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N-{4-[(2-Methoxyphenyl)sulfamoyl]phenyl}acetamide
In the title compound, C(15)H(16)N(2)O(4)S, the S atom has a distorted tetrahedral geometry [maximum deviation: O—S—O = 118.25 (7)°]. The two aromatic rings make a dihedral angle of 62.67 (10)° with each other. An intramolecular N—H⋯O hydrogen bond forms an S(6) ring motif. In the crystal, molecu...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051762/ https://www.ncbi.nlm.nih.gov/pubmed/21522993 http://dx.doi.org/10.1107/S1600536811000432 |
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author | Ahmad, Saba Farrukh, Muhammad Akhyar Qureshi, Fahim Ashraf Adnan, Ahmad Akkurt, Mehmet |
author_facet | Ahmad, Saba Farrukh, Muhammad Akhyar Qureshi, Fahim Ashraf Adnan, Ahmad Akkurt, Mehmet |
author_sort | Ahmad, Saba |
collection | PubMed |
description | In the title compound, C(15)H(16)N(2)O(4)S, the S atom has a distorted tetrahedral geometry [maximum deviation: O—S—O = 118.25 (7)°]. The two aromatic rings make a dihedral angle of 62.67 (10)° with each other. An intramolecular N—H⋯O hydrogen bond forms an S(6) ring motif. In the crystal, molecules form centrosymmetric dimers via pairwise N—H⋯O interactions, forming an R (2) (2)(8) ring motif, and these dimers are connected by N—H⋯O hydrogen bonds, generating a three-dimensional network. Furthermore, a weak C—H⋯π interaction helps to reinforce the crystal structure. The O atom in the acetamide group is disordered over two positions with major and minor occupancies of 0.52 (5) and 0.48 (5), respectively. |
format | Text |
id | pubmed-3051762 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30517622011-04-26 N-{4-[(2-Methoxyphenyl)sulfamoyl]phenyl}acetamide Ahmad, Saba Farrukh, Muhammad Akhyar Qureshi, Fahim Ashraf Adnan, Ahmad Akkurt, Mehmet Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(15)H(16)N(2)O(4)S, the S atom has a distorted tetrahedral geometry [maximum deviation: O—S—O = 118.25 (7)°]. The two aromatic rings make a dihedral angle of 62.67 (10)° with each other. An intramolecular N—H⋯O hydrogen bond forms an S(6) ring motif. In the crystal, molecules form centrosymmetric dimers via pairwise N—H⋯O interactions, forming an R (2) (2)(8) ring motif, and these dimers are connected by N—H⋯O hydrogen bonds, generating a three-dimensional network. Furthermore, a weak C—H⋯π interaction helps to reinforce the crystal structure. The O atom in the acetamide group is disordered over two positions with major and minor occupancies of 0.52 (5) and 0.48 (5), respectively. International Union of Crystallography 2011-01-08 /pmc/articles/PMC3051762/ /pubmed/21522993 http://dx.doi.org/10.1107/S1600536811000432 Text en © Ahmad et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Ahmad, Saba Farrukh, Muhammad Akhyar Qureshi, Fahim Ashraf Adnan, Ahmad Akkurt, Mehmet N-{4-[(2-Methoxyphenyl)sulfamoyl]phenyl}acetamide |
title |
N-{4-[(2-Methoxyphenyl)sulfamoyl]phenyl}acetamide |
title_full |
N-{4-[(2-Methoxyphenyl)sulfamoyl]phenyl}acetamide |
title_fullStr |
N-{4-[(2-Methoxyphenyl)sulfamoyl]phenyl}acetamide |
title_full_unstemmed |
N-{4-[(2-Methoxyphenyl)sulfamoyl]phenyl}acetamide |
title_short |
N-{4-[(2-Methoxyphenyl)sulfamoyl]phenyl}acetamide |
title_sort | n-{4-[(2-methoxyphenyl)sulfamoyl]phenyl}acetamide |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051762/ https://www.ncbi.nlm.nih.gov/pubmed/21522993 http://dx.doi.org/10.1107/S1600536811000432 |
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