Methyl 2-[2-(benzyl­oxycarbonyl­amino)­propan-2-yl]-5-hy­droxy-6-meth­oxy­pyrimidine-4-carboxyl­ate

In the title compound, C(18)H(21)N(3)O(6), a pyrimidine derivative, the dihedral angle between the benzene and pyrimidine rings is 52.26 (12)°. The carboxyl­ate unit is twisted with respect to the pyrimidine ring, making a dihedral angle of 12.33 (7)°. In the crystal, mol­ecules are linked by a pair...

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Autores principales: Fun, Hoong-Kun, Sumangala, V., Prasad, D. Jagadeesh, Poojary, Boja, Chantrapromma, Suchada
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051748/
https://www.ncbi.nlm.nih.gov/pubmed/21522966
http://dx.doi.org/10.1107/S160053681005467X
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author Fun, Hoong-Kun
Sumangala, V.
Prasad, D. Jagadeesh
Poojary, Boja
Chantrapromma, Suchada
author_facet Fun, Hoong-Kun
Sumangala, V.
Prasad, D. Jagadeesh
Poojary, Boja
Chantrapromma, Suchada
author_sort Fun, Hoong-Kun
collection PubMed
description In the title compound, C(18)H(21)N(3)O(6), a pyrimidine derivative, the dihedral angle between the benzene and pyrimidine rings is 52.26 (12)°. The carboxyl­ate unit is twisted with respect to the pyrimidine ring, making a dihedral angle of 12.33 (7)°. In the crystal, mol­ecules are linked by a pair of O—H⋯O hydrogen bonds, forming an inversion dimer. The dimers are stacked into columns along the b axis through weak C—H⋯O inter­actions.
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spelling pubmed-30517482011-04-26 Methyl 2-[2-(benzyl­oxycarbonyl­amino)­propan-2-yl]-5-hy­droxy-6-meth­oxy­pyrimidine-4-carboxyl­ate Fun, Hoong-Kun Sumangala, V. Prasad, D. Jagadeesh Poojary, Boja Chantrapromma, Suchada Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(18)H(21)N(3)O(6), a pyrimidine derivative, the dihedral angle between the benzene and pyrimidine rings is 52.26 (12)°. The carboxyl­ate unit is twisted with respect to the pyrimidine ring, making a dihedral angle of 12.33 (7)°. In the crystal, mol­ecules are linked by a pair of O—H⋯O hydrogen bonds, forming an inversion dimer. The dimers are stacked into columns along the b axis through weak C—H⋯O inter­actions. International Union of Crystallography 2011-01-08 /pmc/articles/PMC3051748/ /pubmed/21522966 http://dx.doi.org/10.1107/S160053681005467X Text en © Fun et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Fun, Hoong-Kun
Sumangala, V.
Prasad, D. Jagadeesh
Poojary, Boja
Chantrapromma, Suchada
Methyl 2-[2-(benzyl­oxycarbonyl­amino)­propan-2-yl]-5-hy­droxy-6-meth­oxy­pyrimidine-4-carboxyl­ate
title Methyl 2-[2-(benzyl­oxycarbonyl­amino)­propan-2-yl]-5-hy­droxy-6-meth­oxy­pyrimidine-4-carboxyl­ate
title_full Methyl 2-[2-(benzyl­oxycarbonyl­amino)­propan-2-yl]-5-hy­droxy-6-meth­oxy­pyrimidine-4-carboxyl­ate
title_fullStr Methyl 2-[2-(benzyl­oxycarbonyl­amino)­propan-2-yl]-5-hy­droxy-6-meth­oxy­pyrimidine-4-carboxyl­ate
title_full_unstemmed Methyl 2-[2-(benzyl­oxycarbonyl­amino)­propan-2-yl]-5-hy­droxy-6-meth­oxy­pyrimidine-4-carboxyl­ate
title_short Methyl 2-[2-(benzyl­oxycarbonyl­amino)­propan-2-yl]-5-hy­droxy-6-meth­oxy­pyrimidine-4-carboxyl­ate
title_sort methyl 2-[2-(benzyl­oxycarbonyl­amino)­propan-2-yl]-5-hy­droxy-6-meth­oxy­pyrimidine-4-carboxyl­ate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051748/
https://www.ncbi.nlm.nih.gov/pubmed/21522966
http://dx.doi.org/10.1107/S160053681005467X
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AT prasaddjagadeesh methyl22benzyloxycarbonylaminopropan2yl5hydroxy6methoxypyrimidine4carboxylate
AT poojaryboja methyl22benzyloxycarbonylaminopropan2yl5hydroxy6methoxypyrimidine4carboxylate
AT chantraprommasuchada methyl22benzyloxycarbonylaminopropan2yl5hydroxy6methoxypyrimidine4carboxylate

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