(1,4,7,10,13,16-Hexaoxacyclo­octa­deca­ne)dimethyl­indium(III) trifluoro­methane­sulfonate

In the title compound, [In(CH(3))(2)(C(12)H(24)O(6))](CF(3)O(3)S), two of the In—O distances within the cation are significantly shorter than the other four. The In(III) atom is in a distorted hexa­gonal–bipyramidal coordination geometry in which the C—In—C angle is 175.44 (12)°. The crystal structu...

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Detalles Bibliográficos
Autores principales: Cooper, Benjamin F. T., Macdonald, Charles L. B.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051716/
https://www.ncbi.nlm.nih.gov/pubmed/21522890
http://dx.doi.org/10.1107/S1600536811001899
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author Cooper, Benjamin F. T.
Macdonald, Charles L. B.
author_facet Cooper, Benjamin F. T.
Macdonald, Charles L. B.
author_sort Cooper, Benjamin F. T.
collection PubMed
description In the title compound, [In(CH(3))(2)(C(12)H(24)O(6))](CF(3)O(3)S), two of the In—O distances within the cation are significantly shorter than the other four. The In(III) atom is in a distorted hexa­gonal–bipyramidal coordination geometry in which the C—In—C angle is 175.44 (12)°. The crystal structure is stabilized by weak inter­molecular C—H⋯O hydrogen bonds.
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spelling pubmed-30517162011-04-26 (1,4,7,10,13,16-Hexaoxacyclo­octa­deca­ne)dimethyl­indium(III) trifluoro­methane­sulfonate Cooper, Benjamin F. T. Macdonald, Charles L. B. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [In(CH(3))(2)(C(12)H(24)O(6))](CF(3)O(3)S), two of the In—O distances within the cation are significantly shorter than the other four. The In(III) atom is in a distorted hexa­gonal–bipyramidal coordination geometry in which the C—In—C angle is 175.44 (12)°. The crystal structure is stabilized by weak inter­molecular C—H⋯O hydrogen bonds. International Union of Crystallography 2011-01-22 /pmc/articles/PMC3051716/ /pubmed/21522890 http://dx.doi.org/10.1107/S1600536811001899 Text en © Cooper and Macdonald 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Cooper, Benjamin F. T.
Macdonald, Charles L. B.
(1,4,7,10,13,16-Hexaoxacyclo­octa­deca­ne)dimethyl­indium(III) trifluoro­methane­sulfonate
title (1,4,7,10,13,16-Hexaoxacyclo­octa­deca­ne)dimethyl­indium(III) trifluoro­methane­sulfonate
title_full (1,4,7,10,13,16-Hexaoxacyclo­octa­deca­ne)dimethyl­indium(III) trifluoro­methane­sulfonate
title_fullStr (1,4,7,10,13,16-Hexaoxacyclo­octa­deca­ne)dimethyl­indium(III) trifluoro­methane­sulfonate
title_full_unstemmed (1,4,7,10,13,16-Hexaoxacyclo­octa­deca­ne)dimethyl­indium(III) trifluoro­methane­sulfonate
title_short (1,4,7,10,13,16-Hexaoxacyclo­octa­deca­ne)dimethyl­indium(III) trifluoro­methane­sulfonate
title_sort (1,4,7,10,13,16-hexaoxacyclo­octa­deca­ne)dimethyl­indium(iii) trifluoro­methane­sulfonate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051716/
https://www.ncbi.nlm.nih.gov/pubmed/21522890
http://dx.doi.org/10.1107/S1600536811001899
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