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N-(4-Meth­oxy­phen­yl)benzene­sulfonamide

In the title compound, C(13)H(13)NO(3)S, the benzene ring of the benzene­sulfonamide moiety is disordered with an occupancy ratio of 0.56 (3):0.44 (3), the disorder components being twisted at and angle of 21 (1)° to each other. The meth­oxy­benzene group is roughly planar (r.m.s. deviation = 0.0144...

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Autores principales: Ibrahim, Saba, Tahir, M. Nawaz, Iqbal, Nadeem, Shahwar, Durre, Raza, Muhammad Asam
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051711/
https://www.ncbi.nlm.nih.gov/pubmed/21522988
http://dx.doi.org/10.1107/S1600536811000365
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author Ibrahim, Saba
Tahir, M. Nawaz
Iqbal, Nadeem
Shahwar, Durre
Raza, Muhammad Asam
author_facet Ibrahim, Saba
Tahir, M. Nawaz
Iqbal, Nadeem
Shahwar, Durre
Raza, Muhammad Asam
author_sort Ibrahim, Saba
collection PubMed
description In the title compound, C(13)H(13)NO(3)S, the benzene ring of the benzene­sulfonamide moiety is disordered with an occupancy ratio of 0.56 (3):0.44 (3), the disorder components being twisted at and angle of 21 (1)° to each other. The meth­oxy­benzene group is roughly planar (r.m.s. deviation = 0.0144 Å) and the amide N atom is displaced from this plane by 0.090 (6) Å. The dihedral angles between the meth­oxy­benzene group and the major and minor occupancy components of the disordered benzene ring are 54.6 (4) and 62.9 (5)°, respectively. In the crystal, infinite polymeric chains are formed along [100] due to inter­molecular N—H⋯O hydrogen bonding. Weak C—H⋯π inter­actions are also present in the crystal.
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spelling pubmed-30517112011-04-26 N-(4-Meth­oxy­phen­yl)benzene­sulfonamide Ibrahim, Saba Tahir, M. Nawaz Iqbal, Nadeem Shahwar, Durre Raza, Muhammad Asam Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(13)H(13)NO(3)S, the benzene ring of the benzene­sulfonamide moiety is disordered with an occupancy ratio of 0.56 (3):0.44 (3), the disorder components being twisted at and angle of 21 (1)° to each other. The meth­oxy­benzene group is roughly planar (r.m.s. deviation = 0.0144 Å) and the amide N atom is displaced from this plane by 0.090 (6) Å. The dihedral angles between the meth­oxy­benzene group and the major and minor occupancy components of the disordered benzene ring are 54.6 (4) and 62.9 (5)°, respectively. In the crystal, infinite polymeric chains are formed along [100] due to inter­molecular N—H⋯O hydrogen bonding. Weak C—H⋯π inter­actions are also present in the crystal. International Union of Crystallography 2011-01-08 /pmc/articles/PMC3051711/ /pubmed/21522988 http://dx.doi.org/10.1107/S1600536811000365 Text en © Ibrahim et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Ibrahim, Saba
Tahir, M. Nawaz
Iqbal, Nadeem
Shahwar, Durre
Raza, Muhammad Asam
N-(4-Meth­oxy­phen­yl)benzene­sulfonamide
title N-(4-Meth­oxy­phen­yl)benzene­sulfonamide
title_full N-(4-Meth­oxy­phen­yl)benzene­sulfonamide
title_fullStr N-(4-Meth­oxy­phen­yl)benzene­sulfonamide
title_full_unstemmed N-(4-Meth­oxy­phen­yl)benzene­sulfonamide
title_short N-(4-Meth­oxy­phen­yl)benzene­sulfonamide
title_sort n-(4-meth­oxy­phen­yl)benzene­sulfonamide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051711/
https://www.ncbi.nlm.nih.gov/pubmed/21522988
http://dx.doi.org/10.1107/S1600536811000365
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