asam Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(13)H(13)NO(3)S, the benzene ring of the benzenesulfonamide moiety is disordered with an occupancy ratio of 0.56 (3):0.44 (3), the disorder components being twisted at and angle of 21 (1)° to each other. The methoxybenzene group is roughly planar (r.m.s. deviation = 0.0144 Å) and the amide N atom is displaced from this plane by 0.090 (6) Å. The dihedral angles between the methoxybenzene group and the major and minor occupancy components of the disordered benzene ring are 54.6 (4) and 62.9 (5)°, respectively. In the crystal, infinite polymeric chains are formed along [100] due to intermolecular N—H⋯O hydrogen bonding. Weak C—H⋯π interactions are also present in the crystal. International Union of Crystallography 2011-01-08 /pmc/articles/PMC3051711/ /pubmed/21522988 http://dx.doi.org/10.1107/S1600536811000365 Text en © Ibrahim et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Ibrahim, Saba Tahir, M. Nawaz Iqbal, Nadeem Shahwar, Durre Raza, Muhammad Asam N-(4-Methoxyphenyl)benzenesulfonamide |
title |
N-(4-Methoxyphenyl)benzenesulfonamide |
title_full |
N-(4-Methoxyphenyl)benzenesulfonamide |
title_fullStr |
N-(4-Methoxyphenyl)benzenesulfonamide |
title_full_unstemmed |
N-(4-Methoxyphenyl)benzenesulfonamide |
title_short |
N-(4-Methoxyphenyl)benzenesulfonamide |
title_sort | n-(4-methoxyphenyl)benzenesulfonamide |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051711/ https://www.ncbi.nlm.nih.gov/pubmed/21522988 http://dx.doi.org/10.1107/S1600536811000365 |
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