Bis{benzyl 3-[(1H-indol-3-yl)methyl­idene]dithio­carbazato-κ(2) N (3),S}palladium(II) pyridine disolvate

The Pd(II) ion in the title compound, [Pd(C(17)H(14)N(3)S(2))(2)]·2C(5)H(5)N, is located on an inversion center and is four-coordinated by two of the deprotonated N,S-bidentate Schiff base ligands in a square-planar geometry. The dihedral angle between the aromatic ring planes within the ligand is 7...

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Detalles Bibliográficos
Autores principales: Khaledi, Hamid, Mohd Ali, Hapipah
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051733/
https://www.ncbi.nlm.nih.gov/pubmed/21522888
http://dx.doi.org/10.1107/S1600536811001991
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author Khaledi, Hamid
Mohd Ali, Hapipah
author_facet Khaledi, Hamid
Mohd Ali, Hapipah
author_sort Khaledi, Hamid
collection PubMed
description The Pd(II) ion in the title compound, [Pd(C(17)H(14)N(3)S(2))(2)]·2C(5)H(5)N, is located on an inversion center and is four-coordinated by two of the deprotonated N,S-bidentate Schiff base ligands in a square-planar geometry. The dihedral angle between the aromatic ring planes within the ligand is 71.12 (9)°. The indole NH groups are bonded to the pyridine solvent mol­ecules via an N—H⋯N inter­action. The crystal structure is consolidated by inter­molecular C—H⋯S inter­actions.
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spelling pubmed-30517332011-04-26 Bis{benzyl 3-[(1H-indol-3-yl)methyl­idene]dithio­carbazato-κ(2) N (3),S}palladium(II) pyridine disolvate Khaledi, Hamid Mohd Ali, Hapipah Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Pd(II) ion in the title compound, [Pd(C(17)H(14)N(3)S(2))(2)]·2C(5)H(5)N, is located on an inversion center and is four-coordinated by two of the deprotonated N,S-bidentate Schiff base ligands in a square-planar geometry. The dihedral angle between the aromatic ring planes within the ligand is 71.12 (9)°. The indole NH groups are bonded to the pyridine solvent mol­ecules via an N—H⋯N inter­action. The crystal structure is consolidated by inter­molecular C—H⋯S inter­actions. International Union of Crystallography 2011-01-22 /pmc/articles/PMC3051733/ /pubmed/21522888 http://dx.doi.org/10.1107/S1600536811001991 Text en © Khaledi and Mohd Ali 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Khaledi, Hamid
Mohd Ali, Hapipah
Bis{benzyl 3-[(1H-indol-3-yl)methyl­idene]dithio­carbazato-κ(2) N (3),S}palladium(II) pyridine disolvate
title Bis{benzyl 3-[(1H-indol-3-yl)methyl­idene]dithio­carbazato-κ(2) N (3),S}palladium(II) pyridine disolvate
title_full Bis{benzyl 3-[(1H-indol-3-yl)methyl­idene]dithio­carbazato-κ(2) N (3),S}palladium(II) pyridine disolvate
title_fullStr Bis{benzyl 3-[(1H-indol-3-yl)methyl­idene]dithio­carbazato-κ(2) N (3),S}palladium(II) pyridine disolvate
title_full_unstemmed Bis{benzyl 3-[(1H-indol-3-yl)methyl­idene]dithio­carbazato-κ(2) N (3),S}palladium(II) pyridine disolvate
title_short Bis{benzyl 3-[(1H-indol-3-yl)methyl­idene]dithio­carbazato-κ(2) N (3),S}palladium(II) pyridine disolvate
title_sort bis{benzyl 3-[(1h-indol-3-yl)methyl­idene]dithio­carbazato-κ(2) n (3),s}palladium(ii) pyridine disolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051733/
https://www.ncbi.nlm.nih.gov/pubmed/21522888
http://dx.doi.org/10.1107/S1600536811001991
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AT mohdalihapipah bisbenzyl31hindol3ylmethylidenedithiocarbazatok2n3spalladiumiipyridinedisolvate

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