Bis(2,1,3-benzoselenadiazole-κN)dibromidocopper(II)

In the title complex, [CuBr(2)(C(6)H(4)N(2)Se)(2)], the Cu(II) ion is tetra­coordinated by two bromide anions and two N atoms in a distorted square-planar geometry. The two essentially planar 2,1,3-benzoselenadiazole ligands [maximum deviations = 0.012 (2) and 0.030 (2) Å] are approximately coplanar...

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Autores principales: Fun, Hoong-Kun, Goh, Jia Hao, Maity, Annada C., Goswami, Shyamaprosad
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051764/
https://www.ncbi.nlm.nih.gov/pubmed/21522854
http://dx.doi.org/10.1107/S160053681005422X
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author Fun, Hoong-Kun
Goh, Jia Hao
Maity, Annada C.
Goswami, Shyamaprosad
author_facet Fun, Hoong-Kun
Goh, Jia Hao
Maity, Annada C.
Goswami, Shyamaprosad
author_sort Fun, Hoong-Kun
collection PubMed
description In the title complex, [CuBr(2)(C(6)H(4)N(2)Se)(2)], the Cu(II) ion is tetra­coordinated by two bromide anions and two N atoms in a distorted square-planar geometry. The two essentially planar 2,1,3-benzoselenadiazole ligands [maximum deviations = 0.012 (2) and 0.030 (2) Å] are approximately coplanar [dihedral angle = 6.14 (6)°]. In the crystal, short inter­molecular Se⋯Br, Se⋯N and N⋯N inter­actions are observed. These short inter­actions and inter­molecular C—H⋯Br hydrogen bonds link the complex mol­ecules into two-dimensional arrays parallel to the ac plane.
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spelling pubmed-30517642011-04-26 Bis(2,1,3-benzoselenadiazole-κN)dibromidocopper(II) Fun, Hoong-Kun Goh, Jia Hao Maity, Annada C. Goswami, Shyamaprosad Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [CuBr(2)(C(6)H(4)N(2)Se)(2)], the Cu(II) ion is tetra­coordinated by two bromide anions and two N atoms in a distorted square-planar geometry. The two essentially planar 2,1,3-benzoselenadiazole ligands [maximum deviations = 0.012 (2) and 0.030 (2) Å] are approximately coplanar [dihedral angle = 6.14 (6)°]. In the crystal, short inter­molecular Se⋯Br, Se⋯N and N⋯N inter­actions are observed. These short inter­actions and inter­molecular C—H⋯Br hydrogen bonds link the complex mol­ecules into two-dimensional arrays parallel to the ac plane. International Union of Crystallography 2011-01-15 /pmc/articles/PMC3051764/ /pubmed/21522854 http://dx.doi.org/10.1107/S160053681005422X Text en © Fun et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Fun, Hoong-Kun
Goh, Jia Hao
Maity, Annada C.
Goswami, Shyamaprosad
Bis(2,1,3-benzoselenadiazole-κN)dibromidocopper(II)
title Bis(2,1,3-benzoselenadiazole-κN)dibromidocopper(II)
title_full Bis(2,1,3-benzoselenadiazole-κN)dibromidocopper(II)
title_fullStr Bis(2,1,3-benzoselenadiazole-κN)dibromidocopper(II)
title_full_unstemmed Bis(2,1,3-benzoselenadiazole-κN)dibromidocopper(II)
title_short Bis(2,1,3-benzoselenadiazole-κN)dibromidocopper(II)
title_sort bis(2,1,3-benzoselenadiazole-κn)dibromidocopper(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051764/
https://www.ncbi.nlm.nih.gov/pubmed/21522854
http://dx.doi.org/10.1107/S160053681005422X
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