2-{2-[(2,6-Dichloro­phen­yl)amino]­phen­yl}ethanol

In the title compound, C(14)H(13)Cl(2)NO, the 2,6-dichloro­anilino unit is roughly planar (r.m.s. deviation = 0.0298 Å) and makes a dihedral angle of 67.71 (4)° with the benzene ring containing the ethanol group. The C–C–O fragment is oriented at a dihedral angle of 64.94 (9)° with respect to its pa...

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Detalles Bibliográficos
Autores principales: Nasirullah, Ul Islam, Nazar, Tahir, M. Nawaz, Khan, Ikhtiar
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051747/
https://www.ncbi.nlm.nih.gov/pubmed/21522965
http://dx.doi.org/10.1107/S1600536810054590
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author Nasirullah,
Ul Islam, Nazar
Tahir, M. Nawaz
Khan, Ikhtiar
author_facet Nasirullah,
Ul Islam, Nazar
Tahir, M. Nawaz
Khan, Ikhtiar
author_sort Nasirullah,
collection PubMed
description In the title compound, C(14)H(13)Cl(2)NO, the 2,6-dichloro­anilino unit is roughly planar (r.m.s. deviation = 0.0298 Å) and makes a dihedral angle of 67.71 (4)° with the benzene ring containing the ethanol group. The C–C–O fragment is oriented at a dihedral angle of 64.94 (9)° with respect to its parent benzene ring. The molecular conformation is stabilised by a bifurcated N—H⋯(O,Cl) hydrogen bond. C—H⋯π, O—H⋯π and π–π inter­actions [centroid–centroid distance = 3.5706 (11) Å] stabilize the crystal structure.
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spelling pubmed-30517472011-04-26 2-{2-[(2,6-Dichloro­phen­yl)amino]­phen­yl}ethanol Nasirullah, Ul Islam, Nazar Tahir, M. Nawaz Khan, Ikhtiar Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(14)H(13)Cl(2)NO, the 2,6-dichloro­anilino unit is roughly planar (r.m.s. deviation = 0.0298 Å) and makes a dihedral angle of 67.71 (4)° with the benzene ring containing the ethanol group. The C–C–O fragment is oriented at a dihedral angle of 64.94 (9)° with respect to its parent benzene ring. The molecular conformation is stabilised by a bifurcated N—H⋯(O,Cl) hydrogen bond. C—H⋯π, O—H⋯π and π–π inter­actions [centroid–centroid distance = 3.5706 (11) Å] stabilize the crystal structure. International Union of Crystallography 2011-01-08 /pmc/articles/PMC3051747/ /pubmed/21522965 http://dx.doi.org/10.1107/S1600536810054590 Text en © Nasirullah et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Nasirullah,
Ul Islam, Nazar
Tahir, M. Nawaz
Khan, Ikhtiar
2-{2-[(2,6-Dichloro­phen­yl)amino]­phen­yl}ethanol
title 2-{2-[(2,6-Dichloro­phen­yl)amino]­phen­yl}ethanol
title_full 2-{2-[(2,6-Dichloro­phen­yl)amino]­phen­yl}ethanol
title_fullStr 2-{2-[(2,6-Dichloro­phen­yl)amino]­phen­yl}ethanol
title_full_unstemmed 2-{2-[(2,6-Dichloro­phen­yl)amino]­phen­yl}ethanol
title_short 2-{2-[(2,6-Dichloro­phen­yl)amino]­phen­yl}ethanol
title_sort 2-{2-[(2,6-dichloro­phen­yl)amino]­phen­yl}ethanol
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051747/
https://www.ncbi.nlm.nih.gov/pubmed/21522965
http://dx.doi.org/10.1107/S1600536810054590
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AT ulislamnazar 2226dichlorophenylaminophenylethanol
AT tahirmnawaz 2226dichlorophenylaminophenylethanol
AT khanikhtiar 2226dichlorophenylaminophenylethanol

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