meso-5,5′-Bis[(4-fluoro­phen­yl)diazen­yl]-2,2′-(pentane-3,3-di­yl)di-1H-pyrrole

There are two independent molecules in the asymmetric unit of the title compound, C(25)H(24)F(2)N(6), in which the N=N bonds adopt a trans configuration with distances in the range 1.262 (2)–1.269 (3) Å. The dihedral angles between heterocycles are 86.7 (2) and 85.6 (2)° in the two molecules while t...

Descripción completa

Detalles Bibliográficos
Autores principales: Li, Boyang, Zhang, Guilong, Sun, Shipeng, Yin, Zhenming
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051718/
https://www.ncbi.nlm.nih.gov/pubmed/21522941
http://dx.doi.org/10.1107/S1600536810053535
_version_ 1782199545690587136
author Li, Boyang
Zhang, Guilong
Sun, Shipeng
Yin, Zhenming
author_facet Li, Boyang
Zhang, Guilong
Sun, Shipeng
Yin, Zhenming
author_sort Li, Boyang
collection PubMed
description There are two independent molecules in the asymmetric unit of the title compound, C(25)H(24)F(2)N(6), in which the N=N bonds adopt a trans configuration with distances in the range 1.262 (2)–1.269 (3) Å. The dihedral angles between heterocycles are 86.7 (2) and 85.6 (2)° in the two molecules while the dihedral angles between the heterocylic rings and the adjacent benzene rings are 13.4 (2) and 13.4 (2)° in one molecule and 5.3 (2) and 6.5 (2)° in the other. In the crystal, pairs of independent mol­ecules are held together by four N—H⋯N hydrogen bonds, forming inter­locked dimers.
format Text
id pubmed-3051718
institution National Center for Biotechnology Information
language English
publishDate 2011
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-30517182011-04-26 meso-5,5′-Bis[(4-fluoro­phen­yl)diazen­yl]-2,2′-(pentane-3,3-di­yl)di-1H-pyrrole Li, Boyang Zhang, Guilong Sun, Shipeng Yin, Zhenming Acta Crystallogr Sect E Struct Rep Online Organic Papers There are two independent molecules in the asymmetric unit of the title compound, C(25)H(24)F(2)N(6), in which the N=N bonds adopt a trans configuration with distances in the range 1.262 (2)–1.269 (3) Å. The dihedral angles between heterocycles are 86.7 (2) and 85.6 (2)° in the two molecules while the dihedral angles between the heterocylic rings and the adjacent benzene rings are 13.4 (2) and 13.4 (2)° in one molecule and 5.3 (2) and 6.5 (2)° in the other. In the crystal, pairs of independent mol­ecules are held together by four N—H⋯N hydrogen bonds, forming inter­locked dimers. International Union of Crystallography 2011-01-08 /pmc/articles/PMC3051718/ /pubmed/21522941 http://dx.doi.org/10.1107/S1600536810053535 Text en © Li et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Li, Boyang
Zhang, Guilong
Sun, Shipeng
Yin, Zhenming
meso-5,5′-Bis[(4-fluoro­phen­yl)diazen­yl]-2,2′-(pentane-3,3-di­yl)di-1H-pyrrole
title meso-5,5′-Bis[(4-fluoro­phen­yl)diazen­yl]-2,2′-(pentane-3,3-di­yl)di-1H-pyrrole
title_full meso-5,5′-Bis[(4-fluoro­phen­yl)diazen­yl]-2,2′-(pentane-3,3-di­yl)di-1H-pyrrole
title_fullStr meso-5,5′-Bis[(4-fluoro­phen­yl)diazen­yl]-2,2′-(pentane-3,3-di­yl)di-1H-pyrrole
title_full_unstemmed meso-5,5′-Bis[(4-fluoro­phen­yl)diazen­yl]-2,2′-(pentane-3,3-di­yl)di-1H-pyrrole
title_short meso-5,5′-Bis[(4-fluoro­phen­yl)diazen­yl]-2,2′-(pentane-3,3-di­yl)di-1H-pyrrole
title_sort meso-5,5′-bis[(4-fluoro­phen­yl)diazen­yl]-2,2′-(pentane-3,3-di­yl)di-1h-pyrrole
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051718/
https://www.ncbi.nlm.nih.gov/pubmed/21522941
http://dx.doi.org/10.1107/S1600536810053535
work_keys_str_mv AT liboyang meso55bis4fluorophenyldiazenyl22pentane33diyldi1hpyrrole
AT zhangguilong meso55bis4fluorophenyldiazenyl22pentane33diyldi1hpyrrole
AT sunshipeng meso55bis4fluorophenyldiazenyl22pentane33diyldi1hpyrrole
AT yinzhenming meso55bis4fluorophenyldiazenyl22pentane33diyldi1hpyrrole

Ejemplares similares