2,7-Dimethyl-2,7-diazo­niapyrene bis­(hexa­fluoro­phosphate)

In the title compound, C(16)H(14)N(2) (2+)·2PF(6) (−), the 2,7-dimethyl-2,7-diaza­pyrenium (DM-diaz) cation lies on a crystallographic twofold rotation axes. The diaz groups are nearly coplanar, with a maximum deviation of 0.008 (3) Å. In the crystal, mol­ecules are linked into a two-dimensional lam...

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Detalles Bibliográficos
Autor principal: Ang, Li
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051768/
https://www.ncbi.nlm.nih.gov/pubmed/21523159
http://dx.doi.org/10.1107/S1600536811001978
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author Ang, Li
author_facet Ang, Li
author_sort Ang, Li
collection PubMed
description In the title compound, C(16)H(14)N(2) (2+)·2PF(6) (−), the 2,7-dimethyl-2,7-diaza­pyrenium (DM-diaz) cation lies on a crystallographic twofold rotation axes. The diaz groups are nearly coplanar, with a maximum deviation of 0.008 (3) Å. In the crystal, mol­ecules are linked into a two-dimensional lamellar framework parallel to (104) through weak C—H⋯F inter­actions.
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spelling pubmed-30517682011-04-26 2,7-Dimethyl-2,7-diazo­niapyrene bis­(hexa­fluoro­phosphate) Ang, Li Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(16)H(14)N(2) (2+)·2PF(6) (−), the 2,7-dimethyl-2,7-diaza­pyrenium (DM-diaz) cation lies on a crystallographic twofold rotation axes. The diaz groups are nearly coplanar, with a maximum deviation of 0.008 (3) Å. In the crystal, mol­ecules are linked into a two-dimensional lamellar framework parallel to (104) through weak C—H⋯F inter­actions. International Union of Crystallography 2011-01-29 /pmc/articles/PMC3051768/ /pubmed/21523159 http://dx.doi.org/10.1107/S1600536811001978 Text en © Li Ang 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Ang, Li
2,7-Dimethyl-2,7-diazo­niapyrene bis­(hexa­fluoro­phosphate)
title 2,7-Dimethyl-2,7-diazo­niapyrene bis­(hexa­fluoro­phosphate)
title_full 2,7-Dimethyl-2,7-diazo­niapyrene bis­(hexa­fluoro­phosphate)
title_fullStr 2,7-Dimethyl-2,7-diazo­niapyrene bis­(hexa­fluoro­phosphate)
title_full_unstemmed 2,7-Dimethyl-2,7-diazo­niapyrene bis­(hexa­fluoro­phosphate)
title_short 2,7-Dimethyl-2,7-diazo­niapyrene bis­(hexa­fluoro­phosphate)
title_sort 2,7-dimethyl-2,7-diazo­niapyrene bis­(hexa­fluoro­phosphate)
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051768/
https://www.ncbi.nlm.nih.gov/pubmed/21523159
http://dx.doi.org/10.1107/S1600536811001978
work_keys_str_mv AT angli 27dimethyl27diazoniapyrenebishexafluorophosphate

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