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N-{4-[(2-Methoxyphenyl)sulfamoyl]phenyl}acetamide
In the title compound, C(15)H(16)N(2)O(4)S, the S atom has a distorted tetrahedral geometry [maximum deviation: O—S—O = 118.25 (7)°]. The two aromatic rings make a dihedral angle of 62.67 (10)° with each other. An intramolecular N—H⋯O hydrogen bond forms an S(6) ring motif. In the crystal, molecu...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051762/ https://www.ncbi.nlm.nih.gov/pubmed/21522993 http://dx.doi.org/10.1107/S1600536811000432 |
Sumario: | In the title compound, C(15)H(16)N(2)O(4)S, the S atom has a distorted tetrahedral geometry [maximum deviation: O—S—O = 118.25 (7)°]. The two aromatic rings make a dihedral angle of 62.67 (10)° with each other. An intramolecular N—H⋯O hydrogen bond forms an S(6) ring motif. In the crystal, molecules form centrosymmetric dimers via pairwise N—H⋯O interactions, forming an R (2) (2)(8) ring motif, and these dimers are connected by N—H⋯O hydrogen bonds, generating a three-dimensional network. Furthermore, a weak C—H⋯π interaction helps to reinforce the crystal structure. The O atom in the acetamide group is disordered over two positions with major and minor occupancies of 0.52 (5) and 0.48 (5), respectively. |
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