2-Methyl-1,3-benzoxazol-4-yl diphenyl­phosphinate

The title compound, C(20)H(16)NO(3)P, was synthesized by the addition of diphenyl­phosphine chloride to a tetra­hydro­furan solution of Et(3)N and 2-methyl-1,3-benzoxazol-4-ol at 233 K. In the mol­ecule, the almost planar (r.m.s. deviation = 0.010 Å) benzoxazole moiety is attached to the slightly di...

Descripción completa

Detalles Bibliográficos
Autor principal: Kleinhans, Dewald J.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051727/
https://www.ncbi.nlm.nih.gov/pubmed/21523022
http://dx.doi.org/10.1107/S1600536811000420
_version_ 1782199547831779328
author Kleinhans, Dewald J.
author_facet Kleinhans, Dewald J.
author_sort Kleinhans, Dewald J.
collection PubMed
description The title compound, C(20)H(16)NO(3)P, was synthesized by the addition of diphenyl­phosphine chloride to a tetra­hydro­furan solution of Et(3)N and 2-methyl-1,3-benzoxazol-4-ol at 233 K. In the mol­ecule, the almost planar (r.m.s. deviation = 0.010 Å) benzoxazole moiety is attached to the slightly distorted tetra­hedral P atom [C—P—C—C torsion angle = 132.20 (18)°]. The crystal structure does not exhibit any significant inter­molecular inter­actions.
format Text
id pubmed-3051727
institution National Center for Biotechnology Information
language English
publishDate 2011
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-30517272011-04-26 2-Methyl-1,3-benzoxazol-4-yl diphenyl­phosphinate Kleinhans, Dewald J. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(20)H(16)NO(3)P, was synthesized by the addition of diphenyl­phosphine chloride to a tetra­hydro­furan solution of Et(3)N and 2-methyl-1,3-benzoxazol-4-ol at 233 K. In the mol­ecule, the almost planar (r.m.s. deviation = 0.010 Å) benzoxazole moiety is attached to the slightly distorted tetra­hedral P atom [C—P—C—C torsion angle = 132.20 (18)°]. The crystal structure does not exhibit any significant inter­molecular inter­actions. International Union of Crystallography 2011-01-12 /pmc/articles/PMC3051727/ /pubmed/21523022 http://dx.doi.org/10.1107/S1600536811000420 Text en © Dewald J. Kleinhans 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Kleinhans, Dewald J.
2-Methyl-1,3-benzoxazol-4-yl diphenyl­phosphinate
title 2-Methyl-1,3-benzoxazol-4-yl diphenyl­phosphinate
title_full 2-Methyl-1,3-benzoxazol-4-yl diphenyl­phosphinate
title_fullStr 2-Methyl-1,3-benzoxazol-4-yl diphenyl­phosphinate
title_full_unstemmed 2-Methyl-1,3-benzoxazol-4-yl diphenyl­phosphinate
title_short 2-Methyl-1,3-benzoxazol-4-yl diphenyl­phosphinate
title_sort 2-methyl-1,3-benzoxazol-4-yl diphenyl­phosphinate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051727/
https://www.ncbi.nlm.nih.gov/pubmed/21523022
http://dx.doi.org/10.1107/S1600536811000420
work_keys_str_mv AT kleinhansdewaldj 2methyl13benzoxazol4yldiphenylphosphinate

Ejemplares similares