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Di-μ-methanolato-κ(4) O:O-bis[trichlorido(dimethylformamide-κO)tin(IV)]
The title compound, [Sn(2)(CH(3)O)(2)Cl(6)(C(3)H(7)NO)(2)], contains two hexacoordinated Sn(IV) atoms symmetrically bridged by two deprotonated methanol ligands, with an inversion center in the middle of the planar Sn(2)O(2) ring. The other sites of the distorted octahedral coordination geometry o...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051740/ https://www.ncbi.nlm.nih.gov/pubmed/21522830 http://dx.doi.org/10.1107/S1600536810053997 |
Sumario: | The title compound, [Sn(2)(CH(3)O)(2)Cl(6)(C(3)H(7)NO)(2)], contains two hexacoordinated Sn(IV) atoms symmetrically bridged by two deprotonated methanol ligands, with an inversion center in the middle of the planar Sn(2)O(2) ring. The other sites of the distorted octahedral coordination geometry of the Sn(IV) atom are occupied by three Cl atoms and one O atom from a dimethylformamide molecule. The complex molecules are connected by weak C—H⋯Cl hydrogen bonds into a two-dimensional supramolecular network parallel to (10[Image: see text]). |
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