A new ortho­rhom­bic polymorph of 1,1′-seleno­bis­(N,N-diethyl­sulfanecarbothio­amide)

The title compound [systematic name: N,N-dieth­yl({[(diethyl­carbamothio­yl)sulfan­yl]selan­yl}sulfan­yl)carbothio­amide], C(10)H(20)N(2)S(4)Se, crystallizes in a new form in the space group Pca2(1): the previously reported polymorph crystallizes in the space group P2(1)2(1)2(1). The new phase conta...

Descripción completa

Detalles Bibliográficos
Autores principales: Pöllnitz, Alpar, Varga, Richard A., Silvestru, Anca
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051749/
https://www.ncbi.nlm.nih.gov/pubmed/21523082
http://dx.doi.org/10.1107/S1600536811000511
_version_ 1782199553067319296
author Pöllnitz, Alpar
Varga, Richard A.
Silvestru, Anca
author_facet Pöllnitz, Alpar
Varga, Richard A.
Silvestru, Anca
author_sort Pöllnitz, Alpar
collection PubMed
description The title compound [systematic name: N,N-dieth­yl({[(diethyl­carbamothio­yl)sulfan­yl]selan­yl}sulfan­yl)carbothio­amide], C(10)H(20)N(2)S(4)Se, crystallizes in a new form in the space group Pca2(1): the previously reported polymorph crystallizes in the space group P2(1)2(1)2(1). The new phase contains two independent mol­ecules in the asymmetric unit. The Se atoms are tetra­coordinated, with a distorted square-planar geometry. The ligands coordinate asymmetrically to the Se atoms, with one strong Se—S bond [range 2.2833 (13)–2.3041 (15) Å] and one weaker bond [range 2.7318 (14)–2.7873 (12) Å].
format Text
id pubmed-3051749
institution National Center for Biotechnology Information
language English
publishDate 2011
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-30517492011-04-26 A new ortho­rhom­bic polymorph of 1,1′-seleno­bis­(N,N-diethyl­sulfanecarbothio­amide) Pöllnitz, Alpar Varga, Richard A. Silvestru, Anca Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound [systematic name: N,N-dieth­yl({[(diethyl­carbamothio­yl)sulfan­yl]selan­yl}sulfan­yl)carbothio­amide], C(10)H(20)N(2)S(4)Se, crystallizes in a new form in the space group Pca2(1): the previously reported polymorph crystallizes in the space group P2(1)2(1)2(1). The new phase contains two independent mol­ecules in the asymmetric unit. The Se atoms are tetra­coordinated, with a distorted square-planar geometry. The ligands coordinate asymmetrically to the Se atoms, with one strong Se—S bond [range 2.2833 (13)–2.3041 (15) Å] and one weaker bond [range 2.7318 (14)–2.7873 (12) Å]. International Union of Crystallography 2011-01-15 /pmc/articles/PMC3051749/ /pubmed/21523082 http://dx.doi.org/10.1107/S1600536811000511 Text en © Pöllnitz et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Pöllnitz, Alpar
Varga, Richard A.
Silvestru, Anca
A new ortho­rhom­bic polymorph of 1,1′-seleno­bis­(N,N-diethyl­sulfanecarbothio­amide)
title A new ortho­rhom­bic polymorph of 1,1′-seleno­bis­(N,N-diethyl­sulfanecarbothio­amide)
title_full A new ortho­rhom­bic polymorph of 1,1′-seleno­bis­(N,N-diethyl­sulfanecarbothio­amide)
title_fullStr A new ortho­rhom­bic polymorph of 1,1′-seleno­bis­(N,N-diethyl­sulfanecarbothio­amide)
title_full_unstemmed A new ortho­rhom­bic polymorph of 1,1′-seleno­bis­(N,N-diethyl­sulfanecarbothio­amide)
title_short A new ortho­rhom­bic polymorph of 1,1′-seleno­bis­(N,N-diethyl­sulfanecarbothio­amide)
title_sort new ortho­rhom­bic polymorph of 1,1′-seleno­bis­(n,n-diethyl­sulfanecarbothio­amide)
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051749/
https://www.ncbi.nlm.nih.gov/pubmed/21523082
http://dx.doi.org/10.1107/S1600536811000511
work_keys_str_mv AT pollnitzalpar aneworthorhombicpolymorphof11selenobisnndiethylsulfanecarbothioamide
AT vargaricharda aneworthorhombicpolymorphof11selenobisnndiethylsulfanecarbothioamide
AT silvestruanca aneworthorhombicpolymorphof11selenobisnndiethylsulfanecarbothioamide
AT pollnitzalpar neworthorhombicpolymorphof11selenobisnndiethylsulfanecarbothioamide
AT vargaricharda neworthorhombicpolymorphof11selenobisnndiethylsulfanecarbothioamide
AT silvestruanca neworthorhombicpolymorphof11selenobisnndiethylsulfanecarbothioamide

Ejemplares similares