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8-Hydroxy-2-methylquinolinium tetrachlorido(quinolin-2-olato-κ(2) N,O)stannate(IV) methanol disolvate
In the reaction of 8-hydroxyquinoline, 2-methyl-8-hydroxyquinoline and stannic chloride, the 2-methyl-8-hydroxyquinoline is protonated, yielding the disolvated title salt, (C(10)H(10)NO)[SnCl(4)(C(9)H(6)NO)]·2CH(3)OH. The Sn(IV) atom in the anion is N,O-chelated by the hydroxyquinolinate in...
| Autores principales: | , , |
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| Formato: | Texto |
| Lenguaje: | English |
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International Union of Crystallography
2011
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051736/ https://www.ncbi.nlm.nih.gov/pubmed/21522896 http://dx.doi.org/10.1107/S1600536811001954 |
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| author | Najafi, Ezzatollah Amini, Mostafa M. Ng, Seik Weng |
| author_facet | Najafi, Ezzatollah Amini, Mostafa M. Ng, Seik Weng |
| author_sort | Najafi, Ezzatollah |
| collection | PubMed |
| description | In the reaction of 8-hydroxyquinoline, 2-methyl-8-hydroxyquinoline and stannic chloride, the 2-methyl-8-hydroxyquinoline is protonated, yielding the disolvated title salt, (C(10)H(10)NO)[SnCl(4)(C(9)H(6)NO)]·2CH(3)OH. The Sn(IV) atom in the anion is N,O-chelated by the hydroxyquinolinate in a cis-SnNOCl(4) octahedral geometry. In the crystal, the cation, anion and solvent molecules are linked by N—H⋯O, O—H⋯O and O—H⋯Cl hydrogen bonds, generating a three-dimensional network. |
| format | Text |
| id | pubmed-3051736 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-30517362011-04-26 8-Hydroxy-2-methylquinolinium tetrachlorido(quinolin-2-olato-κ(2) N,O)stannate(IV) methanol disolvate Najafi, Ezzatollah Amini, Mostafa M. Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the reaction of 8-hydroxyquinoline, 2-methyl-8-hydroxyquinoline and stannic chloride, the 2-methyl-8-hydroxyquinoline is protonated, yielding the disolvated title salt, (C(10)H(10)NO)[SnCl(4)(C(9)H(6)NO)]·2CH(3)OH. The Sn(IV) atom in the anion is N,O-chelated by the hydroxyquinolinate in a cis-SnNOCl(4) octahedral geometry. In the crystal, the cation, anion and solvent molecules are linked by N—H⋯O, O—H⋯O and O—H⋯Cl hydrogen bonds, generating a three-dimensional network. International Union of Crystallography 2011-01-22 /pmc/articles/PMC3051736/ /pubmed/21522896 http://dx.doi.org/10.1107/S1600536811001954 Text en © Najafi et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Najafi, Ezzatollah Amini, Mostafa M. Ng, Seik Weng 8-Hydroxy-2-methylquinolinium tetrachlorido(quinolin-2-olato-κ(2) N,O)stannate(IV) methanol disolvate |
| title | 8-Hydroxy-2-methylquinolinium tetrachlorido(quinolin-2-olato-κ(2)
N,O)stannate(IV) methanol disolvate |
| title_full | 8-Hydroxy-2-methylquinolinium tetrachlorido(quinolin-2-olato-κ(2)
N,O)stannate(IV) methanol disolvate |
| title_fullStr | 8-Hydroxy-2-methylquinolinium tetrachlorido(quinolin-2-olato-κ(2)
N,O)stannate(IV) methanol disolvate |
| title_full_unstemmed | 8-Hydroxy-2-methylquinolinium tetrachlorido(quinolin-2-olato-κ(2)
N,O)stannate(IV) methanol disolvate |
| title_short | 8-Hydroxy-2-methylquinolinium tetrachlorido(quinolin-2-olato-κ(2)
N,O)stannate(IV) methanol disolvate |
| title_sort | 8-hydroxy-2-methylquinolinium tetrachlorido(quinolin-2-olato-κ(2)
n,o)stannate(iv) methanol disolvate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051736/ https://www.ncbi.nlm.nih.gov/pubmed/21522896 http://dx.doi.org/10.1107/S1600536811001954 |
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