Bis(μ-chloroacetato-κ(2) O:O′)bis(chloro­acetato-κO)di-μ(3)-oxido-tetrakis[dibenzyl­tin(IV)]

The title tetra­nuclear complex mol­ecule, [Sn(4)(C(7)H(7))(8)(C(2)H(2)ClO(2))(4)O(2)], has crystallographically imposed inversion symmetry. Each Sn atom has a distorted trigonal–bipyramidal geometry, with the equatorial plane formed by an oxido O atom and two C atoms of two benzyl anions. The confi...

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Detalles Bibliográficos
Autores principales: Li, Jing, Yin, Handong, Wang, Daqi
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051761/
https://www.ncbi.nlm.nih.gov/pubmed/21522831
http://dx.doi.org/10.1107/S1600536810054000
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author Li, Jing
Yin, Handong
Wang, Daqi
author_facet Li, Jing
Yin, Handong
Wang, Daqi
author_sort Li, Jing
collection PubMed
description The title tetra­nuclear complex mol­ecule, [Sn(4)(C(7)H(7))(8)(C(2)H(2)ClO(2))(4)O(2)], has crystallographically imposed inversion symmetry. Each Sn atom has a distorted trigonal–bipyramidal geometry, with the equatorial plane formed by an oxido O atom and two C atoms of two benzyl anions. The configuration of the complex is stabilized by a pair of C—H⋯O hydrogen bonds. In the crystal, complex mol­ecules are linked into zigzag chains along [110] by C—H⋯O hydrogen bonds.
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spelling pubmed-30517612011-04-26 Bis(μ-chloroacetato-κ(2) O:O′)bis(chloro­acetato-κO)di-μ(3)-oxido-tetrakis[dibenzyl­tin(IV)] Li, Jing Yin, Handong Wang, Daqi Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title tetra­nuclear complex mol­ecule, [Sn(4)(C(7)H(7))(8)(C(2)H(2)ClO(2))(4)O(2)], has crystallographically imposed inversion symmetry. Each Sn atom has a distorted trigonal–bipyramidal geometry, with the equatorial plane formed by an oxido O atom and two C atoms of two benzyl anions. The configuration of the complex is stabilized by a pair of C—H⋯O hydrogen bonds. In the crystal, complex mol­ecules are linked into zigzag chains along [110] by C—H⋯O hydrogen bonds. International Union of Crystallography 2011-01-08 /pmc/articles/PMC3051761/ /pubmed/21522831 http://dx.doi.org/10.1107/S1600536810054000 Text en © Li et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Li, Jing
Yin, Handong
Wang, Daqi
Bis(μ-chloroacetato-κ(2) O:O′)bis(chloro­acetato-κO)di-μ(3)-oxido-tetrakis[dibenzyl­tin(IV)]
title Bis(μ-chloroacetato-κ(2) O:O′)bis(chloro­acetato-κO)di-μ(3)-oxido-tetrakis[dibenzyl­tin(IV)]
title_full Bis(μ-chloroacetato-κ(2) O:O′)bis(chloro­acetato-κO)di-μ(3)-oxido-tetrakis[dibenzyl­tin(IV)]
title_fullStr Bis(μ-chloroacetato-κ(2) O:O′)bis(chloro­acetato-κO)di-μ(3)-oxido-tetrakis[dibenzyl­tin(IV)]
title_full_unstemmed Bis(μ-chloroacetato-κ(2) O:O′)bis(chloro­acetato-κO)di-μ(3)-oxido-tetrakis[dibenzyl­tin(IV)]
title_short Bis(μ-chloroacetato-κ(2) O:O′)bis(chloro­acetato-κO)di-μ(3)-oxido-tetrakis[dibenzyl­tin(IV)]
title_sort bis(μ-chloroacetato-κ(2) o:o′)bis(chloro­acetato-κo)di-μ(3)-oxido-tetrakis[dibenzyl­tin(iv)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051761/
https://www.ncbi.nlm.nih.gov/pubmed/21522831
http://dx.doi.org/10.1107/S1600536810054000
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AT yinhandong bismchloroacetatok2oobischloroacetatokodim3oxidotetrakisdibenzyltiniv
AT wangdaqi bismchloroacetatok2oobischloroacetatokodim3oxidotetrakisdibenzyltiniv

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