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N-{4-[(2-Meth­oxy­phen­yl)sulfamo­yl]phen­yl}acetamide

In the title compound, C(15)H(16)N(2)O(4)S, the S atom has a distorted tetra­hedral geometry [maximum deviation: O—S—O = 118.25 (7)°]. The two aromatic rings make a dihedral angle of 62.67 (10)° with each other. An intra­molecular N—H⋯O hydrogen bond forms an S(6) ring motif. In the crystal, mol­ecu...

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Autores principales: Ahmad, Saba, Farrukh, Muhammad Akhyar, Qureshi, Fahim Ashraf, Adnan, Ahmad, Akkurt, Mehmet
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051762/
https://www.ncbi.nlm.nih.gov/pubmed/21522993
http://dx.doi.org/10.1107/S1600536811000432
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author Ahmad, Saba
Farrukh, Muhammad Akhyar
Qureshi, Fahim Ashraf
Adnan, Ahmad
Akkurt, Mehmet
author_facet Ahmad, Saba
Farrukh, Muhammad Akhyar
Qureshi, Fahim Ashraf
Adnan, Ahmad
Akkurt, Mehmet
author_sort Ahmad, Saba
collection PubMed
description In the title compound, C(15)H(16)N(2)O(4)S, the S atom has a distorted tetra­hedral geometry [maximum deviation: O—S—O = 118.25 (7)°]. The two aromatic rings make a dihedral angle of 62.67 (10)° with each other. An intra­molecular N—H⋯O hydrogen bond forms an S(6) ring motif. In the crystal, mol­ecules form centrosymmetric dimers via pairwise N—H⋯O inter­actions, forming an R (2) (2)(8) ring motif, and these dimers are connected by N—H⋯O hydrogen bonds, generating a three-dimensional network. Furthermore, a weak C—H⋯π inter­action helps to reinforce the crystal structure. The O atom in the acetamide group is disordered over two positions with major and minor occupancies of 0.52 (5) and 0.48 (5), respectively.
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spelling pubmed-30517622011-04-26 N-{4-[(2-Meth­oxy­phen­yl)sulfamo­yl]phen­yl}acetamide Ahmad, Saba Farrukh, Muhammad Akhyar Qureshi, Fahim Ashraf Adnan, Ahmad Akkurt, Mehmet Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(15)H(16)N(2)O(4)S, the S atom has a distorted tetra­hedral geometry [maximum deviation: O—S—O = 118.25 (7)°]. The two aromatic rings make a dihedral angle of 62.67 (10)° with each other. An intra­molecular N—H⋯O hydrogen bond forms an S(6) ring motif. In the crystal, mol­ecules form centrosymmetric dimers via pairwise N—H⋯O inter­actions, forming an R (2) (2)(8) ring motif, and these dimers are connected by N—H⋯O hydrogen bonds, generating a three-dimensional network. Furthermore, a weak C—H⋯π inter­action helps to reinforce the crystal structure. The O atom in the acetamide group is disordered over two positions with major and minor occupancies of 0.52 (5) and 0.48 (5), respectively. International Union of Crystallography 2011-01-08 /pmc/articles/PMC3051762/ /pubmed/21522993 http://dx.doi.org/10.1107/S1600536811000432 Text en © Ahmad et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Ahmad, Saba
Farrukh, Muhammad Akhyar
Qureshi, Fahim Ashraf
Adnan, Ahmad
Akkurt, Mehmet
N-{4-[(2-Meth­oxy­phen­yl)sulfamo­yl]phen­yl}acetamide
title N-{4-[(2-Meth­oxy­phen­yl)sulfamo­yl]phen­yl}acetamide
title_full N-{4-[(2-Meth­oxy­phen­yl)sulfamo­yl]phen­yl}acetamide
title_fullStr N-{4-[(2-Meth­oxy­phen­yl)sulfamo­yl]phen­yl}acetamide
title_full_unstemmed N-{4-[(2-Meth­oxy­phen­yl)sulfamo­yl]phen­yl}acetamide
title_short N-{4-[(2-Meth­oxy­phen­yl)sulfamo­yl]phen­yl}acetamide
title_sort n-{4-[(2-meth­oxy­phen­yl)sulfamo­yl]phen­yl}acetamide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051762/
https://www.ncbi.nlm.nih.gov/pubmed/21522993
http://dx.doi.org/10.1107/S1600536811000432
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