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Bis[bis(2-ethyl-5-methyl-1H-imidazol-4-yl-κN (3))methane](nitrato-κ(2) O,O′)nickel(II) nitrate
In the title compound, [Ni(NO(3))(C(13)H(20)N(4))(2)]NO(3), the Ni(II) ion shows a distorted octahedral geometry formed by four N atoms from two bis(2-ethyl-5-methyl-1H-imidazol-4-yl)methane ligands and two O atoms from a chelating nitrate anion. Three ethyl groups in the complex cation and the O...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051755/ https://www.ncbi.nlm.nih.gov/pubmed/21522875 http://dx.doi.org/10.1107/S1600536811001000 |
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author | Gao, Ge Mao, Shu-Lin Qian, Xiao-Min Luo, Yang-Hui Li, Jin-Feng |
author_facet | Gao, Ge Mao, Shu-Lin Qian, Xiao-Min Luo, Yang-Hui Li, Jin-Feng |
author_sort | Gao, Ge |
collection | PubMed |
description | In the title compound, [Ni(NO(3))(C(13)H(20)N(4))(2)]NO(3), the Ni(II) ion shows a distorted octahedral geometry formed by four N atoms from two bis(2-ethyl-5-methyl-1H-imidazol-4-yl)methane ligands and two O atoms from a chelating nitrate anion. Three ethyl groups in the complex cation and the O atoms of the uncoordinated nitrate anion are disordered over two sets of positions [occupancy ratios of 0.52 (3):0.48 (3) and 0.63 (3):0.37 (3), respectively]. In the crystal, intermolecular N—H⋯O hydrogen bonds connect the complex cations into a zigzag chain along [010] and further N—H⋯O hydrogen bonds between the chains and the uncoordinated nitrate anions lead to layers parallel to (100). |
format | Text |
id | pubmed-3051755 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30517552011-04-26 Bis[bis(2-ethyl-5-methyl-1H-imidazol-4-yl-κN (3))methane](nitrato-κ(2) O,O′)nickel(II) nitrate Gao, Ge Mao, Shu-Lin Qian, Xiao-Min Luo, Yang-Hui Li, Jin-Feng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Ni(NO(3))(C(13)H(20)N(4))(2)]NO(3), the Ni(II) ion shows a distorted octahedral geometry formed by four N atoms from two bis(2-ethyl-5-methyl-1H-imidazol-4-yl)methane ligands and two O atoms from a chelating nitrate anion. Three ethyl groups in the complex cation and the O atoms of the uncoordinated nitrate anion are disordered over two sets of positions [occupancy ratios of 0.52 (3):0.48 (3) and 0.63 (3):0.37 (3), respectively]. In the crystal, intermolecular N—H⋯O hydrogen bonds connect the complex cations into a zigzag chain along [010] and further N—H⋯O hydrogen bonds between the chains and the uncoordinated nitrate anions lead to layers parallel to (100). International Union of Crystallography 2011-01-15 /pmc/articles/PMC3051755/ /pubmed/21522875 http://dx.doi.org/10.1107/S1600536811001000 Text en © Gao et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Gao, Ge Mao, Shu-Lin Qian, Xiao-Min Luo, Yang-Hui Li, Jin-Feng Bis[bis(2-ethyl-5-methyl-1H-imidazol-4-yl-κN (3))methane](nitrato-κ(2) O,O′)nickel(II) nitrate |
title | Bis[bis(2-ethyl-5-methyl-1H-imidazol-4-yl-κN
(3))methane](nitrato-κ(2)
O,O′)nickel(II) nitrate |
title_full | Bis[bis(2-ethyl-5-methyl-1H-imidazol-4-yl-κN
(3))methane](nitrato-κ(2)
O,O′)nickel(II) nitrate |
title_fullStr | Bis[bis(2-ethyl-5-methyl-1H-imidazol-4-yl-κN
(3))methane](nitrato-κ(2)
O,O′)nickel(II) nitrate |
title_full_unstemmed | Bis[bis(2-ethyl-5-methyl-1H-imidazol-4-yl-κN
(3))methane](nitrato-κ(2)
O,O′)nickel(II) nitrate |
title_short | Bis[bis(2-ethyl-5-methyl-1H-imidazol-4-yl-κN
(3))methane](nitrato-κ(2)
O,O′)nickel(II) nitrate |
title_sort | bis[bis(2-ethyl-5-methyl-1h-imidazol-4-yl-κn
(3))methane](nitrato-κ(2)
o,o′)nickel(ii) nitrate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051755/ https://www.ncbi.nlm.nih.gov/pubmed/21522875 http://dx.doi.org/10.1107/S1600536811001000 |
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