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(2,2′-Bipyridyl-κ(2) N,N′)chlorido(dl-threoninato-κ(2) N,O (1))copper(II) monohydrate
In the title compound, [Cu(C(4)H(8)NO(3))Cl(C(10)H(8)N(2))]·H(2)O, the Cu(II) atom is in a slightly distorted square-pyramidal coordination geometry with the basal plane defined by the two N atoms of the bipyridine ligand and the N and O atoms from the threoninate ion and the apical site occupied by...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051714/ https://www.ncbi.nlm.nih.gov/pubmed/21522913 http://dx.doi.org/10.1107/S1600536811002583 |
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author | Tan, Yi-Han Teoh, Siang-Guan Rosli, Mohd Mustaqim Fun, Hoong-Kun |
author_facet | Tan, Yi-Han Teoh, Siang-Guan Rosli, Mohd Mustaqim Fun, Hoong-Kun |
author_sort | Tan, Yi-Han |
collection | PubMed |
description | In the title compound, [Cu(C(4)H(8)NO(3))Cl(C(10)H(8)N(2))]·H(2)O, the Cu(II) atom is in a slightly distorted square-pyramidal coordination geometry with the basal plane defined by the two N atoms of the bipyridine ligand and the N and O atoms from the threoninate ion and the apical site occupied by the Cl atom. In the crystal, intermolecular O—H⋯O, N—H⋯O, O—H⋯Cl, C—H⋯O and C—H⋯Cl interactions link the molecules into a three-dimensional network. A π–π interaction with a centroid–centroid distance of 3.461 (1) Å is also present. |
format | Text |
id | pubmed-3051714 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30517142011-04-26 (2,2′-Bipyridyl-κ(2) N,N′)chlorido(dl-threoninato-κ(2) N,O (1))copper(II) monohydrate Tan, Yi-Han Teoh, Siang-Guan Rosli, Mohd Mustaqim Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(C(4)H(8)NO(3))Cl(C(10)H(8)N(2))]·H(2)O, the Cu(II) atom is in a slightly distorted square-pyramidal coordination geometry with the basal plane defined by the two N atoms of the bipyridine ligand and the N and O atoms from the threoninate ion and the apical site occupied by the Cl atom. In the crystal, intermolecular O—H⋯O, N—H⋯O, O—H⋯Cl, C—H⋯O and C—H⋯Cl interactions link the molecules into a three-dimensional network. A π–π interaction with a centroid–centroid distance of 3.461 (1) Å is also present. International Union of Crystallography 2011-01-26 /pmc/articles/PMC3051714/ /pubmed/21522913 http://dx.doi.org/10.1107/S1600536811002583 Text en © Tan et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Tan, Yi-Han Teoh, Siang-Guan Rosli, Mohd Mustaqim Fun, Hoong-Kun (2,2′-Bipyridyl-κ(2) N,N′)chlorido(dl-threoninato-κ(2) N,O (1))copper(II) monohydrate |
title | (2,2′-Bipyridyl-κ(2)
N,N′)chlorido(dl-threoninato-κ(2)
N,O
(1))copper(II) monohydrate |
title_full | (2,2′-Bipyridyl-κ(2)
N,N′)chlorido(dl-threoninato-κ(2)
N,O
(1))copper(II) monohydrate |
title_fullStr | (2,2′-Bipyridyl-κ(2)
N,N′)chlorido(dl-threoninato-κ(2)
N,O
(1))copper(II) monohydrate |
title_full_unstemmed | (2,2′-Bipyridyl-κ(2)
N,N′)chlorido(dl-threoninato-κ(2)
N,O
(1))copper(II) monohydrate |
title_short | (2,2′-Bipyridyl-κ(2)
N,N′)chlorido(dl-threoninato-κ(2)
N,O
(1))copper(II) monohydrate |
title_sort | (2,2′-bipyridyl-κ(2)
n,n′)chlorido(dl-threoninato-κ(2)
n,o
(1))copper(ii) monohydrate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051714/ https://www.ncbi.nlm.nih.gov/pubmed/21522913 http://dx.doi.org/10.1107/S1600536811002583 |
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