8-Hy­droxy-2-methyl­quinolinium tetra­chlorido(quinolin-2-olato-κ(2) N,O)stannate(IV) methanol disolvate

In the reaction of 8-hy­droxy­quinoline, 2-methyl-8-hy­droxy­quinoline and stannic chloride, the 2-methyl-8-hy­droxy­quinoline is protonated, yielding the disolvated title salt, (C(10)H(10)NO)[SnCl(4)(C(9)H(6)NO)]·2CH(3)OH. The Sn(IV) atom in the anion is N,O-chelated by the hy­droxy­quinolinate in...

Descripción completa

Detalles Bibliográficos
Autores principales: Najafi, Ezzatollah, Amini, Mostafa M., Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051736/
https://www.ncbi.nlm.nih.gov/pubmed/21522896
http://dx.doi.org/10.1107/S1600536811001954
Descripción
Sumario:In the reaction of 8-hy­droxy­quinoline, 2-methyl-8-hy­droxy­quinoline and stannic chloride, the 2-methyl-8-hy­droxy­quinoline is protonated, yielding the disolvated title salt, (C(10)H(10)NO)[SnCl(4)(C(9)H(6)NO)]·2CH(3)OH. The Sn(IV) atom in the anion is N,O-chelated by the hy­droxy­quinolinate in a cis-SnNOCl(4) octa­hedral geometry. In the crystal, the cation, anion and solvent mol­ecules are linked by N—H⋯O, O—H⋯O and O—H⋯Cl hydrogen bonds, generating a three-dimensional network.

Ejemplares similares