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(2,2′-Bipyridyl-κ(2) N,N′)chlorido(dl-threoninato-κ(2) N,O (1))copper(II) monohydrate
In the title compound, [Cu(C(4)H(8)NO(3))Cl(C(10)H(8)N(2))]·H(2)O, the Cu(II) atom is in a slightly distorted square-pyramidal coordination geometry with the basal plane defined by the two N atoms of the bipyridine ligand and the N and O atoms from the threoninate ion and the apical site occupied by...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051714/ https://www.ncbi.nlm.nih.gov/pubmed/21522913 http://dx.doi.org/10.1107/S1600536811002583 |
Sumario: | In the title compound, [Cu(C(4)H(8)NO(3))Cl(C(10)H(8)N(2))]·H(2)O, the Cu(II) atom is in a slightly distorted square-pyramidal coordination geometry with the basal plane defined by the two N atoms of the bipyridine ligand and the N and O atoms from the threoninate ion and the apical site occupied by the Cl atom. In the crystal, intermolecular O—H⋯O, N—H⋯O, O—H⋯Cl, C—H⋯O and C—H⋯Cl interactions link the molecules into a three-dimensional network. A π–π interaction with a centroid–centroid distance of 3.461 (1) Å is also present. |
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