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Bis[bis­(2-ethyl-5-methyl-1H-imidazol-4-yl-κN (3))methane](nitrato-κ(2) O,O′)nickel(II) nitrate

In the title compound, [Ni(NO(3))(C(13)H(20)N(4))(2)]NO(3), the Ni(II) ion shows a distorted octa­hedral geometry formed by four N atoms from two bis­(2-ethyl-5-methyl-1H-imidazol-4-yl)methane ligands and two O atoms from a chelating nitrate anion. Three ethyl groups in the complex cation and the O...

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Detalles Bibliográficos
Autores principales: Gao, Ge, Mao, Shu-Lin, Qian, Xiao-Min, Luo, Yang-Hui, Li, Jin-Feng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051755/
https://www.ncbi.nlm.nih.gov/pubmed/21522875
http://dx.doi.org/10.1107/S1600536811001000
Descripción
Sumario:In the title compound, [Ni(NO(3))(C(13)H(20)N(4))(2)]NO(3), the Ni(II) ion shows a distorted octa­hedral geometry formed by four N atoms from two bis­(2-ethyl-5-methyl-1H-imidazol-4-yl)methane ligands and two O atoms from a chelating nitrate anion. Three ethyl groups in the complex cation and the O atoms of the uncoordinated nitrate anion are disordered over two sets of positions [occupancy ratios of 0.52 (3):0.48 (3) and 0.63 (3):0.37 (3), respectively]. In the crystal, inter­molecular N—H⋯O hydrogen bonds connect the complex cations into a zigzag chain along [010] and further N—H⋯O hydrogen bonds between the chains and the uncoordinated nitrate anions lead to layers parallel to (100).