1-(4-Meth­oxy­phen­yl)-4-(3-nitro­phen­yl)-3-phen­oxy­azetidin-2-one

In the title compound, C(22)H(18)N(2)O(5), the four-membered β-lactam ring is nearly planar, with a maximum deviation of 0.023 (2) Å for the N atom, and has long C—C distances of 1.525 (5) and 1.571 (5) Å. The mean plane of this group makes dihedral angles of 11.61 (19), 74.5 (2) and 72.3 (2)° with...

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Autores principales: Baktır, Zeliha, Akkurt, Mehmet, Jarrahpour, Aliasghar, Heiran, Roghaye
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051763/
https://www.ncbi.nlm.nih.gov/pubmed/21523185
http://dx.doi.org/10.1107/S1600536811003382
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author Baktır, Zeliha
Akkurt, Mehmet
Jarrahpour, Aliasghar
Heiran, Roghaye
author_facet Baktır, Zeliha
Akkurt, Mehmet
Jarrahpour, Aliasghar
Heiran, Roghaye
author_sort Baktır, Zeliha
collection PubMed
description In the title compound, C(22)H(18)N(2)O(5), the four-membered β-lactam ring is nearly planar, with a maximum deviation of 0.023 (2) Å for the N atom, and has long C—C distances of 1.525 (5) and 1.571 (5) Å. The mean plane of this group makes dihedral angles of 11.61 (19), 74.5 (2) and 72.3 (2)° with three aromatic rings. An intra­molecular C—H⋯O hydrogen bond occurs. The packing of the mol­ecules in the crystal structure is governed mainly by inter­molecular C—H⋯O hydrogen-bonding and C—H⋯π stacking inter­actions. Furthermore, a π–π inter­action [centroid–centroid distance = 3.6129 (19) Å] helps to stabilize the crystal structure.
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spelling pubmed-30517632011-04-26 1-(4-Meth­oxy­phen­yl)-4-(3-nitro­phen­yl)-3-phen­oxy­azetidin-2-one Baktır, Zeliha Akkurt, Mehmet Jarrahpour, Aliasghar Heiran, Roghaye Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(22)H(18)N(2)O(5), the four-membered β-lactam ring is nearly planar, with a maximum deviation of 0.023 (2) Å for the N atom, and has long C—C distances of 1.525 (5) and 1.571 (5) Å. The mean plane of this group makes dihedral angles of 11.61 (19), 74.5 (2) and 72.3 (2)° with three aromatic rings. An intra­molecular C—H⋯O hydrogen bond occurs. The packing of the mol­ecules in the crystal structure is governed mainly by inter­molecular C—H⋯O hydrogen-bonding and C—H⋯π stacking inter­actions. Furthermore, a π–π inter­action [centroid–centroid distance = 3.6129 (19) Å] helps to stabilize the crystal structure. International Union of Crystallography 2011-01-29 /pmc/articles/PMC3051763/ /pubmed/21523185 http://dx.doi.org/10.1107/S1600536811003382 Text en © Baktır et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Baktır, Zeliha
Akkurt, Mehmet
Jarrahpour, Aliasghar
Heiran, Roghaye
1-(4-Meth­oxy­phen­yl)-4-(3-nitro­phen­yl)-3-phen­oxy­azetidin-2-one
title 1-(4-Meth­oxy­phen­yl)-4-(3-nitro­phen­yl)-3-phen­oxy­azetidin-2-one
title_full 1-(4-Meth­oxy­phen­yl)-4-(3-nitro­phen­yl)-3-phen­oxy­azetidin-2-one
title_fullStr 1-(4-Meth­oxy­phen­yl)-4-(3-nitro­phen­yl)-3-phen­oxy­azetidin-2-one
title_full_unstemmed 1-(4-Meth­oxy­phen­yl)-4-(3-nitro­phen­yl)-3-phen­oxy­azetidin-2-one
title_short 1-(4-Meth­oxy­phen­yl)-4-(3-nitro­phen­yl)-3-phen­oxy­azetidin-2-one
title_sort 1-(4-meth­oxy­phen­yl)-4-(3-nitro­phen­yl)-3-phen­oxy­azetidin-2-one
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051763/
https://www.ncbi.nlm.nih.gov/pubmed/21523185
http://dx.doi.org/10.1107/S1600536811003382
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AT jarrahpouraliasghar 14methoxyphenyl43nitrophenyl3phenoxyazetidin2one
AT heiranroghaye 14methoxyphenyl43nitrophenyl3phenoxyazetidin2one

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