Chlorido{N-[(diethyl­amino)­dimethyl­sil­yl]anilido-κN}(N,N,N′,N′-tetra­methyl­ethane-1,2-diamine-κ(2) N,N′)cobalt(II)

In the title cobalt(II) compound, [Co(C(12)H(21)N(2)Si)Cl(C(6)H(16)N(2))], the ethane-1,2-diamine donor mol­ecule coordin­ates the metal atom in an N,N′-chelating mode, with Co—N distances of 2.136 (2) and 2.140 (3) Å. An anilide ligand connects to the Co(II) atom with a σ–bond, the Co—N(anilide) di...

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Detalles Bibliográficos
Autores principales: Bai, Sheng-Di, Hu, Min
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051766/
https://www.ncbi.nlm.nih.gov/pubmed/21522921
http://dx.doi.org/10.1107/S1600536811002959
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author Bai, Sheng-Di
Hu, Min
author_facet Bai, Sheng-Di
Hu, Min
author_sort Bai, Sheng-Di
collection PubMed
description In the title cobalt(II) compound, [Co(C(12)H(21)N(2)Si)Cl(C(6)H(16)N(2))], the ethane-1,2-diamine donor mol­ecule coordin­ates the metal atom in an N,N′-chelating mode, with Co—N distances of 2.136 (2) and 2.140 (3) Å. An anilide ligand connects to the Co(II) atom with a σ–bond, the Co—N(anilide) distance being 1.931 (2) Å. The four-coordinate Co(II) atom demonstrates a slightly distorted tetra­hedral geometry.
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spelling pubmed-30517662011-04-26 Chlorido{N-[(diethyl­amino)­dimethyl­sil­yl]anilido-κN}(N,N,N′,N′-tetra­methyl­ethane-1,2-diamine-κ(2) N,N′)cobalt(II) Bai, Sheng-Di Hu, Min Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title cobalt(II) compound, [Co(C(12)H(21)N(2)Si)Cl(C(6)H(16)N(2))], the ethane-1,2-diamine donor mol­ecule coordin­ates the metal atom in an N,N′-chelating mode, with Co—N distances of 2.136 (2) and 2.140 (3) Å. An anilide ligand connects to the Co(II) atom with a σ–bond, the Co—N(anilide) distance being 1.931 (2) Å. The four-coordinate Co(II) atom demonstrates a slightly distorted tetra­hedral geometry. International Union of Crystallography 2011-01-29 /pmc/articles/PMC3051766/ /pubmed/21522921 http://dx.doi.org/10.1107/S1600536811002959 Text en © Bai and Hu 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Bai, Sheng-Di
Hu, Min
Chlorido{N-[(diethyl­amino)­dimethyl­sil­yl]anilido-κN}(N,N,N′,N′-tetra­methyl­ethane-1,2-diamine-κ(2) N,N′)cobalt(II)
title Chlorido{N-[(diethyl­amino)­dimethyl­sil­yl]anilido-κN}(N,N,N′,N′-tetra­methyl­ethane-1,2-diamine-κ(2) N,N′)cobalt(II)
title_full Chlorido{N-[(diethyl­amino)­dimethyl­sil­yl]anilido-κN}(N,N,N′,N′-tetra­methyl­ethane-1,2-diamine-κ(2) N,N′)cobalt(II)
title_fullStr Chlorido{N-[(diethyl­amino)­dimethyl­sil­yl]anilido-κN}(N,N,N′,N′-tetra­methyl­ethane-1,2-diamine-κ(2) N,N′)cobalt(II)
title_full_unstemmed Chlorido{N-[(diethyl­amino)­dimethyl­sil­yl]anilido-κN}(N,N,N′,N′-tetra­methyl­ethane-1,2-diamine-κ(2) N,N′)cobalt(II)
title_short Chlorido{N-[(diethyl­amino)­dimethyl­sil­yl]anilido-κN}(N,N,N′,N′-tetra­methyl­ethane-1,2-diamine-κ(2) N,N′)cobalt(II)
title_sort chlorido{n-[(diethyl­amino)­dimethyl­sil­yl]anilido-κn}(n,n,n′,n′-tetra­methyl­ethane-1,2-diamine-κ(2) n,n′)cobalt(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051766/
https://www.ncbi.nlm.nih.gov/pubmed/21522921
http://dx.doi.org/10.1107/S1600536811002959
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AT humin chloridondiethylaminodimethylsilylanilidoknnnnntetramethylethane12diaminek2nncobaltii

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