(1,4,7,10,13,16-Hexaoxacyclo­octa­deca­ne)dimethyl­indium(III) trifluoro­methane­sulfonate

In the title compound, [In(CH(3))(2)(C(12)H(24)O(6))](CF(3)O(3)S), two of the In—O distances within the cation are significantly shorter than the other four. The In(III) atom is in a distorted hexa­gonal–bipyramidal coordination geometry in which the C—In—C angle is 175.44 (12)°. The crystal structu...

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Detalles Bibliográficos
Autores principales: Cooper, Benjamin F. T., Macdonald, Charles L. B.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051716/
https://www.ncbi.nlm.nih.gov/pubmed/21522890
http://dx.doi.org/10.1107/S1600536811001899
Descripción
Sumario:In the title compound, [In(CH(3))(2)(C(12)H(24)O(6))](CF(3)O(3)S), two of the In—O distances within the cation are significantly shorter than the other four. The In(III) atom is in a distorted hexa­gonal–bipyramidal coordination geometry in which the C—In—C angle is 175.44 (12)°. The crystal structure is stabilized by weak inter­molecular C—H⋯O hydrogen bonds.

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