Di-μ-methanolato-κ(4) O:O-bis[tri­chlorido(dimethyl­formamide-κO)tin(IV)]

The title compound, [Sn(2)(CH(3)O)(2)Cl(6)(C(3)H(7)NO)(2)], contains two hexa­coordinated Sn(IV) atoms symmetrically bridged by two deprotonated methanol ligands, with an inversion center in the middle of the planar Sn(2)O(2) ring. The other sites of the distorted octa­hedral coordination geometry o...

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Detalles Bibliográficos
Autores principales: Zhang, Qijun, Yin, Handong, Wang, Daqi
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051740/
https://www.ncbi.nlm.nih.gov/pubmed/21522830
http://dx.doi.org/10.1107/S1600536810053997
Descripción
Sumario:The title compound, [Sn(2)(CH(3)O)(2)Cl(6)(C(3)H(7)NO)(2)], contains two hexa­coordinated Sn(IV) atoms symmetrically bridged by two deprotonated methanol ligands, with an inversion center in the middle of the planar Sn(2)O(2) ring. The other sites of the distorted octa­hedral coordination geometry of the Sn(IV) atom are occupied by three Cl atoms and one O atom from a dimethyl­formamide mol­ecule. The complex mol­ecules are connected by weak C—H⋯Cl hydrogen bonds into a two-dimensional supra­molecular network parallel to (10[Image: see text]).

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