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Bis[bis­(2-ethyl-5-methyl-1H-imidazol-4-yl-κN (3))methane](nitrato-κ(2) O,O′)nickel(II) nitrate

In the title compound, [Ni(NO(3))(C(13)H(20)N(4))(2)]NO(3), the Ni(II) ion shows a distorted octa­hedral geometry formed by four N atoms from two bis­(2-ethyl-5-methyl-1H-imidazol-4-yl)methane ligands and two O atoms from a chelating nitrate anion. Three ethyl groups in the complex cation and the O...

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Autores principales: Gao, Ge, Mao, Shu-Lin, Qian, Xiao-Min, Luo, Yang-Hui, Li, Jin-Feng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051755/
https://www.ncbi.nlm.nih.gov/pubmed/21522875
http://dx.doi.org/10.1107/S1600536811001000
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author Gao, Ge
Mao, Shu-Lin
Qian, Xiao-Min
Luo, Yang-Hui
Li, Jin-Feng
author_facet Gao, Ge
Mao, Shu-Lin
Qian, Xiao-Min
Luo, Yang-Hui
Li, Jin-Feng
author_sort Gao, Ge
collection PubMed
description In the title compound, [Ni(NO(3))(C(13)H(20)N(4))(2)]NO(3), the Ni(II) ion shows a distorted octa­hedral geometry formed by four N atoms from two bis­(2-ethyl-5-methyl-1H-imidazol-4-yl)methane ligands and two O atoms from a chelating nitrate anion. Three ethyl groups in the complex cation and the O atoms of the uncoordinated nitrate anion are disordered over two sets of positions [occupancy ratios of 0.52 (3):0.48 (3) and 0.63 (3):0.37 (3), respectively]. In the crystal, inter­molecular N—H⋯O hydrogen bonds connect the complex cations into a zigzag chain along [010] and further N—H⋯O hydrogen bonds between the chains and the uncoordinated nitrate anions lead to layers parallel to (100).
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spelling pubmed-30517552011-04-26 Bis[bis­(2-ethyl-5-methyl-1H-imidazol-4-yl-κN (3))methane](nitrato-κ(2) O,O′)nickel(II) nitrate Gao, Ge Mao, Shu-Lin Qian, Xiao-Min Luo, Yang-Hui Li, Jin-Feng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Ni(NO(3))(C(13)H(20)N(4))(2)]NO(3), the Ni(II) ion shows a distorted octa­hedral geometry formed by four N atoms from two bis­(2-ethyl-5-methyl-1H-imidazol-4-yl)methane ligands and two O atoms from a chelating nitrate anion. Three ethyl groups in the complex cation and the O atoms of the uncoordinated nitrate anion are disordered over two sets of positions [occupancy ratios of 0.52 (3):0.48 (3) and 0.63 (3):0.37 (3), respectively]. In the crystal, inter­molecular N—H⋯O hydrogen bonds connect the complex cations into a zigzag chain along [010] and further N—H⋯O hydrogen bonds between the chains and the uncoordinated nitrate anions lead to layers parallel to (100). International Union of Crystallography 2011-01-15 /pmc/articles/PMC3051755/ /pubmed/21522875 http://dx.doi.org/10.1107/S1600536811001000 Text en © Gao et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Gao, Ge
Mao, Shu-Lin
Qian, Xiao-Min
Luo, Yang-Hui
Li, Jin-Feng
Bis[bis­(2-ethyl-5-methyl-1H-imidazol-4-yl-κN (3))methane](nitrato-κ(2) O,O′)nickel(II) nitrate
title Bis[bis­(2-ethyl-5-methyl-1H-imidazol-4-yl-κN (3))methane](nitrato-κ(2) O,O′)nickel(II) nitrate
title_full Bis[bis­(2-ethyl-5-methyl-1H-imidazol-4-yl-κN (3))methane](nitrato-κ(2) O,O′)nickel(II) nitrate
title_fullStr Bis[bis­(2-ethyl-5-methyl-1H-imidazol-4-yl-κN (3))methane](nitrato-κ(2) O,O′)nickel(II) nitrate
title_full_unstemmed Bis[bis­(2-ethyl-5-methyl-1H-imidazol-4-yl-κN (3))methane](nitrato-κ(2) O,O′)nickel(II) nitrate
title_short Bis[bis­(2-ethyl-5-methyl-1H-imidazol-4-yl-κN (3))methane](nitrato-κ(2) O,O′)nickel(II) nitrate
title_sort bis[bis­(2-ethyl-5-methyl-1h-imidazol-4-yl-κn (3))methane](nitrato-κ(2) o,o′)nickel(ii) nitrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051755/
https://www.ncbi.nlm.nih.gov/pubmed/21522875
http://dx.doi.org/10.1107/S1600536811001000
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