Di-μ-methanolato-κ(4) O:O-bis[tri­chlorido(dimethyl­formamide-κO)tin(IV)]

The title compound, [Sn(2)(CH(3)O)(2)Cl(6)(C(3)H(7)NO)(2)], contains two hexa­coordinated Sn(IV) atoms symmetrically bridged by two deprotonated methanol ligands, with an inversion center in the middle of the planar Sn(2)O(2) ring. The other sites of the distorted octa­hedral coordination geometry o...

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Detalles Bibliográficos
Autores principales: Zhang, Qijun, Yin, Handong, Wang, Daqi
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051740/
https://www.ncbi.nlm.nih.gov/pubmed/21522830
http://dx.doi.org/10.1107/S1600536810053997
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author Zhang, Qijun
Yin, Handong
Wang, Daqi
author_facet Zhang, Qijun
Yin, Handong
Wang, Daqi
author_sort Zhang, Qijun
collection PubMed
description The title compound, [Sn(2)(CH(3)O)(2)Cl(6)(C(3)H(7)NO)(2)], contains two hexa­coordinated Sn(IV) atoms symmetrically bridged by two deprotonated methanol ligands, with an inversion center in the middle of the planar Sn(2)O(2) ring. The other sites of the distorted octa­hedral coordination geometry of the Sn(IV) atom are occupied by three Cl atoms and one O atom from a dimethyl­formamide mol­ecule. The complex mol­ecules are connected by weak C—H⋯Cl hydrogen bonds into a two-dimensional supra­molecular network parallel to (10[Image: see text]).
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spelling pubmed-30517402011-04-26 Di-μ-methanolato-κ(4) O:O-bis[tri­chlorido(dimethyl­formamide-κO)tin(IV)] Zhang, Qijun Yin, Handong Wang, Daqi Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Sn(2)(CH(3)O)(2)Cl(6)(C(3)H(7)NO)(2)], contains two hexa­coordinated Sn(IV) atoms symmetrically bridged by two deprotonated methanol ligands, with an inversion center in the middle of the planar Sn(2)O(2) ring. The other sites of the distorted octa­hedral coordination geometry of the Sn(IV) atom are occupied by three Cl atoms and one O atom from a dimethyl­formamide mol­ecule. The complex mol­ecules are connected by weak C—H⋯Cl hydrogen bonds into a two-dimensional supra­molecular network parallel to (10[Image: see text]). International Union of Crystallography 2011-01-08 /pmc/articles/PMC3051740/ /pubmed/21522830 http://dx.doi.org/10.1107/S1600536810053997 Text en © Zhang et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhang, Qijun
Yin, Handong
Wang, Daqi
Di-μ-methanolato-κ(4) O:O-bis[tri­chlorido(dimethyl­formamide-κO)tin(IV)]
title Di-μ-methanolato-κ(4) O:O-bis[tri­chlorido(dimethyl­formamide-κO)tin(IV)]
title_full Di-μ-methanolato-κ(4) O:O-bis[tri­chlorido(dimethyl­formamide-κO)tin(IV)]
title_fullStr Di-μ-methanolato-κ(4) O:O-bis[tri­chlorido(dimethyl­formamide-κO)tin(IV)]
title_full_unstemmed Di-μ-methanolato-κ(4) O:O-bis[tri­chlorido(dimethyl­formamide-κO)tin(IV)]
title_short Di-μ-methanolato-κ(4) O:O-bis[tri­chlorido(dimethyl­formamide-κO)tin(IV)]
title_sort di-μ-methanolato-κ(4) o:o-bis[tri­chlorido(dimethyl­formamide-κo)tin(iv)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051740/
https://www.ncbi.nlm.nih.gov/pubmed/21522830
http://dx.doi.org/10.1107/S1600536810053997
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AT yinhandong dimmethanolatok4oobistrichloridodimethylformamidekotiniv
AT wangdaqi dimmethanolatok4oobistrichloridodimethylformamidekotiniv

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