Bis(trimethyl­ammonium) tetra­chlorido­diphenyl­stannate(IV)

The title compound, [(CH(3))(3)NH](2)[Sn(C(6)H(5))(2)Cl(4)], consists of [(CH(3))(3)NH](+) cations and [SnPh(2)Cl(4)](2−) anions in which the Sn atom, located on a centre of inversion, is bonded to four Cl atoms and two phenyl rings, giving an octa­hedral geometry with the phenyl rings in trans posi...

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Detalles Bibliográficos
Autores principales: Diop, Tidiane, Diop, Libasse, Molloy, K. C. Kieran, Kocioc-Köhn, Gabrielle
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051760/
https://www.ncbi.nlm.nih.gov/pubmed/21522868
http://dx.doi.org/10.1107/S1600536811000870
Descripción
Sumario:The title compound, [(CH(3))(3)NH](2)[Sn(C(6)H(5))(2)Cl(4)], consists of [(CH(3))(3)NH](+) cations and [SnPh(2)Cl(4)](2−) anions in which the Sn atom, located on a centre of inversion, is bonded to four Cl atoms and two phenyl rings, giving an octa­hedral geometry with the phenyl rings in trans positions. In the crystal, the cations and the anions are connected by N—H⋯Cl hydrogen bonds and C—H⋯Cl inter­actions.

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