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(2,2′-Bipyridyl-κ(2) N,N′)chlorido(dl-threoninato-κ(2) N,O (1))copper(II) monohydrate

In the title compound, [Cu(C(4)H(8)NO(3))Cl(C(10)H(8)N(2))]·H(2)O, the Cu(II) atom is in a slightly distorted square-pyramidal coordination geometry with the basal plane defined by the two N atoms of the bipyridine ligand and the N and O atoms from the threoninate ion and the apical site occupied by...

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Autores principales: Tan, Yi-Han, Teoh, Siang-Guan, Rosli, Mohd Mustaqim, Fun, Hoong-Kun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051714/
https://www.ncbi.nlm.nih.gov/pubmed/21522913
http://dx.doi.org/10.1107/S1600536811002583
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author Tan, Yi-Han
Teoh, Siang-Guan
Rosli, Mohd Mustaqim
Fun, Hoong-Kun
author_facet Tan, Yi-Han
Teoh, Siang-Guan
Rosli, Mohd Mustaqim
Fun, Hoong-Kun
author_sort Tan, Yi-Han
collection PubMed
description In the title compound, [Cu(C(4)H(8)NO(3))Cl(C(10)H(8)N(2))]·H(2)O, the Cu(II) atom is in a slightly distorted square-pyramidal coordination geometry with the basal plane defined by the two N atoms of the bipyridine ligand and the N and O atoms from the threoninate ion and the apical site occupied by the Cl atom. In the crystal, inter­molecular O—H⋯O, N—H⋯O, O—H⋯Cl, C—H⋯O and C—H⋯Cl inter­actions link the mol­ecules into a three-dimensional network. A π–π inter­action with a centroid–centroid distance of 3.461 (1) Å is also present.
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spelling pubmed-30517142011-04-26 (2,2′-Bipyridyl-κ(2) N,N′)chlorido(dl-threoninato-κ(2) N,O (1))copper(II) monohydrate Tan, Yi-Han Teoh, Siang-Guan Rosli, Mohd Mustaqim Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(C(4)H(8)NO(3))Cl(C(10)H(8)N(2))]·H(2)O, the Cu(II) atom is in a slightly distorted square-pyramidal coordination geometry with the basal plane defined by the two N atoms of the bipyridine ligand and the N and O atoms from the threoninate ion and the apical site occupied by the Cl atom. In the crystal, inter­molecular O—H⋯O, N—H⋯O, O—H⋯Cl, C—H⋯O and C—H⋯Cl inter­actions link the mol­ecules into a three-dimensional network. A π–π inter­action with a centroid–centroid distance of 3.461 (1) Å is also present. International Union of Crystallography 2011-01-26 /pmc/articles/PMC3051714/ /pubmed/21522913 http://dx.doi.org/10.1107/S1600536811002583 Text en © Tan et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Tan, Yi-Han
Teoh, Siang-Guan
Rosli, Mohd Mustaqim
Fun, Hoong-Kun
(2,2′-Bipyridyl-κ(2) N,N′)chlorido(dl-threoninato-κ(2) N,O (1))copper(II) monohydrate
title (2,2′-Bipyridyl-κ(2) N,N′)chlorido(dl-threoninato-κ(2) N,O (1))copper(II) monohydrate
title_full (2,2′-Bipyridyl-κ(2) N,N′)chlorido(dl-threoninato-κ(2) N,O (1))copper(II) monohydrate
title_fullStr (2,2′-Bipyridyl-κ(2) N,N′)chlorido(dl-threoninato-κ(2) N,O (1))copper(II) monohydrate
title_full_unstemmed (2,2′-Bipyridyl-κ(2) N,N′)chlorido(dl-threoninato-κ(2) N,O (1))copper(II) monohydrate
title_short (2,2′-Bipyridyl-κ(2) N,N′)chlorido(dl-threoninato-κ(2) N,O (1))copper(II) monohydrate
title_sort (2,2′-bipyridyl-κ(2) n,n′)chlorido(dl-threoninato-κ(2) n,o (1))copper(ii) monohydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051714/
https://www.ncbi.nlm.nih.gov/pubmed/21522913
http://dx.doi.org/10.1107/S1600536811002583
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