2-Meth­oxy­carbonyl­pyridinium tetra­chlorido(pyridine-2-carboxyl­ato-κ(2) N,O)stannate(IV)

In the reaction of pyridine-2-carb­oxy­lic acid and stannic chloride in methanol, one equivalent of the carb­oxy­lic acid is protonated at the amino site and is also esterified, yielding the title salt, (C(7)H(8)NO(2))[SnCl(4)(C(6)H(4)NO(2))]. The Sn(IV) atom in the anion is N,O-chelated by a pyridi...

Descripción completa

Detalles Bibliográficos
Autores principales: Najafi, Ezzatollah, Amini, Mostafa M., Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051751/
https://www.ncbi.nlm.nih.gov/pubmed/21522894
http://dx.doi.org/10.1107/S1600536811001930
_version_ 1782199553538129920
author Najafi, Ezzatollah
Amini, Mostafa M.
Ng, Seik Weng
author_facet Najafi, Ezzatollah
Amini, Mostafa M.
Ng, Seik Weng
author_sort Najafi, Ezzatollah
collection PubMed
description In the reaction of pyridine-2-carb­oxy­lic acid and stannic chloride in methanol, one equivalent of the carb­oxy­lic acid is protonated at the amino site and is also esterified, yielding the title salt, (C(7)H(8)NO(2))[SnCl(4)(C(6)H(4)NO(2))]. The Sn(IV) atom in the anion is N,O-chelated by a pyridine-2-carboxyl­ate in a cis-SnNOCl(4) octa­hedral geometry. The cation is linked to the anion by an N—H⋯O hydrogen bond.
format Text
id pubmed-3051751
institution National Center for Biotechnology Information
language English
publishDate 2011
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-30517512011-04-26 2-Meth­oxy­carbonyl­pyridinium tetra­chlorido(pyridine-2-carboxyl­ato-κ(2) N,O)stannate(IV) Najafi, Ezzatollah Amini, Mostafa M. Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the reaction of pyridine-2-carb­oxy­lic acid and stannic chloride in methanol, one equivalent of the carb­oxy­lic acid is protonated at the amino site and is also esterified, yielding the title salt, (C(7)H(8)NO(2))[SnCl(4)(C(6)H(4)NO(2))]. The Sn(IV) atom in the anion is N,O-chelated by a pyridine-2-carboxyl­ate in a cis-SnNOCl(4) octa­hedral geometry. The cation is linked to the anion by an N—H⋯O hydrogen bond. International Union of Crystallography 2011-01-22 /pmc/articles/PMC3051751/ /pubmed/21522894 http://dx.doi.org/10.1107/S1600536811001930 Text en © Najafi et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Najafi, Ezzatollah
Amini, Mostafa M.
Ng, Seik Weng
2-Meth­oxy­carbonyl­pyridinium tetra­chlorido(pyridine-2-carboxyl­ato-κ(2) N,O)stannate(IV)
title 2-Meth­oxy­carbonyl­pyridinium tetra­chlorido(pyridine-2-carboxyl­ato-κ(2) N,O)stannate(IV)
title_full 2-Meth­oxy­carbonyl­pyridinium tetra­chlorido(pyridine-2-carboxyl­ato-κ(2) N,O)stannate(IV)
title_fullStr 2-Meth­oxy­carbonyl­pyridinium tetra­chlorido(pyridine-2-carboxyl­ato-κ(2) N,O)stannate(IV)
title_full_unstemmed 2-Meth­oxy­carbonyl­pyridinium tetra­chlorido(pyridine-2-carboxyl­ato-κ(2) N,O)stannate(IV)
title_short 2-Meth­oxy­carbonyl­pyridinium tetra­chlorido(pyridine-2-carboxyl­ato-κ(2) N,O)stannate(IV)
title_sort 2-meth­oxy­carbonyl­pyridinium tetra­chlorido(pyridine-2-carboxyl­ato-κ(2) n,o)stannate(iv)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051751/
https://www.ncbi.nlm.nih.gov/pubmed/21522894
http://dx.doi.org/10.1107/S1600536811001930
work_keys_str_mv AT najafiezzatollah 2methoxycarbonylpyridiniumtetrachloridopyridine2carboxylatok2nostannateiv
AT aminimostafam 2methoxycarbonylpyridiniumtetrachloridopyridine2carboxylatok2nostannateiv
AT ngseikweng 2methoxycarbonylpyridiniumtetrachloridopyridine2carboxylatok2nostannateiv

Ejemplares similares